Reaction of η5-cyclopentadienylbis(triphenylphosphine)cobalt(I) with alkadiynes. Preparation and reactions of bicyclic cobalt metallocycles and a stable trimethylsilyl-substituted mono-complexed alkadiyne. Comments on the mechanism of cobalt-catalyzed alkyne cooligomerization

Reactions of η⁵-cyclopentadienylbis(triphenylphosphine)cobalt(I) (5) with several 2,n-alkadiynes (2) were investigated. Each of these reactions leads initially to a material in which one of the acetylene functional groups is π-coordinated to cobalt; this complex then undergoes conversion to a metallocycle. In cases where the two acetylene functions are connected by three- and four-carbon bridges (2b, 2c), metallocycles formed by intramolecular reaction of two acetylene functions in the same molecule may be isolated. In cases where the acetylene functions are joined by larger or smaller bridges, the reactions are more complex, and both inter- and intramolecular metallocycles are formed. Reactions of 5 with 1,8-bis(trimethylsilyl)-1,7-octadiyne (16) gives an isolable crystalline mono-acetylene complex (17), this material is stable in the solid state but undergoes conversion to metallocycle (18) in benzene solution. The relationship of these results to the mechanism of the CpCo(CO)₂-catalyzed benzocycloalkene synthesis is discussed; it is suggested that intramolecular metallocycles are intermediates in reactions leading to benzocyclopentanes and -cyclohexenes, but intermolecular metallocycles are probably involved in reactions leading to benzocyclobutenes.     

“信号与系统的结构与解释”课程的教学体会

＂信号与系统的结构与解释＂作为＂信号与系统＂和＂数字信号处理＂课程之间的桥梁,是美国加州大学伯克利分校近几年开设的一门新课程。本文较系统地介绍了该课程的讲授内容和考核题目的形式,以及在我校开设选修课的体会。最后,给出对学生的无记名调查问卷内容和统计分析。     

基于BDB的XML检索引擎算法设计与实现

XML作为互联网数据交换及数据表现的标准,其重要性日益凸显,如何从大量的XML中挖掘有效信息已成为目前亟待解决的问题。设计并实现一个基于BDB的XML检索引擎算法XObject,通过构造关键词结构查询路径、进行结构聚类,并最终在BDBXML执行Xquery查询实现本地XML的关键字检索,从而解决XML信息挖掘中的关键技术课题——xML信息检索。     

Sequence of the most informative joints (SMIJ): A new representation for human skeletal action recognition

Much of the existing work on action recognition combines simple features with complex classifiers or models to represent an action. Parameters of such models usually do not have any physical meaning nor do they provide any qualitative insight relating the action to the actual motion of the body or its parts. In this paper, we propose a new representation of human actions called sequence of the most informative joints (SMIJ), which is extremely easy to interpret. At each time instant, we automatically select a few skeletal joints that are deemed to be the most informative for performing the current action based on highly interpretable measures such as the mean or variance of joint angle trajectories. We then represent the action as a sequence of these most informative joints. Experiments on multiple databases show that the SMIJ representation is discriminative for human action recognition and performs better than several state-of-the-art algorithms.     

Influence of surface relaxation on the IR spectrum of microcrystalline MgO

Relaxation effects on the infrared spectra of microcrystalline MgO prepared under controlled conditions have been studied both by varying the average particle size and by chemisorption of pyndine. The results are compared with the phonon density of states distribution calculated by other authors.     

基于VxWorks的嵌入式数据库工程实现与应用

随着嵌入式系统的应用越来越广泛,嵌入式系统存储和处理的数据量不断增加,数据安全性和可靠性成为嵌入式系统设计阶段需要考虑的重要因素之一。介绍了伯克利数据库(Berkeley DB)的基本原理,并给出了基于Vx-Works系统的Berkeley DB的应用方法,最后通过一个设计实例,对比了传统文件操作和数据库操作在存储空间和读写时间上的性能比较。     

Surface composition of Fe-Al2O3 granular thin films by X-ray photoemission spectroscopy

X-ray photoemission Spectroscopy (XPS) results are presented which have given a direct insight into the surface composition of Fe-Al₂ O₃ “granular” thin films consisting of fine iron particles (φ ~ 40–150 Å) dispersed in an insulating alumina matrix. The data are mainly discussed in relation to: (i) the bulk iron content in the sample, (ii) the sample preparation procedure (e.g., by rotation of the sample target) and (iii) the mean iron particle size.At the surface, the iron is in a fully oxidized 3⁺ state within an alumina-rich partly hydrated region. Depth analysis, achieved by an Ar⁺ etching procedure, provides evidence of metallic iron and iron aluminate forms. In general, the metallic iron percentage increases with depth and with increasing iron bulk content.Good agreement is found between X-ray photoemission spectroscopy and Mössbauer Spectroscopy data. Fe²⁺ aluminate forms, which indicate an interaction between the metal particle and the alumina matrix, show increasing percentages with decreasing mean particle sizes.Particular attention is paid to evaluating the accuracy of XPS quantitative results, obtained by use of a first-principles model, and to assessing the importance of the artefacts associated with the Ar⁺ etching procedure.     

In Appreciation

Leslie Foldy’s diminutive stature and modest demeanor gave little clue to the powerful intellect responsible for several significant advances in theoretical physics.Two were particularly important. His 1945 theory of the multiple scattering of waves laid out the fundamentals that most modern theories have followed (and sometimes rediscovered), while his work with Siegfried Wouthuysen on the nonrelativistic limit of the Dirac equation opened the way to a wealth of valuable insights. In this article we recall some of the milestones along Foldy’s path through a life in physics. Some of the anecdotes we report here were related to one of the authors (PLT) just before an event in 2000 celebrating Foldy’s 80th birthday, while others were told to us over the course of the nearly forty years during which we were colleagues. Still others were uncovered during the course of WJF’s research for his book, Physics at a Research University: Case Western Reserve 1830–1990 (Cleveland: Case Western Reserve University, 2006). Other details were provided by Foldy’s widow, Roma. Philip L. Taylor is the Perkins Professor of Physics and Professor of Macromolecular Science and Engineering at Case Western Reserve University. William J. Fickinger is Professor Emeritus of Physics at Case Western Reserve University.     

On the Ramsey numbers R(3, 8) and R(3, 9)

Using methods developed by Graver and Yackel, and various computer algorithms, we show that 28 ≤ R(3, 8) ≤ 29, and R(3, 9) = 36, where R(k, l) is the classical Ramsey number for 2-coloring the edges of a complete graph.