全文获取类型
收费全文 | 8677篇 |
免费 | 2392篇 |
国内免费 | 634篇 |
专业分类
化学 | 6168篇 |
晶体学 | 37篇 |
力学 | 133篇 |
综合类 | 36篇 |
数学 | 155篇 |
物理学 | 5174篇 |
出版年
2024年 | 40篇 |
2023年 | 133篇 |
2022年 | 382篇 |
2021年 | 417篇 |
2020年 | 565篇 |
2019年 | 443篇 |
2018年 | 386篇 |
2017年 | 408篇 |
2016年 | 685篇 |
2015年 | 649篇 |
2014年 | 952篇 |
2013年 | 913篇 |
2012年 | 781篇 |
2011年 | 686篇 |
2010年 | 495篇 |
2009年 | 522篇 |
2008年 | 500篇 |
2007年 | 519篇 |
2006年 | 367篇 |
2005年 | 314篇 |
2004年 | 266篇 |
2003年 | 205篇 |
2002年 | 144篇 |
2001年 | 121篇 |
2000年 | 126篇 |
1999年 | 103篇 |
1998年 | 83篇 |
1997年 | 81篇 |
1996年 | 89篇 |
1995年 | 54篇 |
1994年 | 44篇 |
1993年 | 28篇 |
1992年 | 30篇 |
1991年 | 29篇 |
1990年 | 24篇 |
1989年 | 22篇 |
1988年 | 21篇 |
1987年 | 19篇 |
1986年 | 8篇 |
1985年 | 14篇 |
1984年 | 16篇 |
1983年 | 3篇 |
1982年 | 12篇 |
1980年 | 2篇 |
1975年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
1.
Synthesis of Small‐Sized,Porous, and Low‐Toxic Magnetite Nanoparticles by Thin POSS Silica Coating 下载免费PDF全文
Dr. Swee Kuan Yen D. Prathyusha Varma Wei Mei Guo Dr. Vincent H. B. Ho Dr. Vimalan Vijayaragavan Dr. Parasuraman Padmanabhan Prof. Kishore Bhakoo Prof. Subramanian Tamil Selvan 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(10):3914-3918
In this communication, we report the synthesis of small‐sized (<10 nm), water‐soluble, magnetic nanoparticles (MNPs) coated with polyhedral oligomeric silsesquioxanes (POSS), which contain either polyethylene glycol (PEG) or octa(tetramethylammonium) (OctaTMA) as functional groups. The POSS‐coated MNPs exhibit superparamagnetic behavior with saturation magnetic moments (51–53 emu g?1) comparable to silica‐coated MNPs. They also provide good colloidal stability at different pH and salt concentrations, and low cytotoxicity to MCF‐7 human breast epithelial cells. The relaxivity data and magnetic resonance (MR) phantom images demonstrate the potential application of these MNPs in bioimaging. 相似文献
2.
Prof. Dr. Frank Glorius 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(22):8047-8051
A general and efficient methodology for the direct transition metal free trifluoromethylthiolation of a broad range of biologically relevant N‐heteroarenes is reported employing abundant sodium chloride as the catalyst. This method is operationally simple, exhibits high functional group tolerance, and does not require protecting groups. 相似文献
3.
4.
通过分析计算,设计了一种大口径宽视场折射式红外相机光学系统。该系统设计用于超长线阵扫描红外相机的地面演示成像,它能同时对短波2μm—3μm、中波3μm—4.5μm双波段成像,且同时具有24°的大视场和150mm的宽口径,成像质量接近衍射极限。该系统在航天遥感领域应用广泛。 相似文献
5.
K. Dayananda R. Dhamodharan K. Vijayakumaran T. Rajamannar 《Journal of polymer science. Part A, Polymer chemistry》2004,42(21):5413-5423
A monolayer of covalently anchored, novel, binaphthyl ketone is used as a surface‐confined photochemical radical generator (PRG) for anchoring a variety of polymers to silicon surfaces. The precursor PRG is synthesized by the application of a facile and novel method for the oxidation of sterically hindered benzylic hydrocarbons to carbonyl compounds. Oxidation was carried out with a stoichiometric amount of potassium peroxydisulfate, in the presence of a catalytic amount of copper sulfate in an acetonitrile/water mixture. The PRG synthesized is characterized by 1H NMR, UV, and Fourier transform infrared (FTIR). The covalently attached monolayers are characterized by X‐ray photoelectron spectroscopy, ellipsometry, and water contact angle measurements. The method developed is applicable to the preparation of a monolayer of a variety of polymers on a wide range of substrates carrying surface hydroxyl groups. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5413–5423, 2004 相似文献
6.
Vadim G. Kessler 《Journal of Sol-Gel Science and Technology》2004,32(1-3):11-17
The article describes the principles of the Single Source Precursor approach to inorganic materials and introduces the Geometrical Molecular Structure Design Concept (MSDC) based on the choice of a proper molecular structure type for the desired precursor and completing it with ligands providing both the necessary number of donor atoms and the sterical protection of the chosen core. Application of MSDC is illustrated with examples taken from development of new approaches in the synthesis of oxide and sulfide catalysts and ferroelectric oxide materials. 相似文献
7.
8.
Wolfgang Kirmse 《Angewandte Chemie (International ed. in English)》1997,36(11):1164-1170
Alkenylidenes R2C?C: (= alkylidene carbenes) undergo regio- and stereoselective intramolecular C? H insertion reactions that are excellently suited for the synthesis of cyclopentenes. The 1, 2-shifts occurring with R?H and R?Ar are useful for the preparation of alkynes. Alkenylidenes are efficiently generated from carbonyl compounds by diazomethylation, from vinyl halides by α-elimination, from alkynyliodonium salts by addition of nucleophiles, and from alkynes by retro-1, 2-shifts. Specific applications of the various methods, particularly in the synthesis of natural products, are discussed. 相似文献
9.
10.
Recently, molecular imaging has been rapidly developed to studyphysiological and pathological processes in vivo at the cellularand molecular levels. Among molecular imaging modalities, opticalimaging has attracted a major attention for its unique advantages.In this paper, we establish a mathematical framework for multispectralbioluminescence tomography (BLT) that allows simultaneous studiesof multiple optical reporters. We show solution existence, uniquenessand continuous dependence on data as well as the limiting behaviourswhen the regularization parameter approaches zero or when thepenalty parameter approaches infinity. Then, we propose twonumerical schemes for multispectral BLT and derive error estimatesfor the corresponding solutions. 相似文献