全文获取类型
收费全文 | 885篇 |
免费 | 196篇 |
国内免费 | 112篇 |
专业分类
化学 | 407篇 |
晶体学 | 6篇 |
力学 | 119篇 |
综合类 | 12篇 |
数学 | 234篇 |
物理学 | 415篇 |
出版年
2024年 | 4篇 |
2023年 | 20篇 |
2022年 | 33篇 |
2021年 | 34篇 |
2020年 | 62篇 |
2019年 | 44篇 |
2018年 | 40篇 |
2017年 | 69篇 |
2016年 | 56篇 |
2015年 | 37篇 |
2014年 | 44篇 |
2013年 | 70篇 |
2012年 | 47篇 |
2011年 | 55篇 |
2010年 | 45篇 |
2009年 | 46篇 |
2008年 | 45篇 |
2007年 | 47篇 |
2006年 | 46篇 |
2005年 | 41篇 |
2004年 | 31篇 |
2003年 | 22篇 |
2002年 | 39篇 |
2001年 | 35篇 |
2000年 | 23篇 |
1999年 | 23篇 |
1998年 | 28篇 |
1997年 | 19篇 |
1996年 | 13篇 |
1995年 | 8篇 |
1994年 | 8篇 |
1993年 | 9篇 |
1992年 | 7篇 |
1991年 | 2篇 |
1990年 | 8篇 |
1989年 | 3篇 |
1988年 | 3篇 |
1987年 | 6篇 |
1986年 | 5篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1979年 | 3篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1973年 | 1篇 |
1971年 | 1篇 |
排序方式: 共有1193条查询结果,搜索用时 62 毫秒
1.
以氧化石墨烯(GO)为原料, 利用温和方法制备了3种不同还原程度的部分还原氧化石墨烯pRGO1, pRGO2和pRGO3(pRGO1—3); 利用傅里叶变换红外光谱(FTIR)、 拉曼光谱(Raman)、 X 射线光电子能谱(XPS)、 紫外-可见光谱(UV-Vis)、 透射电子显微镜(TEM)和 EDS能谱对其结构和形貌进行了表征. 细胞实验结果表明, 无激光照射下pRGO1—3本身的细胞毒性较低; 近红外(NIR)激光照射下pRGO1—3通过光热和光毒性双重作用杀伤肿瘤细胞. 实验结果显示了pRGO 在肿瘤光热疗法和光动力疗法领域的应用潜力. 相似文献
2.
Edward G. Sheetz Zhao Zhang Alyssa Marogil Minwei Che Dr. Maren Pink Dr. Veronica Carta Prof. Dr. Krishnan Raghavachari Prof. Dr. Amar H. Flood 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(60):e202201584
The recognition of boron compounds is well developed as boronic acids but untapped as organotrifluoroborate anions (R−BF3−). We are exploring the development of these and other designer anions as anion-recognition motifs by considering them as substituted versions of the parent inorganic ion. To this end, we demonstrate strong and reliable binding of organic trifluoroborates, R−BF3−, by cyanostar macrocycles that are size-complementary to the inorganic BF4− progenitors. We find that recognition is modulated by the substituent's sterics and that the affinities are retained using the common K+ salts of R−BF3− anions. 相似文献
3.
线性分式规划最优解集的求法 总被引:5,自引:0,他引:5
薛声家 《应用数学与计算数学学报》2002,16(1):90-96
本文使用多面集的表示定理,导出了线性分式规划最优解集的结构,并给出确定全部最优解的计算步骤。 相似文献
4.
V.I. Fernández A. Iucci C.M. Naón 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,30(1):53-56
We present an extension of the Tomonaga-Luttinger model in which left and right-moving particles have different Fermi velocities.
We derive expressions for one-particle Green's functions, momentum-distributions, density of states, charge compressibility
and conductivity as functions of both the velocity difference ε and the strength of the interaction β. This allows us to identify
a novel restricted region in the parameter space in which the system keeps the main features of a Luttinger liquid but with
an unusual behavior of the density of states and the static charge compressibility κ. In particular κ diverges on the boundary
of the restricted region, indicating the occurrence of a phase transition.
