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利用向环金属配体的C-Ir键的对位进行苯基取代这一结构修饰策略,成功合成了两种新型铱(III)配合物(3PhNbt)2Ir(acac)和(3OMePhNbt)2Ir(acac).相较其橙光发射的母体化合物(Nbt)2Ir(acac),两个目标化合物的抗结晶性、非晶态热稳定性及溶解性均有显著提高,其磷光发射带也发生了5~10 nm的红移.以(3PhNbt)2Ir(acac)和(3OMePhNbt)2Ir(acac)为发光客体材料所制备的单层溶液加工电致红光器件,其最大发光亮度分别为1830 cd·m-2和6630 cd·m-2,最大电流效率分别为2.4 cd·A-1和8.7 cd·A-1,CIE1931色坐标分别为(0.61,0.39)和(0.62,0.38).相比之下,以母体化合物(Nbt)2Ir(acac)为发光客体材料所制备的参比器件,其最大发光亮度则为1620 cd·m-2,最大电流效率仅为1.5 cd·A-1,CIE1931色坐标为(0.59,0.41).上述研究结果表明:向C-Ir键对位进行苯基修饰可以在提高铱(III)配合物的可溶液加工性能的同时,获得更为红移的电致发光波长,是一种简单而有效的红光铱(III)配合物的分子设计策略. 相似文献
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Photovoltaic performance of the organic solar cells(OSCs)based on 2-((5′-(4-((4-((E)-2-(5′-(2,2-dicyanovinyl)-3′,4-dihexyl-2,2′-bithiophen-5-yl)vinyl)phenyl)(phenyl)amino)styryl)-4,4′-dihexyl-2,2′-bithiophen-5-yl)methylene)malononitrile(L(TPAbTV-DCN))as donor and PC70BM as acceptor was optimized using 0.25 vol%high boiling point solvent additive of1-chloronaphthalene(CN),1,6-hexanedithiol(HDT),or 1,8-diodooctane(DIO).The optimized OSC based on L(TPA-bTVDCN)–PC70BM(1:2,w/w)with 0.25 vol%CN exhibits an enhanced power conversion efficiency(PCE)of 2.61%,with Voc of0.87 V,Jsc of 6.95 mA/cm2,and FF of 43.2%,under the illumination of 100 mW/cm2 AM 1.5 G simulated solar light,whereas the PCE of the OSC based on the same active layer without additive is only 1.79%.The effect of the additive on absorption spectra and the atomic force microscopy images of L(TPA-bTV-DCN)–PC70BM blend films were further investigated.The improved efficiency of the device could be ascribed to the enhanced absorption and optimized domain size in the L(TPA-bTV-DCN)–PC70BM blend film. 相似文献
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Junyi Li Neeta Karjule Jiani Qin Ying Wang Jesús Barrio Menny Shalom 《Molecules (Basel, Switzerland)》2021,26(6)
Carbon nitride materials require high temperatures (>500 °C) for their preparation, which entails substantial energy consumption. Furthermore, the high reaction temperature limits the materials’ processability and the control over their elemental composition. Therefore, alternative synthetic pathways that operate under milder conditions are still very much sought after. In this work, we prepared semiconductive carbon nitride (CN) polymers at low temperatures (300 °C) by carrying out the thermal condensation of triaminopyrimidine and acetoguanamine under a N2 atmosphere. These molecules are isomers: they display the same chemical formula but a different spatial distribution of their elements. X-ray photoelectron spectroscopy (XPS) experiments and electrochemical and photophysical characterization confirm that the initial spatial organization strongly determines the chemical composition and electronic structure of the materials, which, thanks to the preservation of functional groups in their surface, display excellent processability in liquid media. 相似文献
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