全文获取类型
收费全文 | 5002篇 |
免费 | 851篇 |
国内免费 | 361篇 |
专业分类
化学 | 3186篇 |
晶体学 | 77篇 |
力学 | 229篇 |
综合类 | 32篇 |
数学 | 68篇 |
物理学 | 2622篇 |
出版年
2024年 | 4篇 |
2023年 | 31篇 |
2022年 | 116篇 |
2021年 | 110篇 |
2020年 | 138篇 |
2019年 | 138篇 |
2018年 | 129篇 |
2017年 | 162篇 |
2016年 | 234篇 |
2015年 | 230篇 |
2014年 | 269篇 |
2013年 | 363篇 |
2012年 | 278篇 |
2011年 | 306篇 |
2010年 | 241篇 |
2009年 | 298篇 |
2008年 | 300篇 |
2007年 | 359篇 |
2006年 | 349篇 |
2005年 | 275篇 |
2004年 | 294篇 |
2003年 | 223篇 |
2002年 | 203篇 |
2001年 | 213篇 |
2000年 | 153篇 |
1999年 | 140篇 |
1998年 | 106篇 |
1997年 | 103篇 |
1996年 | 89篇 |
1995年 | 75篇 |
1994年 | 51篇 |
1993年 | 48篇 |
1992年 | 46篇 |
1991年 | 22篇 |
1990年 | 23篇 |
1989年 | 18篇 |
1988年 | 17篇 |
1987年 | 12篇 |
1986年 | 10篇 |
1985年 | 5篇 |
1984年 | 5篇 |
1983年 | 2篇 |
1982年 | 6篇 |
1981年 | 4篇 |
1980年 | 3篇 |
1979年 | 6篇 |
1975年 | 1篇 |
1973年 | 1篇 |
1971年 | 1篇 |
1957年 | 2篇 |
排序方式: 共有6214条查询结果,搜索用时 15 毫秒
1.
Crosslinked poly(ethylene oxide) containing siloxanes fabricated through thiol‐ene photochemistry
下载免费PDF全文
![点击此处可从《Journal of polymer science. Part A, Polymer chemistry》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Victor A. Kusuma Elliot A. Roth William P. Clafshenkel Steven S. Klara Xu Zhou Surendar R. Venna Erik Albenze David R. Luebke Meagan S. Mauter Richard R. Koepsel Alan J. Russell David Hopkinson Hunaid B. Nulwala 《Journal of polymer science. Part A, Polymer chemistry》2015,53(13):1548-1557
Homogenous amphiphilic crosslinked polymer films comprising of poly(ethylene oxide) and polysiloxane were synthesized utilizing thiol‐ene “ click ” photochemistry. A systematic variation in polymer composition was Carried out to obtain high quality films with varied amount of siloxane and poly(ethylene oxide). These films showed improved gas separation performance with high gas permeabilities with good CO2/N2 selectivity. Furthermore, the resulting films were also tested for its biocompatibility, as a carrier media which allow human adult mesenchymal stem cells to retain their capacity for osteoblastic differentiation after transplantation. The obtained crosslinked films were characterized using differential scanning calorimetry, dynamic mechanical analysis, thermogravimetric analysis, FTIR, Raman‐IR , and small angle X‐ray scattering. The synthesis ease and commercial availability of the starting materials suggests that these new crosslinked polymer networks could find applications in wide range of applications. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 1548–1557 相似文献
2.
Activated carbon production from almond shells using phosphoric acid activation agent was achieved by applying both conventional heating and microwave heating in succession. The morphology and surface properties of activated carbon were studied using thermogravimetric and differential gravimetric analysis, Fourier-transform infrared spectroscopy, scanning electron microscopy, and Brunauer–Emmett–Teller analysis. A surface area of 1128 m2/g was achieved by optimizing the microwave power (500?W), microwave application time (15?minutes), conventional heating time (45?minutes), conventional heating temperature (500?°C), and the phosphoric acid:sample ratio (0.7:1). An adsorption capacity of methylene blue of 148?mg/g and an iodine value of 791?mg/g was obtained for the prepared activated carbon. 相似文献
3.
