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The dissolution behaviour of cellulose in low temperature molten salts was investigated. Depending on the chosen anions in the melt, cellulose shows different reaction behaviour in different Li+pp40/xxlarge8208.gif" alt="dash" align="MIDDLE" BORDER="0">containing melts. Dissolution of the polymer was observed in molten LiClO4pp40/xxlarge267.gif" alt="cdot" align="BASELINE" BORDER="0">3H2O and molten LiIpp40/xxlarge267.gif" alt="cdot" align="BASELINE" BORDER="0">2H2O. In the hydrated melts of LiCH3COOpp40/xxlarge267.gif" alt="cdot" align="BASELINE" BORDER="0">2H2O and LiNO3pp40/xxlarge267.gif" alt="cdot" align="BASELINE" BORDER="0">3H2O a fine distribution of cellulose was stated. Cellulose can be regenerated by cooling the melt and removing the salt by dissolution in water.The structure of the recrystallized product is determined by the used low temperature molten salt. 相似文献
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Pogliani L 《Journal of computational chemistry》2003,24(9):1097-1109
The complete graph conjecture that encodes the inner-core electrons of atoms with principal quantum number n >or= 2 with complete graphs, and especially with odd complete graphs, is discussed. This conjecture is used to derive new values for the molecular connectivity and pseudoconnectivity basis indices of hydrogen-suppressed chemical pseudographs. For atoms with n = 2 the new values derived with this conjecture are coincident with the old ones. The modeling ability of the new homogeneous basis indices, and of the higher-order terms, is tested and compared with previous modeling studies, which are centered on basis indices that are either based on quantum concepts or partially based on this new conjecture for the inner-core electrons. Two similar algorithms have been proposed with this conjecture, and they parallel the two "quantum" algorithms put forward by molecular connectivity for atoms with n > 2. Nine properties of five classes of compounds have been tested: the molecular polarizabilities of a class of organic compounds, the dipole moment, molar refraction, boiling points, ionization energies, and parachor of a series of halomethanes, the lattice enthalpy of metal halides, the rates of hydrogen abstraction of chlorofluorocarbons, and the pED(50) of phenylalkylamines. The two tested algorithms based on the odd complete graph conjecture give rise to a highly interesting model of the nine properties, and three of them can even be modeled by the same set of basis indices. Interesting is the role of some basis indices all along the model. 相似文献
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LU Juan ZHOU Li-Huan MA Wei-Xing HE Xiao-Rong 《理论物理通讯》2008,49(1):207-211
Based on the quark-gluon structure of nucleon and the existence of Odderon in nucleon via gluon selfinteraction, the elastic scattering of pp at high energies is studied. Our theoretical predictions reproduce experimental data perfectly. The contributions from individual terms of quark-quark, gluon-gluon interactions, quark-gluon interference and the Odderon terms to total cross section are analyzed. In addition to the leading quark-quark contribution, the Odderon contribution is quite important. In particular, the Odderon plays an essential role in fitting to data. Therefore, We may claim that the high energy pp and pp elastic scattering may be good processes to search for the Odderon, the three Reggeized gluon bound states. 相似文献
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P. D. Harty I. J. D. MacGregor P. Grabmayr J. Ahrens J. R. M. Annand I. Anthony R. Beck D. Branford G. E. Cross T. Davinson S. J. Hall T. Hehl J. D. Kellie T. Lamparter J. A. MacKenzie J. C. McGeorge G. J. Miller R. O. Owens M. Sauer R. Schneider K. Spaeth 《Physics letters. [Part B]》1996,380(3-4):247-252
The 12C(γ,pn) and 12C(γ,pp) reactions have been studied using tagged photons of energy Eγ = 150–400 MeV. Recoil momentum distributions are compared to the results of Monte Carlo calculations based on a two-nucleon photon absorption model and two different phase space models. The 12C(γ,pn) data at low missing energy are consistent with absorption on 1p2 and 1s1p nucleon pairs. 相似文献
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A quark coalescence model, based on semi-relativistic molecular dynamics with color interactions among quarks, is presented and applied to pp collisions. A phenomenological potential with two tunable parameters is introduced to describe the color interactions between quarks and antiquarks. The interactions drive the process of hadronization that finally results in different color neutral clusters, which can be identified as hadrons based on some criteria. A Monte Carlo generator PYTHIA is used to generate quarks in the initial state of hadronization, and different values of tunable parameters are used to study the final state distributions and correlations. Baryon-to-meson ratio, transverse momentum spectra, pseudorapidity distributions and forward-backward multiplicity correlations of hadrons produced in the hadronization process, obtained from this model with different parameters, are compared with those from PYTHIA. 相似文献
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LIU Bo-Chao ZOU Bing-Song 《理论物理通讯》2006,46(3):501-506
The reaction of pp → pK^+A is a very good channel to study N^* resonances through their KA decay mode, because there is no mixing of isospin I = 1/2 and I = 3/2 due to isospin conservation. In this work, we extend a resonance model, which can reproduce the total cross section very well, to offer differential cross section information about this reaction. It can serve as a reference to build the scheduled hadron detector at Lanzhou Cooler Storage Ring (CSR). Experiment measurement of these differential cross sections in the future will supply us more constraints on the model and help us understanding the strangeness production dynamics better. 相似文献
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研究了关于Lawson序≤l的强左负右pp半群,给出关于Lawson序≤l的强左负右pp半群的构造方法,并且给出了这类半群的结构定理。 相似文献
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Complementary to the conventional experimental studies on N* from πN and γ(*)N reactions, the e+e-, pp and pp collisions can give novel insights into these N* resonances. While the e+e- collisions through production and decay of vector charmonium ψ provide a nice isospin filter for a simultaneously study of N*, △*, ∧*, ∑* and 2*, the pp collisions should be the best place for producing those △*++ with large coupling to p+p though pp →nA*++ reaction, and the pp collisions should be the best place for looking for those N* with large coupling to σN. 相似文献