全文获取类型
收费全文 | 1786篇 |
免费 | 226篇 |
国内免费 | 165篇 |
专业分类
化学 | 527篇 |
晶体学 | 5篇 |
力学 | 214篇 |
综合类 | 37篇 |
数学 | 657篇 |
物理学 | 737篇 |
出版年
2024年 | 3篇 |
2023年 | 22篇 |
2022年 | 41篇 |
2021年 | 41篇 |
2020年 | 45篇 |
2019年 | 47篇 |
2018年 | 43篇 |
2017年 | 56篇 |
2016年 | 45篇 |
2015年 | 49篇 |
2014年 | 86篇 |
2013年 | 137篇 |
2012年 | 112篇 |
2011年 | 108篇 |
2010年 | 88篇 |
2009年 | 96篇 |
2008年 | 84篇 |
2007年 | 113篇 |
2006年 | 96篇 |
2005年 | 95篇 |
2004年 | 74篇 |
2003年 | 90篇 |
2002年 | 85篇 |
2001年 | 57篇 |
2000年 | 62篇 |
1999年 | 65篇 |
1998年 | 49篇 |
1997年 | 49篇 |
1996年 | 35篇 |
1995年 | 30篇 |
1994年 | 29篇 |
1993年 | 21篇 |
1992年 | 21篇 |
1991年 | 20篇 |
1990年 | 7篇 |
1989年 | 13篇 |
1988年 | 9篇 |
1987年 | 10篇 |
1986年 | 9篇 |
1985年 | 5篇 |
1983年 | 3篇 |
1982年 | 7篇 |
1981年 | 5篇 |
1980年 | 3篇 |
1979年 | 5篇 |
1978年 | 2篇 |
1976年 | 1篇 |
1974年 | 2篇 |
1973年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有2177条查询结果,搜索用时 15 毫秒
1.
The biodegradability of phtalic acid esters in marine and freshwater environments was characterized by their binding free energy with corresponding degrading enzymes. According to comprehensive biodegradation effects weights, the binding free energy values were converted into dimensionless efficacy coefficient using ratio normalization method. Then, considering comprehensive dual biodegradation effects value and the structural parameters of PAEs in both marine and freshwater environments, a 3D-QSAR pharmacophore model was constructed, five PAE derivatives (DBP−COOH, DBP−CHO, DBP−OH, DINP−NH2, and DINP−NO2) were screened out based on their environmental friendliness, functionality and stability. The prediction of biodegradation effects on five PAE derivatives by biodegradation models in marine and freshwater environment increased by 15.90 %, 15.84 %, 27.21 %, 12.33 %, and 8.32 %, and 21.57 %, 15.21 %, 20.99 %, 15.10 %, and 9.74 %, respectively. By simulating the photodegradation path of the PAE derivative molecular, it was found that DBP−OH can generate .OH and provides free radicals for the photodegradation of microplastics in the environment. 相似文献
2.
3.
4.
R. J. Saykally K. M. Evenson D. A. Jennings L. R. Zink A. Scalabrin 《International Journal of Infrared and Millimeter Waves》1987,8(6):653-662
Twenty new cw FIR laser lines in CD3OH, optically pumped by a CO2 laser, are reported. The frequencies of 39 of the stronger laser lines were measured relative to stabilized CO2 lasers with a fractional uncertainty, as determined by the reproducibility of the FIR frequency itself, of 2 parts in 107.Contribution of the U.S. Government, not subject to copyright. 相似文献
5.
A one-dimensional bulk reaction model for the oxidation of nickeltitanium is formulated, with preferential oxidation of titaniumbeing included. The modelling is directed at the better understandingof the dominant mechanisms involved in the oxidation processand their significance for the biocompatibility of the alloy.Two different regimes for the relative diffusivities of oxygenand the metals are investigated. By assuming fast bulk reactions,different asymptotic structures emerge in different parameterregimes and the resulting models take the form of moving boundaryproblems. Different profiles of nickel concentration are obtained:in particular a nickel-rich layer (observed in practice) ispresent below the oxide/metal interface for the case when oxygenand the metals diffuse at comparable rates. 相似文献
6.
We investigate the effects of adding uniformity requirements to concepts in computable structure theory such as computable categoricity (of a structure) and intrinsic computability (of a relation on a computable structure). We consider and compare two different notions of uniformity, previously studied by Kudinov and by Ventsov. We discuss some of their results and establish new ones, while also exploring the connections with the relative computable structure theory of Ash, Knight, Manasse, and Slaman and Chisholm and with previous work of Ash, Knight, and Slaman on uniformity in a general computable structure-theoretical setting. 相似文献
7.
8.
We investigate a new interpretation for the Navier-Stokes corrections to the hydrodynamic equation of asymmetric interacting particle systems. We consider a system that starts from a measure associated with a profile that is constant along the drift direction. We show that under diffusive scaling the macroscopic behavior of the process is described by a nonlinear parabolic equation whose diffusion coefficient coincides with the diffusion coefficient of the hydrodynamic equation of the symmetric version of the process. 相似文献
9.
For approximate wave functions, we prove the theorem that there is a one‐to‐one correspondence between the constraints of normalization and of the Fermi–Coulomb and Coulomb hole charge sum rules at each electron position. This correspondence is surprising in light of the fact that normalization depends on the probability of finding an electron at some position. In contrast, the Fermi–Coulomb hole sum rule depends on the probability of two electrons staying apart because of correlations due to the Pauli exclusion principle and Coulomb repulsion, while the Coulomb hole sum rule depends on Coulomb repulsion. We demonstrate the theorem for the ground state of the He atom by the use of two different approximate wave functions that are functionals rather than functions. The first of these wave function functionals is constructed to satisfy the constraint of normalization, and the second that of the Coulomb hole sum rule for each electron position. Each is then shown to satisfy the other corresponding sum rule. The significance of the theorem for the construction of approximate “exchange‐correlation” and “correlation” energy functionals of density functional theory is also discussed. © 2006 Wiley Periodicals, Inc. Int J Quantum Chem, 2007 相似文献
10.
利用关于乘积分布密度的相对熵和相对熵率的概念,建立了相依连续型随机变量序列关于参考微分熵的一类强偏差定理,证明中给出了将Laplace变换应用于微分熵强偏差定理的研究的一种途径. 相似文献