Physicochemical properties of π-π complexes of zinctetraphenylporphyrin with aromatic molecules

Features of the solvation of zinctetraphenylporphyrin (ZnTPP) in benzene, toluene,ortho-, meta-, andpara-xylenes were studied by a thermogravimetric method. The temperature ranges of the stability and the compositions of the corresponding specific gm441622746/xxlarge960.gif" alt="pgr" align="BASELINE" BORDER="0">-gm441622746/xxlarge960.gif" alt="pgr" align="BASELINE" BORDER="0"> complexes were determined from the results of the thermogravimetric investigation of the crystallosolvates of the metalloporphyrin with the solvent molecules, and the energy characteristics of the intermolecular metalloporphyrin—solvent interactions were calculated.Institute of the Chemistry of Nonaqueous Solutions, Russian Academy of Sciences, 153018 Ivanovo. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 7, pp. 1545–1548, July, 1992.     

On K‐Theory of Simplicial Rings and Degreewise Constructions

We give a measure of the difference between Waldhausen's definition of the Kgm519740j0772215/xxlarge8208.gif" alt="dash" align="MIDDLE" BORDER="0">theory of a simplicial ring and the definition we obtain by extending Quillen's definition degreewise. This has computational advantages as the degreewise Kgm519740j0772215/xxlarge8208.gif" alt="dash" align="MIDDLE" BORDER="0">theory sometimes is simpler to work with.     

中国省际碳排放驱动因子及趋势分析:以辽宁省为例

采用1997-2012年辽宁省碳排放时间序列数据,参照STIRPAT模型,通过因子分析和最小二乘法回归拟合得到碳排放量和5类主要影响因子的拟合方程.研究结果表明:人口、人均GDP、第二产业产值、单位GDP能耗和全社会固定资产投资每增加或降低1%将带来碳排放量增加或降低比率分别为:0.3294%、0.1544%、0.1424%、0.2675%和0.1375%.通过灰色预测模型GM(1,1)进行预测分析,预测结果为:2020年和2030年辽宁省的碳排放总量将分别达到38705.368万t和69603.215万t,碳排放强度将分别降至0.576t/万元和0.2878t/万元.     

Lateral shaping and stability of a stretching viscous sheet

We investigate the changes of shape of a stretching viscous sheet by controlling the forcing at the lateral edges, which we refer to as lateral shaping. We propose a one-dimensional model to study the dynamics of the viscous sheet and systematically address stability with respect to draw resonance. Two class of lateral forcing are considered: (i) for the case that the stress at the edges is specified, we show that a pure outward normal stress S_n is usually unfavorable to the draw resonance instability as compared to the case of stress-free lateral boundaries. Alternatively, a pure streamwise tangential stress S_t is stabilizing; (ii) for the case that the lateral velocity at the edges is specified, we show that the stability properties are problem specific but can be rationalized based on the induced stress components (S_n,S_t).     

基于改进灰色GM(1,1)马尔柯夫模型的煤矿事故百万吨死亡率预测

煤矿安全事故预防和控制是煤矿安全评价和决策的基础.灰色预测适合于时间短、数据量少和波动不大的系统对象,而马尔可夫链理论适用于预测随机波动大的动态过程.结合灰色预测GM(1,1)模型和马尔可夫链理论的优点,提出了一种改进的灰色马尔可夫GM(1,1)模型.利用改进的GM(1,1)模型进一步拟合煤矿人因失误事故的发展变化趋势,并以此为基础进行马尔柯夫预测,提高预测效果.以2000-2010年全国煤矿事故百万吨死亡率为例进行了预测分析,结果表明模型既能揭示煤矿人因失误事故百万吨死亡率变化的总体趋势,又能克服随机波动性数据对预测精度的影响,具有较强的工程实用性,并对煤矿人因失误安全事故的预测和控制有一定的实际意义.     

A nano-metallic-particles-based CMOS image sensor for DNA detection

In this paper we report on a study of the CMOS image sensor detection of DNA based on self-assembled nano-metallic particles, which are selectively deposited on the surface of the passive image sensor. The nano-metallic particles effectively block the optical radiation in the visible spectrum of ordinary light source. When such a technical method is applied to DNA detection, the requirement for a special UV light source in the most popular fluorescence is eliminated. The DNA detection methodology is tested on a CMOS sensor chip fabricated using a standard 0.5 μm CMOS process. It is demonstrated that the approach is highly selective to detecting even a signal-base mismatched DNA target with an extremely-low-concentration DNA sample down to 10 pM under an ordinary light source.     

改进GM(2,1)模型的MATLAB实现及其应用

针对经济预测,根据灰色模型GM(1,1)的应用介绍了灰色模型GM(2,1)的原理,并利用最小二乘法改进GM(2,1)算法及其预测步骤,用MATLAB实现了预测,用中国经济增长率数据做了仿真,对观测时间序列拟合出数学模型.     

Stability of inertialess liquid film flowing down a heated inclined plane

This paper investigates the stability of inertialess falling film down an uniformly heated inclined plane. Normal mode analysis is performed to study the linear stability of the falling film.     

Instability and dynamics of thin viscoelastic liquid films

The instability, rupture, and subsequent growth of holes in a thin Jeffreys-type viscoelastic film under the influence of long-range van der Waals force are investigated using both linear stability analysis and nonlinear numerical solutions. The linear stability analysis of full governing equations valid for arbitrary wave numbers shows that although fluid rheology does not influence the dominant length scale of the instability, it significantly affects the growth rate. It is shown that neglect of inertia and solvent dynamics results in a nonphysical singularity in the growth rate beyond a critical value of relaxation time. We further carry out numerical simulations of a set of long-wave, nonlinear differential equations (also derived in Rauscher et al., Eur. Phys. J. E 17, 373 (2005)) governing the evolution of the free surface. The nonlinear simulations, in their domain of validity, confirm the results of the linear analysis. Interestingly, results from nonlinear simulations further show that both for Newtonian and viscoelastic liquids, the shape and the dewetting dynamics of a hole are identical when examined in terms of a rescaled time which depends on rheological parameters. Thus, viscoelasticity of Jeffreys type merely accelerates the growth rate, without however affecting the important morphological characteristics.     

The inertial dynamics of thin film flow of non-Newtonian fluids

Consider the flow of a thin layer of non-Newtonian fluid over a solid surface. I model the case where the viscosity depends nonlinearly on the shear-rate; power law fluids are an important example, but the analysis here is for general nonlinear dependence. The modelling allows for large changes in film thickness provided the changes occur over a relatively large enough lateral length scale. Modifying the surface boundary condition for tangential stress forms an accessible foundation for the analysis where flow with constant shear is a neutral critical mode, in addition to a mode representing conservation of fluid. Perturbatively removing the modification then constructs a model for the coupled dynamics of the fluid depth and the lateral momentum. For example, the results model the dynamics of gravity currents of non-Newtonian fluids when the flow is not creeping.