Dioxane Dibromide–Mediated Solvent‐Free Synthesis of Vicinal Dibromides

Structurally varied vicinal dibromides have been synthesized in high yield and good purity through highly stereoselective anti‐addition of bromine across the olefinic linkages using dioxane dibromide (DD) under solvent‐free conditions.     

主被动光学图像融合技术研究

本文应用扫描式激光成像雷达获取试验数据并实现对激光数据的三维成像处理,给出了基于目标特征的激光雷达图像与被动光学图像的数据融合方法,实现了激光图像和光学图像间的三维融合。试验结果表明,本文所提出的基于目标特征的两种不同质图像间的融合方法是可行的,融合后的图像具有丰富的光谱信息和三维立体信息。     

Morphology and mechanical behavior of isotactic polypropylene with different stereo‐defect distribution in injection molding

Large amount of work has been published on the isotacticity–properties relationship of isotactic polypropylene (iPP). However, the stereo‐defect distribution dependence of morphology and mechanical properties of iPP injection molding samples is still not clear. In this study, two different isotactic polypropylene (iPP) resins (PP‐A and PP‐B) with similar average isotacticity but different stereo‐defect distribution were selected to investigate the morphology evolution and mechanical properties (tensile and notching) of their injection molding samples using differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), 2D wide angle X‐ray diffraction (2D‐WAXD), and scanning electron microscope (SEM). The results of DMA showed that the molecular movement ability of PP‐A (with less uniform distribution of stereo‐defect) was stronger than that of PP‐B, meanwhile the analysis of DSC and SEM suggested that after injection molding, smaller spherullites, and crystals with higher perfection had formed in the specimens of PP‐A. The resulting of tensile properties of PP‐A were found to be better than that of PP‐B. The results of morphology evolution by SEM observation and 2D‐WAXD showed that PP‐A is more likely to occur interspherulite deformation and can disperse the tensile stress more efficiently, and therefore, its crystal structure can withstand a greater force when tensile stress is applied. On the other hand, PP‐B has larger spherulites and boundaries, and low perfection of lamellaes, and the intraspherulte deformation tend to take place. It is easier for the crystal of PP‐B to be broken up and reoriented along the tensile direction. Copyright © 2014 John Wiley & Sons, Ltd.     

基于感知的右视点质量可分级编码算法

为了减少立体视频传输如此庞大的数据量,根据人眼的立体掩蔽效应,提出了基于感知的右视点质量可分级编码算法．该算法将宏块分为3类：平坦块、纹理块和边缘块,通过不同的量化步长使得右视点图像块的质量可分级．实验证明根据左视点的图像质量,右视点在人眼感知范围内码率减少25％～37％．该算法能在人眼主观察觉范围内很好地提高码率,进一步消除人眼立体视觉冗余．     

计算机辅助彩色立体图像生成中的误差分析与处理

柱透镜光栅的计算机辅助立体成像的基本原理是将二维序列图像进行切分和重组,使之以三维模型的形式展现,使合成的图像在柱透镜光栅下观察时具有"纵深感"。该项技术在广告、摄影、电影制作中具有广泛的应用。但是长期以来,在图像切分时并不能保证像素一定被整除,这意味着剩余像素的出现,合成的立体图像必然存在误差。如何处理剩余像素的问题一直是个难题,阻碍了该技术的推广。针对立体图像生成方法中的剩余像素问题,详尽地分析了误差的形成,并提出了强行取整算法和误差分散算法两种误差处理方法。实验表明,这两种算法能较好的处理剩余像素,增强了合成图像的立体效果,这将有助于立体成像技术的进一步推广。     

Different responses of E:Z‐isomers of pesticides in liquid chromatography–electrospray ionization–mass spectrometry

The mass spectrometric behavior of four pairs of stereoisomers was investigated by liquid chromatography–electrospray ionization–mass spectrometry (LC–ESI–MS). The E‐ and Z‐isomers of the pesticides chlorfenvinphos, dimethomorph, mevinphos and phosphamidon—each with one double bond—were chosen for this study. The MS response of the individual isomers was investigated by infusing the isomers individually into the MS or after the separation of isomer mixtures via high‐performance liquid chromatography(HPLC). In the case of dimethomorph, the same MS response was found for the two isomers. In contrast to that, the individual isomers of chlorfenvinphos, mevinphos and phosphamidon showed different MS response both in the single ion monitoring (SIM) mode in single quadrupole MS and multiple reaction monitoring (MRM) mode in tandem MS. The MS response of the isomers partly depends on (1) the declustering potential of the precursor ion in the SIM mode, (2) the selected transition and (3) the collision energy in the MRM mode. Consequently, quantification by summation of the peak areas of the isomers is inaccurate due to over‐ or underestimating of one of the stereoisomers. Accurate quantitative results can only be achieved when the compound‐specific MS parameters are separately determined for each isomer. This can be done by using pure isomers or by the determination of the MS parameters after HPLC separation and the measurement of the actual isomer ratio with an independent technique. Copyright © 2010 John Wiley & Sons, Ltd.     

基于特征面片的复杂型面轮廓视觉测量方法

提出一种基于特征面片的复杂型面轮廓三维视觉测量方法.该方法包括多模式局部特征检测与匹配、特征面片集初始化、膨胀、滤波等重构过程,其输入是已标定的立体图像,输出是覆盖表面的可视稠密面片集.该方法不需要目标和场景的任何初始边界信息,能够自动检测和抛弃外部点和缺失部分;不需要对邻域特征进行任何平滑处理,仅需通过局部单演特征一...     

遥感中的立体成像技术

阐述了用于空间对地观测的立体成像的基本原理，讨论了三种立体成像方法，研制成功了用于机载的三个ＣＣＤ线阵扫描的立体成像系统。完成了实验室立体成像实验，编制了形成立体图所必需的软件，得到了预期的地面三维图像。     

An analysis of SEM techniques used to profile chemical etching on the semiconductor Hg1-xCdxTe

Various methods have been used to obtain accurate cross-sectional profiles of Hg_1-xCd_xTe devices after etching. Preliminary measurements from different etching techniques are also presented. Techniques used were scanning electron microscopy with stereo pairs and cleaved cross-sections, topography SEM (multiple detector SEM) and atomic force microscopy.