全文获取类型
收费全文 | 2226篇 |
免费 | 276篇 |
国内免费 | 193篇 |
专业分类
化学 | 464篇 |
晶体学 | 3篇 |
力学 | 163篇 |
综合类 | 15篇 |
数学 | 1102篇 |
物理学 | 948篇 |
出版年
2024年 | 4篇 |
2023年 | 19篇 |
2022年 | 23篇 |
2021年 | 40篇 |
2020年 | 58篇 |
2019年 | 42篇 |
2018年 | 55篇 |
2017年 | 89篇 |
2016年 | 93篇 |
2015年 | 87篇 |
2014年 | 145篇 |
2013年 | 156篇 |
2012年 | 132篇 |
2011年 | 171篇 |
2010年 | 127篇 |
2009年 | 162篇 |
2008年 | 163篇 |
2007年 | 152篇 |
2006年 | 144篇 |
2005年 | 115篇 |
2004年 | 113篇 |
2003年 | 94篇 |
2002年 | 86篇 |
2001年 | 52篇 |
2000年 | 59篇 |
1999年 | 46篇 |
1998年 | 53篇 |
1997年 | 40篇 |
1996年 | 35篇 |
1995年 | 20篇 |
1994年 | 12篇 |
1993年 | 13篇 |
1992年 | 12篇 |
1991年 | 5篇 |
1990年 | 7篇 |
1989年 | 7篇 |
1988年 | 7篇 |
1987年 | 14篇 |
1986年 | 8篇 |
1985年 | 5篇 |
1984年 | 4篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1978年 | 6篇 |
1977年 | 2篇 |
1976年 | 2篇 |
1973年 | 3篇 |
1972年 | 1篇 |
1936年 | 1篇 |
排序方式: 共有2695条查询结果,搜索用时 296 毫秒
1.
Facile non‐lithographic route to highly aligned silica nanopatterns using unidirectionally aligned polystyrene‐block‐polydimethylsiloxane films
下载免费PDF全文
![点击此处可从《Journal of Polymer Science.Polymer Physics》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Zhe Qiang Maurice L. Wadley Bryan D. Vogt Kevin A. Cavicchi 《Journal of Polymer Science.Polymer Physics》2015,53(15):1058-1064
Thin films (monolayer and bilayer) of cylinder forming polystyrene‐block‐polydimethylsiloxane (PS‐b‐PDMS) were shear aligned by the swelling and deswelling of a crosslinked PDMS pad that was physically adhered to the film during solvent vapor annealing. The nanostructures formed by self‐assembly were exposed to ultraviolet‐ozone to partially oxidize the PDMS, followed by calcination in air at 500 °C. In this process, the PS segments were fully decomposed, while the PDMS yielded silica nanostructures. The highly aligned PDMS cylinders were thus deposited as silica nanolines on the silicon substrate. Using a bilayer film, the center‐to‐center distance of these features were effectively halved from 38 to 19 nm. Similarly, by sequential shear‐alignment of two distinct layers, a rhombic array of silica nanolines was fabricated. This methodology provides a facile route to fabricating complex topographically patterned nanostructures. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 1058–1064 相似文献
2.
An Improved Gradient Projection-based Decomposition Technique for Support Vector Machines 总被引:2,自引:0,他引:2
Luca Zanni 《Computational Management Science》2006,3(2):131-145
In this paper we propose some improvements to a recent decomposition technique for the large quadratic program arising in
training support vector machines. As standard decomposition approaches, the technique we consider is based on the idea to
optimize, at each iteration, a subset of the variables through the solution of a quadratic programming subproblem. The innovative
features of this approach consist in using a very effective gradient projection method for the inner subproblems and a special
rule for selecting the variables to be optimized at each step. These features allow to obtain promising performance by decomposing
the problem into few large subproblems instead of many small subproblems as usually done by other decomposition schemes. We
improve this technique by introducing a new inner solver and a simple strategy for reducing the computational cost of each
iteration. We evaluate the effectiveness of these improvements by solving large-scale benchmark problems and by comparison
with a widely used decomposition package. 相似文献
3.
4.
考虑约束最优化问题:minx∈Ωf(x)其中:f:R^n→R是连续可微函数,Ω是一闭凸集。本文研究了解决此问题的梯度投影方法,在步长的选取时采用了一种新的策略,在较弱的条件下,证明了梯度投影响方法的全局收敛性。 相似文献
5.
6.
《Physica E: Low-dimensional Systems and Nanostructures》2003,16(3-4):568
An inexpensive method to produce a pyramidal-type 2D photonic structures in the silicon substrate was proposed. The method is based on the combination of imprint lithography and wet Si1 0 0 etching in water solution of hydrazine, which etches 1 1 1 faces much more slowly than others. Thermally grown SiO2 mask for the hydrazine etching was used, because single Al mask cannot be well bonded to the substrate and tends to peel during the etching. It was revealed that transmittance in the infrared spectrum region of the patterned silicon decreases by about five times compared with that of flat silicon substrate and this decrease is almost independent of the angle of the incident beam. In the infrared region, decrease of transmittance of the patterned samples is directly proportional to the wave number. The shape of formed pyramids has strong influence on the transmittance. Decrease of the transmittance is much more rapid and larger in the case of sharpless pillars. 相似文献
7.
8.
微模塑法制备PMMA/SiO2二氧化硅杂化材料微结构 总被引:1,自引:0,他引:1
以摩尔比为 1∶1的甲基丙烯酸甲酯 (MMA)、甲基丙烯酸 (3 三乙氧基硅烷基 )丙酯 (ESMA)单体、0 .2 %(单体总量的质量分数 )的偶氮二异丁腈AIBN引发剂和四氢呋喃 (THF)溶剂 ,及 2 0 % (总质量分数 )的正硅酸乙酯TEOS合成出PMMA/SiO2 有机 无机杂化的杂化溶胶 .将溶胶在洗净的普通光学玻璃基片表面甩膜 .利用软刻蚀中的微模塑法 ,把有机硅弹性印章复制有精细图纹一面轻放在杂化溶胶膜上进行微模塑 ,外加 1N压力于12 0℃下处理 2h使溶胶凝胶化 .印章剥离后在基片表面就形成了PMMA/SiO2 有机 无机杂化材料的微图纹结构 .从微图纹的光学显微镜照片可以看出微模塑方法制备杂化材料复制的图纹精细度高 ,操作简单易行 ,是一类比较理想的微细图纹结构加工的方法 . 相似文献
9.
采用MSDI严格角动量投影46Ti、48Cr形变HF谱 总被引:1,自引:1,他引:0
采用修正的表面δ相互作用(MSDI),以球形壳模型单粒子态作基矢,对fp壳层区偶偶核46Ti、48Cr进行形变Hartree–Fock(HF)计算,并用形变HF单粒子态构造Slater行列式波函数,即形变HF内禀态,然后对其实施严格角动量投影程序,得到比较合理的结果. 相似文献
10.
本文给出了Banach空间广义分解定理的一个初等证明,并利用它来证明两个对称不等式.这是首次在Banach空间获得这样的不等式. 相似文献