Coupling in Fe(2 ML)/V(y ML) and Fe(2 ML)/V(y ML)/Fe(3 ML)/V(y ML) (y ≥ 4) superlattices

Fe(2 ML)/V(y ML) and interleaved Fe(2 ML)/V(y ML)/Fe(3 ML)/V(y ML) superlattice systems with spacer thicknesses, y, (4 ≤ y ≤ 17) were investigated macro-magnetically to estimate the coupling strength and the magnetoresistance in these materials, and particularly in the antiferromagnetically coupled monolayers. The results from the magnetic and magnetoresistive measurements indicate that adding one monolayer of Fe increases the antiferromagnetic coupling and the magnetoresistivity ratio from 0.0075 mJ/m² at 20 K and 2 % at 10 K for Fe(2 ML)/V(y ML), to 0.05 mJ/m² and 2.5 % for Fe(2 ML)/V(y ML)/Fe(3 ML)/V(y ML) at the same temperatures. Both systems exhibit in-plane magnetic and magnetoresistive isotropy, therefore the increase of the conferred physical parameters is attributed mainly to the stresses at the interface as governing mechanisms over the magnetoelastic forces.      

Iron Precursor Decomposition in the Magnesium Combustion Flame: A New Approach for the Synthesis of Particulate Metal Oxide Nanocomposites

Powders of Fe–Mg–O nanocomposite particles have been grown using a novel chemical vapor synthesis approach that employs the decomposition of a metalorganic precursor inside the metal combustion flame. After annealing in controlled gas atmospheres composition distribution functions, structure and phase stability of the obtained magnesiowüstite nanoparticles are measured with a combination of techniques such as inductively coupled plasma‐optical emission spectroscopy, energy dispersive X‐ray spectroscopy, X‐ray diffraction, and scanning and transmission electron microscopy. Complementary Mössbauer spectroscopy measurements reveal that depending on Fe loading and temperature of annealing either metastable and superparamagnetic solid solutions of Fe³⁺ ions in periclase (MgO) or phase separated mixtures of MgO and ferrimagnetic magnesioferrite (MgFe₂O₄) nanoparticles can be obtained. The described combustion technique represents a novel concept for the production of mixed metal oxide nanoparticles. Adressing the impact of selected annealing protocols, this study underlines the great potential of vapor phase grown non‐equilibrium solids, where thermal processing provides means to trigger phase separation and, concomitantly, the emergence of new magnetic properties.     

Solvothermally Driven Mn Doping and Clustering of Iron Oxide Nanoparticles for Heat Delivery Applications

Direct interactions between nanoparticles of Mn‐doped magnetite or maghemite (clearly differentiated by Raman spectroscopy) grouped in spherical clusters minimize the effect related to their characteristic magnetic dead layer at the surface. Hence, the clustering process jointly with the manganese doping renders these ferrite nanostructures very attractive as displaying increased saturation magnetization, offering, consequently, outstanding values of the specific absorption rate (SAR) for heat delivery. The whole picture for bio‐related applications has been considered, with issues related to magnetic manipulation, colloidal stability, and biocompatibility.     

Chemical Inhomogeneity,Short‐Range Order,and Magnetism in the LiNiO2‐NiO Solid Solution

NiO:Li is an early exemplar for which hole‐doping of a correlated insulator gives rise to rich and varied magnetic behavior. It is also an important system from the viewpoint of p‐type transparent conducting oxides, and is representative of a large class of materials that have been used in lithium ion batteries, since the end‐member compound, LiNiO₂, belongs to the class of layered cathode materials. Despite the deceptive structural and compositional simplicity of this system, a complete understanding of its complex magnetic properties has remained elusive. Here a comprehensive investigation of the solid solution Li_xNi_2?xO₂, examining samples of precise stoichiometry using a combination of high‐resolution synchrotron X‐ray powder diffraction and SQUID magnetometry, is provided. The focus is on the interesting region between 0.40<x<1.00 in which the magnetic ordering temperature changes drastically with composition. The magnetism evolves from strong G‐type antiferromagnetism of x=0.40 with T_N=327 K to robust uncompensated magnetic order at T_N=240 K when x is close to 0.7, and to glassy A‐type antiferromagnetism of x=1.00 at T_N=9 K. This study demonstrates this magnetic behavior is linked to the Li–Ni chemical order that develops from short‐ to long‐range. The interfaces between ordered domains give rise to magnetic exchange bias, which manifests as a shift in the magnetization‐field loop for samples with nanoscale coherence lengths (0.54<x<0.66).     

