Combined analysis of the high sensitivity Fourier transform and ICLAS-VeCSEL absorption spectra of D2O between 8800 and 9520 cm

The absorption spectrum of dideuterated water, D₂O, has been recorded between 8800 and 9520 cm⁻¹ by intracavity laser absorption spectroscopy (ICLAS) based on a vertical external cavity system emitting laser (VeCSEL) and by high sensitivity Fourier Transform spectroscopy. The combined analysis of the spectra has allowed attributing 1223 transitions to the D₂O species. The spectrum assignment was performed on the basis of the recent results of variational calculations based on an optimized potential energy surface of D₂O. A set of 687 energy levels was derived from transitions assigned to eight upper vibrational states, 577 of them being reported for the first time. A detailed line list has been generated. The line intensities were retrieved mainly from the FTS spectrum and the absolute integrated intensities of the 2v₁ + v₂ + v₃ and the v₂ + 3v₃ bands dominating the spectrum have been determined.     

Fe(100)表面Cu单层膜上CO的吸附,解离以及C-C偶合反应

采用密度泛函方法研究了Fe(100)表面Cu单层膜上CO的吸附,直接解离,氢助解离以及C-C偶合反应.相比洁净的Fe(100)表面,在Fe(100)的单层Cu膜上,CO的吸附和活化都减弱了.特别是,相比Fe(100)上CO的解离能垒1.08 eV,铜单层膜上CO解离能垒高达2.4 eV.在H原子共吸附的情况下,Fe(1...     

激光干涉条纹辅助FTS干涉图数据采样

分析了傅里叶变换光谱仪测量对参考光源的要求,介绍了所研制傅里叶变换光谱仪的光学系统。应用电子学自动增益锁相环倍频技术处理稳频激光干涉图信号,获得了用于干涉图采样的外触发控制信号。选择锁相环８倍频处理实现了电子学信号模拟测量,并且实际测量了Ｈｅ－Ｎｅ激光管６３２．８ｎｍ波长的光谱。该电子学及光学辅助采样系统可以用于测量可见、紫外－真空紫外波段光源光谱。     

Spectroscopy of nickel chloride: Identification of the [15.0] Π3/2 and [15.0] Δ5/2 states

Vibrational bands belonging to the [15.0] ²Δ_5/2-A²Δ_5/2, [15.0] ²Δ_5/2-X²Π_3/2, and [15.0] ²Π_3/2-X²Π_3/2 electronic transitions of NiCl have been observed in the 14 000-16 000 cm⁻¹ region. The [15.0] ²Δ_5/2 and [15.0] ²Π_3/2 states are identified for the first time. The observed bands have been recorded at high spectral resolution using several techniques, which include intracavity laser spectroscopy (ILS), Fourier transform emission spectroscopy (FTS), and laser induced fluorescence (LIF) spectroscopy. For the ILS absorption spectra, NiCl molecules were produced in a nickel hollow cathode operated with a small amount of CCl₄. For the FTS emission spectra, excited NiCl molecules were produced in a King-type carbon tube furnace loaded with NiCl₂ and heated to 1600 °C. In the LIF work, NiCl molecules were produced by reacting laser-ablated nickel with PCl₃ seeded in argon. Detailed analysis of rotational transition lines indicates that the observed [15.0] ²Δ_5/2 and [15.0] ²Π_3/2 states are only separated by 10 cm⁻¹ and are interacting with each other. Molecular constants for these newly observed electronic states are reported.     

Detector quantum efficiency: An important parameter for FT-IR spectroscopy

Spectral detectivities (D ^*()) are commonly used to characterize the sensitivity of infrared detectors, but for most spectroscopic purposes they are very misleading.For photon detectorsspectral detector quantum efficiencies ( _q ()) are needed in order to calculate the (S/N) ratio for the photon-noise limited situation. An equation to calculate _q(#x03C3;) fromD ^*() values is presented. The results for some common IR-detectors are surprising.As an application for the use of _q () values theS/N ratio of an FT-IR spectrum from an optimized FTS instrument under photon-limited conditions is given.     

