A new Monte Carlo model for predicting the mechanical properties of fiber yarns

Understanding the complicated failure mechanisms of hierarchical composites such as fiber yarns is essential for advanced materials design. In this study, we developed a new Monte Carlo model for predicting the mechanical properties of fiber yarns that includes statistical variation in fiber strength. Furthermore, a statistical shear load transfer law based on the shear lag analysis was derived and implemented to simulate the interactions between adjacent fibers and provide a more accurate tensile stress distribution along the overlap distance. Simulations on two types of yarns, made from different raw materials and based on distinct processing approaches, predict yarn strength values that compare favorably with experimental measurements. Furthermore, the model identified very distinct dominant failure mechanisms for the two materials, providing important insights into design features that can improve yarn strength.     

Synthesis of high performance,conductive PEDOT‐coated polyester yarns by OCVD technique

Production of high performance conductive textile yarn fibers for different electronic applications has become a prominent area of many research groups throughout the world. We have used oxidative chemical vapor deposition (OCVD) technique to coat flexible and high strength polyester yarns with conjugated polymer, poly(3,4‐ethylenedioxythiophene) (PEDOT) in presence of ferric (III) chloride (FeCl₃) oxidant. OCVD is an efficient solvent free technique used to get uniform, thin, and highly conductive polymer layers on different substrates. In this paper, PEDOT‐coated polyester (PET) yarns were prepared under specific reaction conditions, and the electrical, mechanical and thermal properties were compared to previously studied PEDOT‐coated viscose yarns. Scanning electron microscopy (SEM) and FT‐IR analysis revealed that polymerization of PEDOT on the surface of the polyester yarns has been taken place successfully and structural analysis showed that PEDOT has strong interactions with viscose yarns as compared to PET yarns. The voltage–current (V–I) characteristics showed that PET yarns are more conductive than PEDOT‐coated viscose yarns. The variation in the conductivity of PEDOT‐coated yarns and the heat generation properties during the flow of current through coated yarns for longer period of time, was studied by time–current (t–I) characteristics. Thermogravimeteric analysis (TGA) was employed to investigate the thermal properties and the amount of PEDOT in PEDOT‐coated PET yarns compared to PEDOT‐coated viscose. The effect of PEDOT coating and ferric (III) chloride concentration on the mechanical properties of coated yarns was evaluated by tensile testing. The obtained PEDOT‐coated conductive polyester yarns could be used in smart clothing for medical and military applications. Copyright © 2011 John Wiley & Sons, Ltd.     

Comparison of the Morphological,Mechanical, and UV Protection Properties of TiO2/Polyamide 6 (PA6), and ZnO/PA6 Nanocomposite Multifilament Yarns

The properties of TiO₂/polyamide 6 (PA6) and ZnO/PA6 nanocomposite filament yarns produced on a pilot-plant melt spinning machine were compared. Concentrated masterbatches were prepared using a twin screw extruder. Then continuous multifilament yarns were produced by blending nylon 6 chips and various amounts of the prepared masterbatches. Melt spinning was carried out at the spinning temperature of 265°C and take-up speed of 4000 m/min. As-spun multifilament yarns were then drawn and textured. Morphological properties of the produced yarns were studied. Thermal behavior and physical properties, including shrinkage and tensile properties, were measured. Weft-knitted fabrics were evaluated for their ultraviolet protection properties. Although both kinds of the nanoparticles had a positive effect on the ultraviolet protection properties of their nanocomposite fabrics as compared to pure PA6 fabric, the efficiency of the TiO₂ nanoparticles was more than that of the ZnO ones for the same concentrations. The differences between the different properties of the two kinds of nanocomposites are discussed based on their interaction with the polymeric matrix, specific surface area, steric hindrance effect, and band gap energies.     

Quasistatic model for two-strand yarn spinning

A theoretical model underlying a two-strand spinning system is given. Based on the force balance and dynamics characters of the system (mass conservation, energy conservation, and momentum conservation), this system of the equations governing the quasistatic two-strand yarn spinning is self-contained, so that the convergence point can be determined with ease for different inlet velocities, densities, sizes (diameters) of the two strands.     

Advanced polymeric composites via commingling for critical engineering applications

The commingled technology is one of the most effective and alternative methodologies for producing more sustainable as well as uniformly distributed natural fiber reinforced composite without inflecting the shearing strength on yarns or reinforcing natural fiber. The term commingled encompasses the materials consisting of both polymer matrix and reinforcing materials over the same fabric cross-section used for the production of highly flexible, continuous fiber-reinforced thermoplastic prepregs. Nonetheless, the increased pathlength and high melt viscosity around 500–5000 Pa s of the molten thermoplastic makes the processing more difficult compared with other thermoset plastic (usually 100 Pa s). Where the commingled hybrid yarns can be considered as one of the promising preforms employed for long fiber reinforced composite because of low cost, ease of storage and manipulation, excellent flexibility, molding capacity, reduced pressure consolidation as well as impregnation time while processing and the ability to form complex-shaped reinforced composite parts. The parameters that affect the process of commingling controls the consolidation of hybrid yarns thermoplastic composite; the degree of commingling depends on the pressure, temperature, and production speed during a fixed period. Recently commingled thermoplastic composite has become one of the possible destines for a wide array of applications in aircrafts, automotive, and sporting goods. This paper reviews types of commingled plastic composite, various processing routes, and the influence of the processing parameters, their properties, and their application. The manufacturing and development of hybrid yarns through air-jet texturing, intermingling process, are also discussed concerning the attributes of advanced composites.     

