Synthesis and mesomorphic properties of novel fishbone-like liquid crystalline polysilsesquioxanes VI. Fishbone-like,ester-based liquid crystalline polysilsesquioxanes

Two novel kinds of fishbone-like, ester-based, liquid crystalline, random copolysilsesquioxanes, LC₁-CH₃-P and LC₂-CH₃-P, have been synthesized for the first time by stepwise coupling polymerization (SCP) from trichlorosilane monomers (RSiCl₃) containing mesogenic ester groups, using three main steps including preaminolysis, hydrolysis and polycondensation. Two new monomers 4-(11-trichlorosilylundecloyloxy)phenyl 4-methoxybenzoate (M₁) and 4-(3-trichlorosilylpropoxy)phenyl 4-methoxybenzoate (M₂) have been synthesized by hydrosilylation reaction of trichlorosilane and the mesogens 4-n-undecenoyloxyphenyl 4-methoxybenzoate and 4-allyloxyphenyl 4-methoxy-benzoate, respectively, in the presence of dicyclopentadienylplatinum(II) chloride (Cp₂Ptcl₂) catalyst. The structures and mesomorphic properties of LC₁-CH₃-P and LC₂-CH₃-P were investigated by FTIR, ¹H NMR, ¹³C NMR, ²⁹Si NMR, gel permeation chromatography, polarizing optical microscopy, differential scanning calorimetry and X-ray diffraction. It is proposed from the characterization data that these two polymers not only have an ordered ladder-like, double main chain, but also show thermotropic smectic behaviour with high clearing points and wide mesophase ranges (ΔT), which may hold promise for potential applications as highly stable gas chromatographic stationary phases.     

连续光条件下对LiNbO3∶Fe∶Mn晶体全息存储性能的理论研究

以双中心模型为基础,在低光强连续光条件下研究了LiNbO3∶Fe∶Mn晶体在稳态情况下的非挥发双光双步全息存储性能。采用数值方法,通过比较双中心模型中深(Mn2+/Mn3+)、浅(Fe2+/Fe3+)能级之间所有可能的电子交换过程,发现由隧穿效应引起的深浅能级之间直接电子交换过程对LiNbO3∶Fe∶Mn晶体总的空间电荷场大小起着决定性的作用。同时,这一电子交换过程对晶体非挥发全息存储性能也起着至关重要的作用。此外,通过相同实验条件下LiNbO3∶Fe∶Mn晶体与近化学比LiNbO3∶Fe晶体总的空间电荷场的比较,显示LiNbO3∶Fe∶Mn晶体在低抽运光和高记录光光强条件下有着比近化学比LiNbO3∶Fe晶体更佳的全息存储性能。     

直线加速器中的非线性空间电荷效应和发射度增长

直线加速器中束团的非线性空间电荷效应是引起发射度增长的重要原因之一．根据计算在屏蔽筒中非均匀分布京团的空间电荷效应的普遍方法，推导了直线加速器圆波导中几种非均匀分布束团的非线性场能公式，并给出数值计算结果．讨论了由非线性所引起发射度增长．     

相对论磁控管中自磁场的影响

针对相对论磁控管中自磁场的产生与分布、自磁场对电子运动的影响以及自磁场对互作用的影响进行了深入分析。分析认为,由于自磁场分布的不对称,自磁场对不同区域电子束的作用不同。加速器一侧的电子束受到更明显的自磁场作用,促使此区域的电子束角向速度增加,直接激化模式竞争。同时,如果阴极比较靠近加速器一侧的1/4区域(距磁控管对称中心大约1/4高度),模式竞争将进一步被激化。     

Photocurrent analysis of organic photovoltaic cells based on CuPc/C60 with Alq3 as a buffer layer

The performance of an organic photovoltaic(OPV) cell based on copper phthalocyanine CuPc/C60 with a tris(8-hydroxyquinolinato) aluminum(Alq3) buffer layer has been investigated.It was found that the power conversion efficiency of the device was 1.51% under illumination with an intensity of 100 mW/cm2,which was limited by a squareroot dependence of the photocurrent on voltage.The photocurrent-optical power density characteristics showed that the OPV cell had a significant space-charge limited photocurrent with a varied saturation voltage and a three quarters power dependence on optical power density.Also,the absorption spectrum was measured by a spectrophotometer,and the results showed that the additional Alq3 layer has a minor effect on photocurrent generation.     