用外差混频和直接检波方法测量亚毫米波连续波源的频谱

在亚毫米波频段,表征信号源的频谱特性是一项重要工作．用外差混频和直接检波（缚里叶变换频谱仪,FTS）两种方法测量一个亚毫米波连续波源（采用锁相技术且可在460～520GHz范围内调频）的频谱．500～GHz频段超导SIS隧道结在外差混频方法里用作混频器,而在直接检波方法里作为直接检波黔．并对两种方法得到的结果进行了比较．     

First assignment of the 5ν4 and ν2+4ν4 band systems of CH4 in the 6287-6550 cm region

This paper reports the first assignment of rovibrational transitions of the 5ν₄ and ν₂+4ν₄ band systems of ¹²CH₄ in the 6287-6550 cm⁻¹ region, which is usually referred to as part of the 1.58 μm methane transparency window. The analysis was based on two line lists previously obtained in Grenoble by cavity ring down spectroscopy at T=297 and 79 K completed by three long-path Fourier transform spectra recorded in Reims (at 290 K, L=1603 m, P=1-34 mbar). In order to determine the dipole transition moment parameters and quantify the intensity borrowing due to the resonance interactions, we had to include in the fit of the effective Hamiltonian model some lines of the stronger ν₁+3ν₄ and ν₂+4ν₄ bands. For this purpose, intensities of 179 additional lines were retrieved from FTS spectra above 6550 cm⁻¹ though the analysis of these higher bands is not complete. About 1955 experimental line positions and 1462 line intensities were fitted with RMS standard deviations of 0.003 cm⁻¹ and 13.1%, respectively. A line list of 8029 calculated and observed transitions which are considered as dominant was constructed for ¹²CH₄ in the 6287-6550 cm⁻¹ region. This is the first high-resolution analysis and modelling of 5-quanta band systems of ¹²CH₄.     

Fuzzy序列紧性,可数Fuzzy紧性和Fuzzy列紧性

本文引进了Fuzzy序列紧性、可数Fuzzy紧性和Fuzzy列紧性,它们是一般拓扑学中相应概念的“良扩张”(R. Lowen意义下),文中讨论了这些fts的主要性质,以及它们之间的联系。     

新型空间调制微型傅里叶变换光谱仪的设计与仿真

傅里叶变换光谱仪(FTS)在光谱分析中的应用越来越广泛,并且其微型化的趋势也愈加明显。文章设计了一种新型空间调制微型傅里叶变换光谱仪。在介绍其结构理论的基础上,对其空间的光强分布进行了模拟,通过对该结构下引起相位误差因素的详细分析,采用改进的Mertz相位校正方法对小双边的采样数据进行了光谱复原,其理论分辨率可达到3.43 nm@800 nm,信噪比的理想分辨极限为6.8 dB。该结构的微型FTS可以用微机械加工的方法来实现,具有性能稳定,误差容易校正等优点,文章对空间调制微型傅里叶变换光谱仪的结构设计及仿真,为微型FTS的微机械加工实验提供了理论支持, 还为微型傅里叶变换光谱仪的进一步应用提供了更广阔的空间。     

氢稀释对FTS沉积a-Si:H薄膜结构特性的影响

采用对靶磁控反应溅射技术,以氢气作为反应气体在不同的氢稀释比条件下制备了氢化非晶硅薄膜.利用台阶仪、傅里叶红外透射光谱、Raman谱和紫外-可见光透射谱测量研究了不同氢稀释比对氢化非晶硅薄膜生长速率和结构特性的影响.分析结果发现,利用对靶磁控溅射技术能够实现低温快速沉积高质量氢化非晶硅薄膜的制备.随着氢稀释比不断增加,薄膜沉积速率呈现先减小后增大的趋势.傅里叶红外透射光谱表明,氢化非晶硅薄膜中氢含量先增大后变小.而Raman谱和紫外-可见光透射谱分析发现,氢稀释比的增加使氢化非晶硅薄膜有序度和光学带隙均先增大后减小.可见,此技术通过改变氢稀释比R能够实现氢化非晶硅薄膜结构的有效控制.