首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   673篇
  免费   102篇
  国内免费   85篇
化学   450篇
晶体学   34篇
力学   44篇
综合类   12篇
数学   45篇
物理学   275篇
  2023年   4篇
  2022年   19篇
  2021年   20篇
  2020年   17篇
  2019年   13篇
  2018年   16篇
  2017年   24篇
  2016年   31篇
  2015年   21篇
  2014年   32篇
  2013年   66篇
  2012年   30篇
  2011年   58篇
  2010年   33篇
  2009年   41篇
  2008年   39篇
  2007年   43篇
  2006年   42篇
  2005年   33篇
  2004年   39篇
  2003年   26篇
  2002年   17篇
  2001年   31篇
  2000年   29篇
  1999年   21篇
  1998年   15篇
  1997年   18篇
  1996年   14篇
  1995年   18篇
  1994年   15篇
  1993年   5篇
  1992年   12篇
  1991年   10篇
  1989年   2篇
  1988年   2篇
  1984年   1篇
  1982年   3篇
排序方式: 共有860条查询结果,搜索用时 15 毫秒
1.
舒兴明 《大学数学》2002,18(3):44-47
本文利用局部比较法 ,在图中定义子图、无效路径、以及可去边 .利用推导的有关定理 ,拆去可去边 ,利用最短路径相同的等价性 ,达到化简图 ,从而求出最短路径  相似文献   
2.
The longitudinal relaxation times (T1) of water in concentrated silica and alumina slurries were measured as a function of solids content. It was shown that the results could be fit very well with a two-phase fast-exchange model between free and surface-bound water. As expected, values of T1 for bound water were in the order of 20–2000 times lower than that for free water, indicating a higher effective viscosity of the surface-bound water. The strength of the interaction depended on the particular surface, and all of the aluminas examined interacted more strongly with water than the two silicas studied, which themselves differed considerably. The chemical mechanical polishing (CMP) removal rate of tantalum by silica slurries was shown to be directly correlated with the interaction parameters, derived from the NMR relation times rather than with total surface hydroxyl group concentration.  相似文献   
3.
The onset of liquid entrainment during discharge from large reservoirs containing a stratified mixture of two immiscible fluids through a side slot of a finite width is considered theoretically. A previously reported analysis in which the slot was approximated as a two-dimensional line sink has been extended to account for the finite width of the slot. The model resulting from the present analysis is expressed in terms of two simple algebraic equations suitable for hand calculations. According to the present results, the ratio of the critical height to the slot width is dependent only on the Froude number. Numerical results show that the present model approaches the correct physical limits at low Froude numbers and it converges to the predictions of the previously reported simple model at high Froude numbers.  相似文献   
4.
二极管激光侧泵浦单横模100Hz电光调Q激光器   总被引:3,自引:0,他引:3  
王卫民  吕百达 《光学学报》1997,17(10):403-1406
介绍了二极管激光侧泵浦单横模100Hz电光调Q激光器的实验结果。泵浦源为一个线阵准连续100W二极管激光器,激光工作介质为NdYAG薄梯形板条,板条与泵浦源间用柱透镜耦合,KD*P电光晶体调Q。在100Hz重复频率下,获得单脉冲能量2.37mJ,脉宽小于7ns,光束质量因子M2=1.1的1.06μm激光,光-光效率为8.5%,斜效率为18.7%。  相似文献   
5.
Poly(monoitaconates) containing octyl, decyl and dodecyl groups and random monoalkylitaconate-co-vinylpyrrolidone copolymers were studied by thermogravimetric analysis. Copolymers of mono-n-octylitaconate (MOI), mono-n-decylitaconate (MDI), and mono-n-dodecylitaconate (MDoI), respectively, with N-vinyl-2-pyrrolidone (VP) of different compositions were studied by dynamic thermogravimetric analysis. The thermal stability of the copolymers depends on the structure of the monoitaconate comonomer and on the composition of the copolymer The kinetic analysis of the degradation data shows that the thermal decomposition of these copolymers can be described by several kinetic orders depending on the copolymer and on the composition. The relative thermal stability of the copolymers increases as the VP content increases and as the length of the side chain of the itaconate increases, following the same trend as the flexibility of the copolymers in solution.  相似文献   
6.
Hindered rotation was considered in calculations of the conformational parameters of a series of polyheteroarylenes with bulky side substituents by the Monte-Carlo method. Within the range of experimental errors, the results of calculations for several polyarylates coincide with the values of conformational rigidity, determined from hydrodynamic experimental data. The proposed procedure was used to estimate the rigidities of a number of polymers with bulky side substuents for which experimental determination is difficult. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1287–1296, July, 1998.  相似文献   
7.
Magnetic field-induced orientation of a chiral side chain liquid crystalline polyacrylate(P-11) was studied by using IR dichroism. For the investigated P-11, it has been shown thatthe magnetic alignment takes place over the entire temperature range between its meltingpoint and clearing point and the orientation level is strongly temperature-dependent, thedevelopment with time of the magnetic orieatation follows an exponeotial-type relation,and the smectic phase state influences the thermal relaxation process in the absence of themagnetic field.  相似文献   
8.
已发现的天然甾醇均为20R 构型。近年来在地质体中发现了具有20S 构型的甾烷类生物标志化合物,并称之为地质构型。合成20S 构型的甾烷的方法之一是由20S 构型的甾醇为原料。20S-胆甾醇及20S-胆甾烷的合成已有报道,但24ξ-甲基-20S-  相似文献   
9.
杨春才  赵晓光 《应用化学》1992,9(5):116-119
侧链液晶聚合物的合成方法,可归纳为3类:一是烯基的单体,如甲基丙烯酸酯,或丙烯酸酯,氯代丙烯酸酯等,经自由基聚合反应,阴离子聚合反应及甲基丙烯酸酯的基团转移聚合反应,得到侧链液晶聚合物;二是变性反应,如聚硅氧烷与丙烯酸酯介  相似文献   
10.
水合醋酸铈直接热分解制备超细氧化铈及其抛光性能   总被引:3,自引:0,他引:3  
Ultra fine ceria was prepared by calcining hydrate cerium acetate. The effects of pyrolysis temperature on the particle size, morphology, specific surface area and loose packing density of ceria were investigated, and the removal rate of optical glasses polishing by ceria was determined. The results show that with the increase of pyrolysis temperature, the loose deposit density and crystallinity increases and the specific surface area decreases, however, the particle size decreases firstly and then increases, the minimum medium particle size D50 is 0.47 μm at pyrolysis temperature of 1 000 ℃. The SEM images of ceria prepared by the decomposition at 800 ℃ or at 1 100 ℃ show porous powders or quasi-sphere small particles with loosely agglomeration, respectively. It was found that the removal rate varied with pyrolysis temperature in preparation of ceria and the property of glass polished. The removal rate for three kinds of glasses was in the order of ZF7> F1> K9, and the maximum value appeared at around 1 000 ℃ for ZF7 and F1, and at around 1 100 ℃ for K9.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号