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排序方式: 共有154条查询结果,搜索用时 15 毫秒
1.
The effect of Re addition on the microstructure and hardening behaviour of the dual two-phase Ni3Al (L12) and Ni3V (D022) intermetallic alloy was investigated by scanning electron microscopy, transmission electron microscopy and Vickers hardness test. The two-phase eutectoid microstructure accompanying the Re-rich precipitates were observed in the channel region of the alloys in which Re substituted for Ni but not in those in which Re substituted for Al and V. The concomitant addition of Nb (or Ta) with Re more stabilized the two-phase eutectoid microstructure and consequently more induced the fine precipitates in the channel region. The annealing at temperatures below the eutectoid temperature was necessary to induce the fine precipitates in the channel region and thereby result in the precipitation hardening. The fine precipitation in the channel region and related hardening was attributed to the alloying feature so that Re is soluble in the A1 (fcc) phase at high temperatures and becomes less soluble in the two intermetallic phases decomposed from the A1 phase at low temperatures. 相似文献
2.
Keka Chakraborty S K Paranjpe V Siruguri O D Jayakumar S K Kulshreshtha 《Pramana》1997,48(6):1115-1122
Neutron diffraction and M?ssbauer measurements have been carried out on the cubic Laves phase intermetallic TbMnFe. The magnetic
moment on the transition metal atom is found to be low, 0.2μ
B, at room temperature. This moment is temperature independent down to 10 K. Magnetic moment on the rare earth atom varies
from 2.5μ
B at 296 K to 7.27μ
B at 10 K. M?ssbauer spectra recorded at 298 K and 78 K have magnetic character but there is a large distribution of hyperfine
field values. Both these features arise due to magnetic frustration created in the sample due to the competing ferro and antiferromagnetic
interactions between the transition metal atoms. 相似文献
3.
Svilen Bobev Paul H. Tobash Joe D. Thompson John L. Sarrao 《Journal of solid state chemistry》2005,178(6):2091-2103
A number of rare-earth alumo-silicides (R-Al-Si) have been synthesized from the corresponding elements by high-temperature reactions, carried out in excess of aluminum to serve as a flux. Under these experimental conditions, large single crystals of all R-Al-Si ternary phases were readily produced. The crystal structures these ternaries adopt were studied by means of powder and single-crystal X-ray diffraction and were classified as follows: (1) the early rare-earths (R=La, Ce, Pr, Nd, Sm, Gd) yield RAlxSi2−x, x∼1, non-stoichiometric ternary derivatives of the body-centered α-ThSi2-type; (2) the late rare-earths (R=Tb, Dy, Ho, Er, Tm) form stoichiometric R2Al3Si2 compounds that crystallize in the C-centered monoclinic Y2Al3Si2-type; (3) the divalent Eu and Yb produce EuAl2Si2 and YbAl2Si2 with the trigonal CaAl2Si2-type, whereas the last lanthanide element, Lu, forms LuAlSi with C-centered orthorhombic YAlGe-type. These structural trends are reviewed, and the evolution of the basic physical properties such as magnetism, heat capacity and electrical resistivity when moving across the series is described in detail. 相似文献
4.
Dr. Yuliang Yuan Zhilong Yang Dr. Wenchuan Lai Lei Gao Mengfan Li Dr. Jiawei Zhang Prof. Hongwen Huang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(67):16564-16580
Characterized by long-range atomic ordering, well-defined stoichiometry, and controlled crystal structure, intermetallics have attracted increasing attention in the area of chemical synthesis and catalytic applications. Liquid-phase synthesis of intermetallics has arisen as the promising methodology due to its precise control over size, shape, and resistance toward sintering compared with the traditional metallurgy. This short review tends to provide perspectives on the liquid-phase synthesis of intermetallics in terms of both thermodynamics and methodology, as well as its applications in various catalytic reactions. Specifically, basic thermodynamics and kinetics in the synthesis of intermetallics will be first discussed, followed by discussing the main factors that will affect the formation of intermetallics during synthesis. The application of intermetallics in electrocatalysis will be demonstrated case by case at last. We conclude the review with perspectives on the future developments with respect to both synthesis and catalytic applications. 相似文献
5.
T. Joseph Sahaya Anand Chua Kok Yau Yeow See Leong Lim Weng Keat Hng May Ting 《Current Applied Physics》2013,13(8):1674-1683
Effects of High Temperature Storage (HTS) and bonding toward microstructure change of intermetallic compound (IMC) at the wire bonding interface of 3 types of bond pad (Al, AlSiCu and NiPdAu) were presented in this paper. Optical and electron microscope analyses revealed that the IMC growth rate of samples under 175 and 200 °C HTS increased in the order of Al > AlSiCu > NiPdAu. Besides, higher HTS and bonding temperatures also promoted higher IMC thickness. The compositional study showed that higher HTS and bonding temperature developed rapid interdiffusion in bonding interface. In the mechanical ball shear test, a decrease of the shear force of Al and AlSiCu bond pads after 500 h HTS was believed due to poorly developed IMC at bonding interface. On the other hand, shear force degradation at 1000 h was due to excessive growth of IMC that in turn causes the formation of defects. For NiPdAu bond pad, increasing trend of shear force with HTS duration at 175 °C implied a good reliability of the Cu wire bonding. The rapid microscopic inspection on Cu wired Al bond pad under HTS 175 °C showed the IMC development from the periphery to the center of the ball bond. However, after 500 h voids started to develop until the crack was observed at 1000 h. 相似文献
6.