A simulation of the mixed spin 3–spin 3/2 ferrimagnetic Ising model

The mixed spin 3–spin 3/2 ferrimagnetic Ising model was simulated using cooling algorithm on cellular automaton (CA). The simulations were carried out in the intervals ?4 ≤ D_A/J ≤ 8 and ?4 ≤ D_B/J ≤ 8 for the square lattices with periodic boundary conditions. The ground-state phase diagram of the model has different types of ferrimagnetic phases. Although only the antiferromagnetic nearest-neighbor interaction was contained in the Hamiltonian, the compensation points emerged through D_A/J = 2 at kT/J = 0. The values of the critical exponents (ν, α , β and γ) were estimated within the framework of the finite-size scaling theory and power-law relations for the selected D_A/J values (?2, 0, 1, 2, and 4). The estimated critical exponent values were in good agreement with the universal values of the two-dimensional Ising model (ν = 1, α = α′ = 0, β = 0.125, β′ = 0.875 and γ = γ′ = 1.75).     

Some characteristic phenomena in a transverse Ising nanotube

The phase diagram and magnetizations of a cylindrical nanotube described by the transverse Ising model are investigated by the use of the effective field theory with correlations. Some comparisons between the nanotube and the nanowire have been given for the phase diagrams. In particular, the temperature dependences of longitudinal magnetization in the system with a negative shell–core interaction are investigated. Some characteristic phenomena (new types in ferrimagnetism) which have not been observed in the nanowire as well as similar phenomena are found in the thermal variations, depending on the ratio of the physical parameters in the surface shell and the core. The possibilities of two compensation points and a field induced compensation point in the nanotube are also discussed.     

Ferrimagnetism in two antiferromagnetic transverse Ising thin films

The phase diagrams and temperature dependences of total magnetization m_T in two antiferromagnetic transverse Ising thin films with same thickness L (L = 4), consisting of two (A and B) layers, are studied by the uses of the effective-field theory with correlations and the mean-field theory. The A and B layers are consisted of spin-1/2 atoms and they have opposite spin directions. Two magnetic structures are discussed and they exhibit rather different and characteristic behaviors for the magnetic properties. Many characteristic behaviors observed in standard ferrimagnetic materials as well as novel phenomena have been obtained for the thermal variations of m_T in the both systems, when the crystallographically equivalent conditions between the A and B layers are broken.     

Synthesis, crystal structure and magnetic properties of an Os-containing pillared perovskite La5Os3MnO16

A new Os-containing, pillared perovskite, La₅Os₃MnO₁₆, has been synthesized by solid state reaction in sealed quartz tubes. This extends the crystal chemistry of these materials which had been known only for Mo and Re, previously. The crystal structure has been characterized by X-ray and neutron powder diffraction and is described in space group C-1 with parameters a=7.9648(9) Å; b=8.062(1) Å; c=10.156(2) Å, α=90.25(1)°, β=95.5(1)°; γ=89.95(2)°, for La₅Os₃MnO₁₆. The compound is isostructural with the corresponding La₅Re₃MnO₁₆ phase. A very short Os-Os distance of 2.50(1) Å was found in the dimeric pillaring unit, Os₂O₁₀, suggestive of a triple bond as demanded by electron counting. Nearly spin only values for the effective moment for Os⁵⁺ () and Mn²⁺ () were derived from magnetic susceptibility data. Evidence for magnetic transitions was seen near ∼180 and 80 K. Neutron diffraction data indicate that T_c is 170(5) K. The magnetic structure of La₅Os₃MnO₁₆ at 7 K was solved revealing that Os⁵⁺ and Mn²⁺ form ferrimagnetically coupled layers with antiferromagnetic interlayer ordering. The ordered moments are for Mn²⁺ and for Os⁵⁺, which are reduced from the respective spin only values of 5.0 and . The observation of net ferrimagnetic (antiparallel) intraplanar coupling between Os⁵⁺(t_2g³) and Mn²⁺(t_2g³e_g²) is interesting as it appears to contradict the Goodenough-Kanamori rules for 180° superexchange.