This paper reports that the growth of RuOx(110) thin layer growth on Ru(0001)
has been investigated by means of scanning tunnelling microscope (STM). The STM
images showed a domain structure with three rotational domains of RuOx(110)
rotated by an angle of 120℃.
The as-grown RuOx(110) thin layer is expanded from the bulk-truncated
RuOx(110) due to the large mismatch between RuOx(110) and the
Ru(0001) substrate. The results also indicate that growth of RuOx(110)
thin layer on the Ru(0001) substrate by oxidation tends first to formation
of the Ru-O (oxygen) chains in the [001] direction of RuOx(110). 相似文献
4.
H.S RagabA Shehap M.S Abo EllilW.H Osman F.H Abd El-Kader 《Journal of Physics and Chemistry of Solids》2002,63(10):1839-1847
Ternary-phase ceramic system of Li2O Al2O3 4SiO2 doped with CuO, FeO and TiO2 has been prepared and subjected to dc electrical conductivity and thermally stimulated depolarization current (TSDC) measurements as a function of temperature (30-250 °C) and field strength. The electrical conductivity results are explained by assuming both ionic and electronic conduction mechanisms coexist with different contributions over the whole temperature range of experiments. TSDC spectra have been found to be characterized by a broad intense relaxation peak, which can be attributed to an ionic charge polarization. The broad relaxation transitions are apparently a result of the nonuniform nature of this process. Activation energies are calculated for both dc electrical conductivity and TSDC according to Arrhenius equation and initial rise method, respectively. 相似文献
5.
空间遥感相机长条反射镜较圆反射镜的整体刚度相差很大,整个组件在随火箭发射过程中因力学环境引起的自身位置改变导致面形的微小畸变从而对成像质量造成严重影响。因此,反射镜组件的设计就成为整个相机系统研制的重点与难点之一。对其进行科学、严谨的力学环境仿真是设计中的有效辅助手段。对某相机的长条反射镜组件动力学响应进行了较为深入的研究,借助MSC-patran,用有限元法进行了求解。获得了组件的动力学特性。 相似文献
6.
We present the design and study of waveguide structures based on porous silicon where the light confinement is not due to the usual total reflection effect but to the use of photonic crystals (PCs) as confining walls. These PC are omnidirectional mirrors (OMs), consisting of the periodic repetition of two porous silicon layers with different refractive indices and thicknesses. They reflect the radiation for all angles of incidence within a frequency range called the omnidirectional band gap (OBG). We have followed the PC formalism to investigate the properties of the OM as a multimode waveguide: the number of modes within the band gap, their field spatial distribution and their confinement as a function of the frequency and the core thickness. 相似文献
7.
8.
FJZ-250型高速分幅相机时间测量不确定度分析 总被引:2,自引:1,他引:1
FJZ-250型高速转镜分幅相机因转镜速度的不可重复性,光机结构的构造原理和控制系统各路高压触发时间的漂移,导致了时间测量的不确定度。为此,须对相机测量数据进行校正。阐述了校正方法、提供了逐幅校正位置误差的修正系数。若以预置转速对应的名义周期值去处理测量结果,则相机的时间测量合成小确定度将达1%,对名义周期值和名义幅间间隔时间值进行修正后,则可降至0.3%。 相似文献
9.
10.
碳纤维增强复合材料反射镜的刚度分析 总被引:3,自引:2,他引:1
用有限元法对层合板结构和蜂窝夹层结构的两种复合材料反射镜的刚度进行分析计算,分析是以Ex1522环氧树脂为基体,M60J碳为增强材料的平面反射镜为例进行的,分析包括不同铺层取向、顺序的层合板反射镜自重下的镜面变形;对蜂窝夹层结构反射镜,分别比较了以芳纶纸、玻璃布、耐久铝三种夹层材料的反射镜刚度,对比了碳纤维复合材料、铍金属、微晶玻璃为面板材料的反射镜刚度,讨论了不同蜂窝单元结构形状对反射镜刚度的影响.分析表明,对于以Ex1522环氧树脂为基体,M60J碳为增强材料的平面复合材料反射镜,要使其具有相对稳定的面形,应采用单元形状为正三角形铝蜂窝,前后面板各为12层;90/45/0/-45]3层合板的夹层结构. 相似文献