Received 20 May 2002 / Received in final form 23 August 2002 Published online 19 November 2002 相似文献
5.
Editorial: Metal-Enhanced Fluorescence 总被引:1,自引:0,他引:1
6.
L. Bartosch P. Kopietz 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,28(1):29-36
We consider the effect of Coulomb interactions on the average density of states (DOS) of disordered low-dimensional metals
for temperatures T and frequencies ω smaller than the inverse elastic life-time 1/τ. Using the fact that long-range Coulomb interactions in two dimensions (2d) generate ln2-singularities in the DOS ν(ω) but only ln-singularities in the conductivity σ(ω), we can re-sum the most singular contributions
to the average DOS via a simple gauge-transformation. If σ(ω) > 0, then a metallic Coulomb gapν(ω) ∝ |ω|/e
4 appears in the DOS at T = 0 for frequencies below a certain crossover frequency Ω
2 which depends on the value of the DC conductivity σ(0). Here, - e is the charge of the electron. Naively adopting the same procedure to calculate the DOS in quasi 1d metals, we find ν(ω) ∝ (|ω|/Ω
1)1/2exp(- Ω
1/|ω|) at T = 0, where Ω
1 is some interaction-dependent frequency scale. However, we argue that in quasi 1d the above gauge-transformation method is on less firm grounds than in 2d. We also discuss the behavior of the DOS at finite temperatures and give numerical results for the expected tunneling conductance
that can be compared with experiments.
Received 28 August 2001 / Received in final form 28 January 2002 Published online 9 July 2002 相似文献
7.
A conclusive teleportation protocol of a d-dimensional two-particle unknown quantum state using three d- dimensional particles in an arbitrary pure state is proposed. A sender teleports the unknown state conclusively to a receiver by using the positive operator valued measure(POVM) and introducing an ancillary qudit to perform the generalized Bell basis measurement, We calculate the optimal teleportation fidelity. We also discuss and analyse the reason why the information on the teleported state is lost in the course of the protocol, 相似文献
8.
J. M. Skowronski 《Annals of Operations Research》1992,37(1):423-437
The Liapunov technique has been introduced in differential games in a sequence of works over the last decade. We discuss application of this technique to the interface between two competitive semi-games, each with different qualitative objective. The feedback information for controllers is provided from designed, analytically integrable state predictors with reduced dynamics, which considerably shortens the computing time. The case is illustrated on the scenario of target reaching before being intercepted, and intercepting before target is reached.Deceased. 相似文献
9.
采用循环伏安法,对SPEPt电极以及SPEAu-Pt电极上还原态CO2的电化学氧化行为研究表明,此类电极的电化学特性与光滑Pt电极一致:CO2在氢原子吸附电位区0~250mV(vs.RHE)处,可与电极上化学吸附的氢反应,生成还原态的CO2,通过线性扫描,还原态CO2即发生一不可逆电化学氧化过程(阳极剥离).在SPEPt系列及SPEAu-Pt系列上CO2的电化学行为表明,当SPEPt系列上Pt的载量为2.5mL的0.01mol·L-1H2PtCl6的Pt时,对还原态CO2的电催化活性最好,当Pt的载量相同时,在SPEAu-Pt上,催化剂对还原态CO2的电化学氧化行为比SPEPt电极更强,这是由于预先沉积的Au对后沉积的Pt有调制作用. 相似文献
10.
陡前沿脉冲产生的受激布里渊散射稳定性研究 总被引:1,自引:1,他引:0
受激布里渊散射转换效率及相位共轭保真度的稳定性与泵浦脉冲的前沿上升时间有关,对前沿上升时间与介质声学声子寿命接近的泵浦脉冲,在泵浦能量超过受激布里渊散射阈值较多时,会造成严重的相位共轭保真度不稳定。本文针对上升前沿时间为2ns的泵浦脉冲及声学声子寿命的1ns和CCl4介质,在泵浦脉冲前沿根部引入缓慢上升的小信号后,采用振放双池受激布里渊散射相位共轭镜,在泵浦激光能量达到500倍受激布里渊散射阈值时 相似文献