Exciton reflection of ZnSe single crystals with account for the effect of the surface electric field

The mechanism of formation of an exciton reflection band is analyzed using a multilayer model of the near-surface region of ZnSe single crystals. It is shown that the appearance of a fine structure (a spike) in the reflection spectra at large damping parameters of the exciton is due to the surface electric field and the Stark exciton effect. The exciton-resonance energies and the damping parameters of free excitons for temperatures ranging from 12 to 100 K are determined by comparing experimental and predicted contours of the reflection spectrum. The surface concentration of charged centers and the characteristics of the space-charge region are evaluated within the framework of the model employed. Brest Polytechnic Institute, 267, Moskovskaya Str., Brest, 224017, Belarus. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 66, No. 3, pp. 401–407, May–June, 1999.     

箔聚焦强流相对论环形束在同轴波导中的传输

 结合箔聚焦和静电线聚焦的特点,对箔聚焦强流相对论环形电子束在同轴波导中的传输进行了研究。通过数值求解电势满足的泊松方程,得到电势、电场分布及系统的空间电荷限制流,并根据电子的运动方程得到包络电子的平衡条件及其运动轨迹。     

带状电子束的空间电荷场

 利用理论分析和数值计算的方法研究了矩形波导内均匀电流密度的带状电子束模型的空间电荷场,给出了该带状电子束模型的空间电荷场的解析表达式,并研究了空间电荷场随带状电子束的几何参数和物理参数的变化规律。研究表明：在不改变电流密度的前提下,更宽的电子束可以传输更强的束流,而空间电荷场并不随束宽度的增大而增大,但是增加电子束厚度会使空间电荷场显著增强,从而不利于高流强电子束的传输;对于相同电流的带状电子束,保持电子束厚度不变,增大电子束宽度,相应地降低电流密度是降低空间电荷场的一个很好的途径,而保持电子束的宽度不变,增大束厚度,相应地降低电流密度只会使沿着电子束截面宽度方向的电场减小,而沿着电子束截面厚度方向的电场基本不变;对于相同电流和电流密度的带状电子束,更宽、更薄的电子束横截面尺寸能使沿着电子束截面宽度方向的电场降到更低,而沿着电子束截面厚度方向的电场只是略有减小。     

A three-dimensional time-dependent theory for helix traveling wave tubes in beam-wave interaction

This paper presents a three-dimensional time-dependent nonlinear theory of helix traveling wave tubes for beamwave interaction.The radio frequency electromagnetic fields are represented as the superposition of azimuthally symmetric waves in a vacuum sheath helix.Coupling impedance is introduced to the electromagnetic field equations’ stimulating sources,which makes the theory easier and more flexible to realize.The space charge fields are calculated by electron beam space-charge waves expressed as the superposition solutions of Helmholtz equations.The focusing forces due to either a solenoidal field or a periodic permanent magnetic field is also included.The dynamical equations of electrons are Lorentz equations associating with electromagnetic fields,focusing fields and space-charge fields.The numerically simulated results of a tube are presented.     

Improved method for studying the propagation dynamics of ultrafast electron pulses based on mean-field models

We have studied the propagation dynamics of ultrafast electron pulses by using an improved mean-field model, in which the propagation of the electron pulses across the boundary of the acceleration region is explicitly considered. A large decrease in the speed spread of the electron pulses(we called "boundary kick") is observed and properly treated leading to a significant improvement in the simulation accuracy, particularly when the density of electrons is very large. We show that our method is consistent with the simulation by the N-particle method, while others can introduce factorial error.