In the present investigation, the indentation study on the high-energy ball-milled nanocrystalline Al5Fe2 intermetallic compound has established the inverse Hall–Petch (IHP) behaviour. The structural characterisation of the milled powder particles by X-ray diffraction (XRD) and transmission electron microscopy has shown the evolution of nanocrystalline phase. Micro-indentation measurements have revealed the increase in hardness with decreasing grain size, reaching to a maximum of 9.0 ± 0.3 GPa up to a grain size of 32 ± 4 nm, followed by a decrease. The decrease in hardness with further refinement, an indication of grain size softening, demonstrates the IHP-like behaviour. The deviation from the Hall–Petch behaviour has been discussed using various models based on the dislocations and grain boundary-mediated processes. From the analysis, it appears that the model based on mesocopic grain boundary sliding phenomena is more appropriate to account for the observed grain size softening. 相似文献
7.
Single crystals of SrIr9In18 were obtained by induction melting of the elements in a glassy carbon crucible followed by annealing at 1070 K. SrIr9In18 was structurally characterized by X-ray powder and single crystal diffraction: P4 m2, a = 811.21(5), c = 854.49(5) pm, wR2 = 0.0511, 1223 F2 values, and 46 variables. The structure is of a new type. The basic building units are Ir@In8 (distorted square-prismatic, square anti-prismatic and bicapped trigonal prismatic coordination) and Ir@In9 (distorted trigonal prismatic coordination) polyhedra, which condense to a three-dimensional network, which leaves large cavities for the strontium cations, which are coordinated to four iridium and twelve indium atoms. The [Ir9In18]2– polyanionic network is stabilized through Ir–In (267–290 pm) and In–In (302–354 pm) bonding. 相似文献
8.
Menggang Li Zhonghong Xia Yarong Huang Lu Tao Yuguang Chao Kun Yin Wenxiu Yang Weiwei Yang Yongsheng Yu Shaojun Guo 《物理化学学报》2020,36(9):1912049-0
Direct methanol fuel cells (DMFCs), as one of the important energy conversion devices, are of great interest in the fields of energy, catalysis and materials. However, the application of DMFCs is presently challenged because of the limited activity and durability of cathode catalysts as well as the poisoning issues caused by methanol permeation to the cathode during operation. Herein, we report a new class of Rh-doped PdCu nanoparticles (NPs) with ordered intermetallic structure for enhancing the activity and durability of the cathode for oxygen reduction reaction (ORR) and achieving superior methanol tolerance. The disordered Rh-doped PdCu NPs can be prepared via a simple wet-chemical method, followed by annealing to convert it to ordered phases. The results of transmission electron microscopy (TEM), scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDS), power X-ray diffraction (PXRD) analysis and high resolution TEM (HRTEM) successfully demonstrate the formation of near-spherical NPs with an average size of 6.5 ± 0.5 nm and the conversion of the phase structure. The complete phase transition temperatures of Rh-doped PdCu NPs and PdCu are 500 and 400 ℃, respectively. The molar ratio of Rh/Pd/Cu in the as-synthesized Rh-doped PdCu NPs is 5/48/47. Benefitting from Rh doping and the presence of the ordered intermetallic structure, the Rh-doped PdCu intermetallic electrocatalyst achieves the maximum ORR mass activity of 0.96 A·mg-1 at 0.9 V versus reversible hydrogen electrode (RHE) under alkaline conditions—a 7.4-fold enhancement compared to the commercial Pt/C catalyst. For different electrocatalysts, the ORR activities follow the sequence, ordered Rh-doped PdCu intermetallics > ordered PdCu intermetallics > disordered Rh-doped PdCu NPs > disordered PdCu NPs > commercial Pt/C catalyst. In addition, the distinct structure endows the Rh-doped PdCu intermetallics with highly stable ORR durability with unaltered half-wave potential (E1/2) and mass activity after continuous 20000 cycles, which are higher than those of other electrocatalysts. Furthermore, the E1/2 of the Rh-doped PdCu intermetallics decreases by only 5 mV after adding 0.5 mol·L-1 methanol to the electrolyte, while the commercial Pt/C catalyst negatively shifts by 235 mV and a distinct oxidation peak can be observed. The results indicate that the ORR activity of the Rh-doped PdCu intermetallic electrocatalyst can be well maintained even in the presence of poisoning environment. Our results have demonstrated that Rh-doped PdCu NPs with ordered intermetallic structures is a potential electrocatalyst toward the next-generation high-performance DMFCs. 相似文献
9.
Magnetic and transport properties of Tm2Co7B3 compound have been studied. This compound crystallizes in the hexagonal Ce2Co7B3 type structure. The coercivity (H
c) of the compound was determined from hysteresis measurements in fields up to 4 T. The temperature dependence of coercivity has been explained by a thermally activated process of domain wall motion. The resistivity at low temperatures shows a T
2 dependence. At higher temperatures the resistivity is not a linear function of temperature, which indicates an electron-phonon interaction in the presence of a small s-d scattering. 相似文献
10.
Martin Sahlberg Premysl Beran Thomas Kollin Nielsen Yngve Cerenius Krisztina Kads Marko P.J. Punkkinen Levente Vitos Olle Eriksson Torben R. Jensen Yvonne Andersson 《Journal of solid state chemistry》2009,182(11):3113-3117
A novel aluminium rich alloy for hydrogen storage has been discovered, ScAl0.8Mg0.2, which has very promising properties regarding hydrogen storage capacity, kinetics and stability towards air oxidation in comparison to hydrogen absorption in state-of-the-art intermetallic compounds. The absorption of hydrogen was found to be very fast, even without adding any catalyst, and reversible. The discovered alloy crystallizes in a CsCl-type structure, but decomposes to ScH2 and Al(Mg) during hydrogen absorption. Detailed analysis of the hydrogen absorption in ScAl0.8Mg0.2 has been performed using in situ synchrotron radiation powder X-ray diffraction, neutron powder diffraction and quantum mechanical calculations. The results from theory and experiments are in good agreement with each other. 相似文献