全文获取类型
收费全文 | 27371篇 |
免费 | 2422篇 |
国内免费 | 6612篇 |
专业分类
化学 | 29487篇 |
晶体学 | 397篇 |
力学 | 1156篇 |
综合类 | 264篇 |
数学 | 1942篇 |
物理学 | 3159篇 |
出版年
2024年 | 45篇 |
2023年 | 251篇 |
2022年 | 618篇 |
2021年 | 724篇 |
2020年 | 934篇 |
2019年 | 800篇 |
2018年 | 827篇 |
2017年 | 925篇 |
2016年 | 1263篇 |
2015年 | 1200篇 |
2014年 | 1544篇 |
2013年 | 2618篇 |
2012年 | 1771篇 |
2011年 | 1866篇 |
2010年 | 1523篇 |
2009年 | 1766篇 |
2008年 | 1870篇 |
2007年 | 1987篇 |
2006年 | 1968篇 |
2005年 | 1831篇 |
2004年 | 1748篇 |
2003年 | 1518篇 |
2002年 | 1057篇 |
2001年 | 734篇 |
2000年 | 660篇 |
1999年 | 663篇 |
1998年 | 585篇 |
1997年 | 501篇 |
1996年 | 406篇 |
1995年 | 401篇 |
1994年 | 357篇 |
1993年 | 319篇 |
1992年 | 295篇 |
1991年 | 190篇 |
1990年 | 123篇 |
1989年 | 109篇 |
1988年 | 99篇 |
1987年 | 62篇 |
1986年 | 46篇 |
1985年 | 53篇 |
1984年 | 41篇 |
1983年 | 17篇 |
1982年 | 16篇 |
1981年 | 15篇 |
1980年 | 12篇 |
1979年 | 6篇 |
1978年 | 10篇 |
1977年 | 6篇 |
1976年 | 9篇 |
1975年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
1.
数据包络分析(DEA)是评价供应链系统(Supply chain system)间相对有效性的一种重要的工具,但是传统的DEA不考虑供应链的内部结构,对系统效率评价偏高;而本文所研究两阶段串联供应链系统,考虑把部分中间产品作为最终产品输出,增加额外中间投入的情形.基于所提出的供应链系统结构,本文建立相应的串联结构下的网络DEA模型,并针对所建立模型进行相关理论的研究,给出了串联结构下的生产可能集和规模收益情况判定方法.最后,进行数值实验,以验证我们提出的结论. 相似文献
2.
(S)-2-[2-(p-Tolylsulfinyl)phenyl]acetaldehyde reacts with different O-silylated ketenethioacetals in the presence of Yb(OTf)3 yielding β-hydroxythioesters in high yields and diastereoselectivities. The obtained compounds were readily transformed into β-hydroxyacids and their corresponding diols. These Mukaiyama aldol reactions are a direct evidence of the ability of the sulfinyl group to control 1,5- and 1,6-asymmetric induction processes. 相似文献
3.
Non-stoichiometric ternary chalcogenides (Zn,Fe)S were prepared in the film form by pyrolytic spray deposition technique, using air/nitrogen as the carrier gas. The precursor solution comprised of ZnCl2, FeCl2 and thiourea. The depositions were carried out under optimum conditions of experimental parameters viz. carrier gas (air/nitrogen) flow rate, concentration of precursor constituents, nozzle substrate distance and temperature of quartz substrate. The deposited thin films were later sintered in argon at 1073 K for 120 min.The structural, compositional and optical properties of the sintered thin films were studied. X-ray diffraction studies of the thin films indicated the presence of (Zn,Fe)S solid solution with prominent cubic sphalerite phase while surface morphology as determined by scanning electron microscopy (SEM) revealed a granular structure.The chemical composition of the resulting thin films as analyzed by energy dispersive X-ray analysis (EDAX) reflected the composition of the precursor solutions from which the depositions were carried out with Fe at% values ranging from 0.4 up to 33.SEM micrographs of thin films reveal that the grain sizes of the thin films prepared using air as carrier gas and N2 as carrier gas are in the vicinity of 300 and 150 nm, respectively.The diffuse transmittance measurements for thin films, as a function of wavelength reveal the dependence of direct optical band gap on Fe content and type of phase. 相似文献
4.
Let G=(V(G),E(G)) be a graph. A (n,G, λ)‐GD is a partition of the edges of λKn into subgraphs (G‐blocks), each of which is isomorphic to G. The (n,G,λ)‐GD is named as graph design for G or G‐decomposition. The large set of (n,G,λ)‐GD is denoted by (n,G,λ)‐LGD. In this work, we obtain the existence spectrum of (n,P3,λ)‐LGD. © 2002 Wiley Periodicals, Inc. J Combin Designs 10: 151–159, 2002; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/jcd.10008 相似文献
5.
通过分析计算,设计了一种大口径宽视场折射式红外相机光学系统。该系统设计用于超长线阵扫描红外相机的地面演示成像,它能同时对短波2μm—3μm、中波3μm—4.5μm双波段成像,且同时具有24°的大视场和150mm的宽口径,成像质量接近衍射极限。该系统在航天遥感领域应用广泛。 相似文献
6.
7.
David Morris 《Applied biochemistry and biotechnology》2004,113(1-3):5-12
This article addresses two questions: Has the effectiveness of the US governments federal research and development (R&;D) spending suffered from the post-1980 strategic change from freely shared and publicly owned to privately owned scientific advances? What criteria would a federal R&;D program use to design a strategy that most effectively enhances the well-being of farmers and rural communities? Several studies found that the pre-1980 US Department of Agriculture research strategy was very effective. No comparable studies have analyzed the comparative effectiveness of the post-1980 strategy of restricting access to the results of public research. Recent experience and several analytical studies suggest that to significantly enhance the health of rural economies from an expanded use of plant matter as an industrial material, federal policy should channel scientific and engineering research into small- and medium-sized production and processing technologies and should encourage farmer-owned, value-added enterprises. 相似文献
8.
A fluorous osmium catalyst was firstly developed. It had been effectively used as recoverable and reusable catalyst in the dihydroxylation of olefins. 相似文献
9.
10.
Hiroto Kudo Nobuhito Ito Keiji Nakajima Masami Ochiai Tadatomi Nishikubo 《Journal of polymer science. Part A, Polymer chemistry》2007,45(19):4421-4429
The polyaddition of fluorine‐containing bis(epoxide)s and fluorine‐containing triazine di(aryl ether)s were examined to give the corresponding fluorine‐containing poly(cyanurate)s. It was observed that the synthesized fluoropolymers had good thermal stabilities and good film‐forming properties. The glass transition temperatures (Tg's) and refractive‐indices (nD's) of synthesized polymers were determined by differential scanning calorimetry and ellipsometry, respectively, and it was found that the values of Tg's and nD's were supported by their fluorine containing ratios and skeletons. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4421–4429, 2007 相似文献