全文获取类型
收费全文 | 7704篇 |
免费 | 941篇 |
国内免费 | 830篇 |
专业分类
化学 | 3473篇 |
晶体学 | 83篇 |
力学 | 1241篇 |
综合类 | 60篇 |
数学 | 363篇 |
物理学 | 4255篇 |
出版年
2024年 | 15篇 |
2023年 | 88篇 |
2022年 | 187篇 |
2021年 | 212篇 |
2020年 | 269篇 |
2019年 | 207篇 |
2018年 | 222篇 |
2017年 | 267篇 |
2016年 | 302篇 |
2015年 | 263篇 |
2014年 | 382篇 |
2013年 | 556篇 |
2012年 | 349篇 |
2011年 | 481篇 |
2010年 | 374篇 |
2009年 | 471篇 |
2008年 | 452篇 |
2007年 | 504篇 |
2006年 | 484篇 |
2005年 | 409篇 |
2004年 | 398篇 |
2003年 | 344篇 |
2002年 | 363篇 |
2001年 | 329篇 |
2000年 | 286篇 |
1999年 | 239篇 |
1998年 | 166篇 |
1997年 | 141篇 |
1996年 | 107篇 |
1995年 | 100篇 |
1994年 | 75篇 |
1993年 | 51篇 |
1992年 | 46篇 |
1991年 | 51篇 |
1990年 | 29篇 |
1989年 | 28篇 |
1988年 | 23篇 |
1987年 | 20篇 |
1986年 | 16篇 |
1985年 | 21篇 |
1984年 | 24篇 |
1983年 | 11篇 |
1982年 | 18篇 |
1981年 | 9篇 |
1980年 | 12篇 |
1979年 | 17篇 |
1978年 | 10篇 |
1977年 | 9篇 |
1976年 | 11篇 |
1973年 | 8篇 |
排序方式: 共有9475条查询结果,搜索用时 15 毫秒
1.
Herein, we successfully construct the 3D biocompatible graphene through crosslinking 2D graphene nanosheet onto carbon fiber paper with poly(diallyldimethylammonium chloride) (PDDA) as anode of the alcohol biofuel cell. Compared with the bioanode without 3D graphene, the current density and output power of PDDA-graphene-ADH bioanode is increased by 23 % and 41 % at a high concentration of ethanol at pH 8.9, suggesting the stabilization role of graphene in enzyme loading. The study provides us a deep analysis on structures and performances of the bioanode incl. electrochemistry, X-ray photoelectron spectra, and atomic force microscopy images, which is significant to develop the new methods to construct 3D porous electrodes in energy conversion device. 相似文献
2.
Wenpin Wang Qing Yao Jianhui Song Binbin Yao Hui Wang Zhibo Li 《Journal of Polymer Science.Polymer Physics》2019,57(11):662-669
The PeakForce Quantitative Nanomechanical Mapping based on atomic force microscope (AFM) is employed to first visualize and then quantify the elastic properties of a model nitrile rubber/poly(vinyl chloride) (NBR/PVC) blend at the nanoscale. This method allows us to consistently observe the changes in mechanical properties of each phase in polymer blends. Beyond measuring and discriminating elastic modulus and adhesion forces of each phase, we tune the AFM tips and the peak force parameters in order to reliably image samples. In view of viscoelastic difference in each phase, a three‐phase coexistence of an unmixed NBR phase, the mixed phase, and PVC microcrystallites is directly visualized in NBR/PVC blends. The nanomechanical investigation is also capable of recognizing the crosslinked rubber phase in cured rubber. The contribution of the mixed phase was quantified and it was found that the mechanical properties of blends are mainly determined by the homogeneity and stiffness of the mixed phase. This study furthers our understanding the structure–mechanical property relationship of thermoplastic elastomers, which is important for their potential design and applications. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2019 , 57, 662–669 相似文献
3.
Dr. Carla Carrera Dr. Eleonora Cavallari Dr. Giuseppe Digilio Dr. Oksana Bondar Prof. Silvio Aime Dr. Francesca Reineri 《Chemphyschem》2021,22(11):1042-1048
An efficient synthesis of vinyl-[1-13C]pyruvate has been reported, from which 13C hyperpolarized (HP) ethyl-[1-13C]pyruvate has been obtained by means of ParaHydrogen Induced Polarization (PHIP). Due to the intrinsic lability of pyruvate, which leads quickly to degradation of the reaction mixture even under mild reaction conditions, the vinyl-ester has been synthesized through the intermediacy of a more stable ketal derivative. 13C and 1H hyperpolarizations of ethyl-[1-13C]pyruvate, hydrogenated using ParaHydrogen, have been compared to those observed on the more widely used allyl-derivative. It has been demonstrated that the spin order transfer from ParaHydrogen protons to 13C, is more efficient on the ethyl than on the allyl-esterdue to the larger J-couplings involved. The main requirements needed for the biological application of this HP product have been met, i. e. an aqueous solution of the product at high concentration (40 mM) with a good 13C polarization level (4.8 %) has been obtained. The in vitro metabolic transformation of the HP ethyl-[1-13C]pyruvate, catalyzed by an esterase, has been observed. This substrate appears to be a good candidate for in vivo metabolic investigations using PHIP hyperpolarized probes. 相似文献
4.
In this work the results of the statistical topometric analysis of fracture surfaces of soda-lime-silica glass with and without ionic exchange treatment are reported. In this case, the mechanism of substitution is K+-Na+. atomic force microscopy (AFM) was employed to record the topometric data from the fracture surface. The roughness exponent (ζ) and the correlation length (ξ) were calculated by the variable bandwidth method. The analysis for both glasses (subjected and non-subjected to ionic exchange) for ζ shows a value ∼0.8, this value agrees well with that reported in the literature for rapid crack propagation in a variety of materials. The correlation length shows different values for each condition. These results, along with those of microhardness indentations suggest that the self-affine correlation length is influenced by the complex interactions of the stress field of microcracks with that resulting from the collective behavior of the point defects introduced by the strengthening mechanism of ionic exchange. 相似文献
5.
6.
Jong Uhn Kim 《Transactions of the American Mathematical Society》2002,354(3):1117-1135
In this paper we discuss an initial-boundary value problem for a stochastic nonlinear equation arising in one-dimensional viscoelasticity. We propose to use a new direct method to obtain a solution. This method is expected to be applicable to a broad class of nonlinear stochastic partial differential equations.
7.
介绍了原子力显微镜在生物物理领域的最新应用:蛋白质去折叠、DNA拉伸、生物膜受力,通过分析实验得到的力谱,可以获取关于蛋白质、DNA、生物膜结构信息.原子力显微镜不仅能反映测量体系的力学性质,由于其具有独特的时间、空间分辨及实时成像,因而能提供更多信息. 相似文献
8.
9.
Franz H. Asthalter T. Dommach M. Ehnes A. Messel K. Sergueev I. 《Hyperfine Interactions》2002,141(1-4):131-134
The present status of the new nuclear resonance beamline PETRA 1 at HASYLAB, DESY, Hamburg is described. Besides an overview
of the experimental setup some examples of recent experiments are given. Those cover the main applications, i.e., inelastic
scattering from iron alloys and quasielastic scattering from glass-forming liquids.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
10.
For more than 25 yearsJΨ production has helped to sharpen our understanding of QCD. In proton induced reaction some observations are rather well understood
while others are still unclear. The current status of the theory ofJΨ production will be sketched, paying special attention to the issues of formation time andJΨ re-interaction in a nuclear medium. 相似文献