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1.
We present the fabrication of core-shell-satellite Au@SiO2-Pt nanostructures and demonstrate that LSPR excitation of the core Au nanoparticle can induce plasmon coupling effect to initiate photocatalytic hydrogen generation from decomposition of formic acid. Further studies suggest that the plasmon coupling effect induces a strong local electric field between the Au core and Pt nanoparticles on the SiO2 shell, which enables creation of hot electrons on the non-plasmonic-active Pt nanoparticles to participate hydrogen evolution reaction on the Pt surface. In addition, small SiO2 shell thickness is required in order to obtain a strong plamon coupling effect and achieve efficient photocatalytic activities for hydrogen generation. 相似文献
2.
A. P. Vink E. van der Kolk P. Dorenbos C. W. E. van Eijk 《Optics Communications》2002,210(3-6):277-284
The optical properties of Ce3+ in CaSO4, SrSO4 and BaSO4 are reported. The Ce3+ ion shows 4f05d1→2F5/2,2F7/2 luminescence in all three sulphates. Co-doping with Na+ does not change the local surrounding of the Ce3+ ion, but enhances the amount of Ce3+ ions built in. Under optical excitation, besides the typical Ce3+ doublet emission in the ultraviolet spectral region, band emission around 445 nm was observed. This band emission was not assigned to emission from a Ce3+ centre, but to emission from an impurity-trapped exciton. Under X-ray excitation, both Ce3+ emission and an emission band around 380 nm was observed. This band was assigned to emission from a self-trapped exciton. 相似文献
3.
We obtain expressions for the energy spectrum widths of Rayleigh waves corresponding to their deformational coupling to Fermi and Boltzmann electrons in a two-dimensional layer near the surface of a semibounded solid. We evaluate the nonequilibrium energy of Rayleigh waves that depends on these widths and is caused by the same coupling to the corresponding hot electrons. We show that this energy is independent of the degeneracy degree of the electrons and is given by the mean energy of free Rayleigh waves heated up to temperature of the electrons. We find conditions under which the thermodynamics is determined by this nonequilibrium energy of Rayleigh waves in films of a certain thickness with Fermi electrons near the surface and by the equilibrium energy of bulk phonons in thicker samples. All the results are obtained using the Keldysh diagram technique applied to the case of semibounded media. 相似文献
4.
通过系统研究A~190区超形变核中转动带的转动惯量、角动量顺排、旋称分裂随转动频率的变化规律, 结合我们用处理对力的粒子数守恒方法的计算结果, 对A~190区所有转动带的组态结构给出了一个整体的描述. 绝大多数超形变带都建立在强耦合轨道上, 例如中子[512]5/2, [624]9/2. 少数超形变带则建立在高j闯入轨道上, 即中子[761]3/2, [752]5/2. 根据我们提出的组态结构所进行的理论计算结果表明, A~190区所有转动带的一般行为、反常变化和带交叉都得到了满意的解释. 相似文献
5.
PinHuaLI LeiWANG MinWANG JinCanYAN 《中国化学快报》2004,15(11):1295-1298
A Glaser coupling reaction of terminal alkynes in the presence of nickel chloride withoutany organics and bases in hot water has been developed, which produces the correspondinghomo-coupling products in good yields. 相似文献
6.
The proposed model of laser plasma emission spectrum formation enables us to determine the absolute value of the laser pulse
to plasma emitted radiation conversion factor, profile of the emission spectrum, and frequency distribution of the intensity
and energy in the emitted spectra. This is of interest for laser plasma diagnostics and provides a means for direct calculation
of the number of excited nuclei in dependent on the parameters of laser pulse.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
7.
8.
Brian H. Davison Nhuan P. Nghiem Gerald L. Richardson 《Applied biochemistry and biotechnology》2004,114(1-3):653-669
More than 25 sorbents were tested for uptake of succinic acid from aqueous solutions. The best resins were then tested for
successive loading and regeneration using hotwater. The key desired properties for an ideal sorbent are high capacity, complete
stable regenerability, and specificity for the product. The best resins have a stable capacity of about 0.06 g of succinic
acid/g of resin at moderate concentrations (1–5 g/L) of succinic acid. Several sorbents were tested more exhaustively for
uptake of succinic acid and for successive loading and regeneration using hot water. One resin, XUS 40285, has a good stable
isotherm capacity, prefers succinate over glucose, and has good capacities at both acidic and neutral pH. Succinic acid was
removed from simulated media containing salts, succinic acid, acetic acid, and sugar using a packed column of sorbent resin,
XUS 40285. The fermentation byproduct, acetate, was completely separated from succinate. A simple hot water regeneration successfully
concentrated succinate from 10 g/L (inlet) to 40–110 g/L in the effluent. If successful, this would lower separation costs
by reducing the need for chemicals for the initial purification step. Despie promising initial results of good capacity (0.06
g of succinic/g of sorbent), 70% recovery using hot water, and a recovered concentration of >100 g/L, this regeneration was
not stable over 10 cycles in the column. Alternative regeneration schemes using acid and base were examined. Two (XUS 40285
and XFS-40422) showed both good stable capacities for succinic acid over 10 cycles and >95% recovery in a batch operation
using a modified extraction procedure combining acid and hot water washes. These resins showed comparable results with actual
broth. 相似文献
9.
We consider the problem of a self-consistent determination of an essentially inhomogeneous equilibrium state of classical plasma. The solutions of the stationary Vlasov–Poisson equations are constructed in the form of a localized transition layer that separates the domains of homogeneous plasmas with different equilibrium parameters. The layer can also transform into a local perturbation inside a homogeneous plasma. In both cases, the solution contains neither mass currents nor electric currents, and all electrodynamic and hydrodynamic quantities and their derivatives are continuous. The parameters of the adjacent domains uniquely determine the transition layer structure. 相似文献
10.
Ahilleas N. Maurellis Rüdiger Lang Jochen Landgraf 《Journal of Quantitative Spectroscopy & Radiative Transfer》2004,84(3):295-323
The computation of radiation transmittance in nongray, inhomogeneous atmospheric models is frequently complicated by complex bands of line spectra which range in value over many orders of magnitudes and depend strongly on either or both of pressure and temperature. We present here a new opacity sampling technique which is shown to determine correctly the wavelength-averaged extinction due to path-dependent realizations of banded line spectra. The technique is easy to implement computationally and is applicable to a wide variety of atmospheric problems in which frequent iteration of the radiative transfer model is required. We consider two such instances: modeling of solar flux attenuation for use in a time-dependent planetary ionosphere model and retrieval from nadir measurements of backscattered solar irradiance. The power of the new method lies in its straightforward analytical treatment of both atmospheric inhomogeneity and spectral complexity. It is thus relevant for both retrieval and radiative transfer modeling purposes. 相似文献