Processing and Properties of Nanocomposite Filament Yarns with Various Filler Concentrations from Two Different Modification Methods

In this research, the possibility of producing and processing nanocomposite polypropylene filament yarns with permanent antimicrobial efficiency has been assessed by comparing two different methods. Therefore two approaches were used to mix various blending contents of antimicrobial agents based on silver/TiO₂ nano particles with PP: 1) mixing of PP powder and inorganic nanocomposite powder as an antibacterial agent with the appropriate concentration in a twin screw extruder, preparing modified granules and feeding them to the melt spinning machine, 2) producing masterbatch by a twin screw extruder and blending it with PP in the melt spinning process. In both methods, pure PP and all other combined samples had an acceptable spinnability at the spinning temperature of 240 °C and take-up speed of 2000 m/min. After producing as-spun filament yarns by a pilot plant melt spinning machine, samples were drawn, textured and finally weft knitted. Physical and structural properties of as-spun and drawn yarns with constant and variable draw ratios were investigated and compared. Moreover, the DSC, SEM and FTIR techniques have been used for samples characterization. Finally antibacterial efficiency of knitted samples was evaluated. The experimental results indicated that the maximum crystallinity reduction of modified as-spun yarns reached 5%. But by applying method 2 (masterbatch), crystallinity of modified as-spun yarns remained unchanged compared to pure yarn. However, drawing procedure has compensated this difference. By applying the second method, the drawing generally improved the increase of tenacity and modulus of modified fibers, whereas in method 1 the opposite effect was noticed in the case of constant draw ratio. Although the biostatic efficiency of nanocomposite fibers was excellent in both methods, modified fabrics obtained from method 1 showed higher bioactivity.     

A high efficiency 3D photovoltaic microwire with carbon nanotubes (CNT)‐quantum dot (QD) hybrid interface

An innovative hybrid QD sensitized photovoltaic carbon nanotubes microyarn has been developed using thermally‐stable and highly conductive carbon nanotubes yarns (CNYs). These CNYs are highly inter‐aligned, ultrastrong and flexible with excellent electrical conductivity, mechanical integrity and catalytic properties. The CNYs are coated with a QD‐incorporated TiO₂ microfilm and intertwined with a second set of CNYs as a counter electrode (CE). The maximum photon to current conversion efficiency (η_AM1.5) achieved with prolonged‐time stability was 5.93%. These cells are capable of efficiently harvesting incident photons regardless of direction and generating photocurrents with high efficiency and operational stability.

     

Synthesis of carbon nanofibers@MnO2 3D structures over copper foil as binder free anodes for lithium ion batteries

A 3D structured composite of carbon nanofibers@MnO₂ on copper foil is reported here as a binder free anode of lithium ion batteries, with high capacity, fast charge/discharge rate and good stability. Carbon nanofiber yarns were synthesized directly over copper foil through a floating catalyst method. The growth of carbon nanofiber yarns was significantly enhanced by mechanical polishing of the copper foils, which can be attributed to the increased surface roughness and surface area of the copper foils. MnO₂ was then grown over carbon nanofibers through spontaneous reduction of potassium permanganate by the carbon nanofibers. The obtained composites of carbon nanofibers@MnO₂ over copper foil were tested as an anode in lithium ion batteries and they show superior electrochemical performance. The initial reversible capacity of carbon nanofibers@MnO₂ reaches up to around 998 mAh·g^?1 at a rate of 60 mmA·g^?1 based on the mass of carbon nanofibers and MnO₂. The carbon nanofibers@MnO₂ electrodes could deliver a capacity of 630 mAh·g^?1 at the beginning and maintain a capacity of 440 mmAh·g^?1 after 105 cycles at a rate of 600 mA·g^?1. The high initial capacity can be attributed to the presence of porous carbon nanofiber yarns which have good electrical conductivity and the MnO₂ thin film which makes the entire materials electrochemically active. The high cyclic stability of carbon nanofibers@MnO₂ can be ascribed to the MnO₂ thin film which can accommodate the volume expansion and shrinking during charge and discharge and the good contact of carbon nanofibers with MnO₂ and copper foil.     

Un modèle discret du couplage entre les fils dans une structure tisséeA discrete model for the coupling between the yarns in a woven fabric

The coupling between yarns in a piece of fabric has been analysed at the mesoscopic scale, in terms of its impact on the macroscopic unidirectional behaviour. Starting from a discrete model of a woven structure associated to a variational formulation of the equilibrium of the structure, the coupling between both yarns is introduced, the potential energy of which is calculated. The initial shape of the yarn, represented by a planar undulated beam supposed to be periodic, is described by a Fourier series. The coefficients of the series are expressed vs. the contact force exerted at the top of the undulations, and vs. the mechanical properties of the solicited yarn. The contact force is then expressed vs. the mechanical properties of the transverse yarn and vs. the vertical displacement of the contact point. The potential energy of the coupling is then built, assuming the continuity of the displacement at the contact points. The equilibrium shape of the yarn submitted to unidirectional traction is obtained numerically as the minimum of the total potential energy. The simulated traction curve reproduces in a satisfactorily manner the observed behaviour. The respective contributions of the flexional and extensional effects of the yarn are analysed. The consideration of the coupling enhances the rigidity of the response of the yarn; one demonstrates the effect of the geometrical and mechanical parameters of the transverse yarn. To cite this article: B. Ben Boubaker et al., C. R. Mecanique 331 (2003).     

A 4D Composite Reinforced along Cube Diagonals with a Small Content of Yarns under Large Tensile Deformations

The deformation behavior of a 4D composite reinforced along cube diagonals under large tensile deformations is examined. The investigation is based on an applied theory which allows one to perform a macromechanical analysis of composite materials with small volume contents of reinforcing yarns with an accuracy sufficient in practice. It is found that, under large deformations, the properties of composites reinforced along cube diagonals differ qualitatively from their properties under small deformations. The evolution of the structural geometry of the deformed composite material is traced.