固体铝电解电容器用导电高分子制备工艺进展

依据近年的相关专利,综述了用于固体铝电解电容器的导电高分子的最新制备工艺,介绍了导电高分子固体铝电解电容器的结构,详细描述了制备导电高分子的两种主要方法——化学聚合和电化学聚合——及其进展历程。介绍了新颖掺杂剂的发现与使用,对各种工艺的特点进行了评述。     

超高压大容量铝电解电容器的研制

分析了大功率设备用超高压大容量铝电解电容器的特点,通过研制工作电解液、制订制作工艺及零部件设计方案,研制出的超高压大容量铝电解电容器具有损耗角正切小(tgδ为0.25)、承受纹波电流能力强(100 Hz,2.12～27.8 A)及寿命长的特点,耐久性达到85℃,5 000 h。     

提高超小型铝电解电容器生产一次合格率

恰当选择原材料、确保铆接工序质量、重视工作电解液的配比、严控各工序成品率是提高超小型铝电解电容器投入产出一次合格率的关键。以１０Ｖ－４７μＦ（４ｍｍ×７ｍｍ）产品为例，投入产出一次合格率达９４％以上。     

参数设计法在铝电解电容器设计中的应用探讨

论述了参数设计法在铝电解电容器设计开发阶段的应用。文中阐明了铝电解电容器的主要质量特性(损耗因子、电容量)及芯包外径的参数设计原理,并建立了归一化函数作为优选设计方案的判据。实例证明在铝电解电容器的设计过程中应用参数设计法以减小产品质量特性变异是有效的。     

硫酸/盐酸比例和Al~(3+)含量对铝箔隧道孔生长的影响

研究了硫酸/盐酸比例、温度和Al3+含量对高纯铝箔隧道孔生长的影响,发现随着硫酸浓度增加,温度对隧道孔极限长度和孔径的影响减小,在本文条件下隧道孔生长的临界温度最低可降低到35℃。在电解液中一定含量的Al3+可以避免铝箔表面形成大孔,从而改善隧道孔分布均匀性。     

Characterization of ceramic PVD thin films on AZ31 magnesium alloys

Ceramic thin films have been widely used to protect the metal substrate as coatings in the past years. In order to improve the poor corrosion resistance of AZ31 magnesium alloy, the study in this paper used the electron beam evaporation method to prepare ceramic PVD films on its surface with TiO₂ and Al₂O₃ as donors, respectively. Atomic force microscopy (AFM), scanning electron microscope (SEM), energy dispersive X-ray spectrometer (EDS), Auger electron spectroscopy (AES) and X-ray diffraction (XRD) were used to investigate the surface morphology, composition and microstructure of the thin films. Both films deposited on AZ31 took on compact top surface morphologies and grew as amorphous structures on substrate. AES test not only showed that films compositions deviated the standard stoichiometric ratios, but also found that element Mg diffused into films and existed as magnesium oxide in the TiO_x film as well as the AlO_x film. In the electrochemical corrosion test, the AlO_x coating on AZ31 exhibited the largest electrochemical impedance in a 3.5% NaCl solution. But it did not show better corrosion resistance than others for the poorer adhesion. Even if its thickness was small, the TiO_x coating on AZ31 exhibited the best corrosion resistance in this study. According to the observation and analysis, the damage of these films on AZ31 in aggressive solutions was mainly due to the existence of pores, microcracks, vacancies and poor adhesion between coating and substrate.     

精密陶瓷部件近净成型技术的发展

重点介绍了近十年发展起来的陶瓷部件的近净成型技术 ,主要包括直接凝固注模成型、凝胶注模成型、陶瓷注射成型、陶瓷无模成型和微注入成型。对这些新的成型方法的原理、工艺过程及应用特点进行了较全面的分析与比较。     

Effect of the polymer matrices on the dielectric behavior of a percolative high-k polymer composite for embedded capacitor applications

High dielectric constant (high-k) polymer composites are of great interest for embedded capacitor applications. Previously, we demonstrated that epoxy—aluminum composites are promising for embedded capacitor applications, because they have a high dielectric constant and a low dielectric loss due to the core—shell structure of the self-passivated aluminum particles. In this work, to further understand the dielectric behavior of aluminum composites, lower-loss polymers such as silicone, polyimide, polynorbornene, and benzocyclobutene were explored as matrices for the aluminum composites. It is found that the polymer matrices can significantly change the dielectric properties of the aluminum composites. A polymer matrix with a lower dielectric constant generally results in a lower dielectric constant of its aluminum composites. In this regard, polymer—aluminum composites have a similar dielectric characteristic as polymer—ceramic composites. Thermomechanical properties of aluminum composites were characterized by a thermomechanical analyzer.     

从数字看发展片式电容器面临的机遇与挑战

采用海关进、出口统计和行业生产统计资料,通过计算、分析,用数字来说明国内发展片式多层陶瓷电容器、片式钽电解电容器、片式铝电解电容器、片式有机薄膜电容器所面临的机遇与挑战,并对其国内市场需求总量、额,国产品在国内市场占有率等做出评估,为有关单位了解片式电容器的发展提供参考,为国产产品更有效地进入国内市场、促进其发展提供依据。     

Chromium and yttrium-doped magnesium aluminum oxides prepared from layered double hydroxides

Layered double hydroxides with the hydrotalcite-like structures, containing Mg²⁺ and Al³⁺, doped with Cr³⁺ and Y³⁺, have been prepared by precipitation at constant pH. The weight percentages of Cr³⁺ and Y³⁺ were 1, 2, or 3%, and 0.5 or 1%, respectively. Single phases were obtained in all cases, whose crystallinity decreased as the content in Cr and Y was increased. The solids have been characterised by element chemical analysis, powder X-ray diffraction, thermal analyses (differential, thermogravimetric and programmed reduction), FT-IR and UV–vis spectroscopies; the specific surface areas have been determined from nitrogen adsorption isotherms at −196 °C. Upon calcination at 1200 °C for 5 h in air all solids display a mixed structure (spinel and rock salt for MgO); these solids have also been characterised by these techniques and their chromatic coordinates (CIE – L^*a^*b^*) have been determined. Their pink colour makes these solids suitable for being used as ceramic pigments.