Removal of iron (III) oxide particles from a quartz plate by liquid flow

The detachment of submicron particles of iron (III) oxide from a quartz plate in aqueous solutions was investigated by using a well-defined flow of electro-osmosis in comparison with the ordinary flow of water without electrokinetic effect. A rectangular quartz cell was used for removal experiments. Zeta potentials of the particles and the plate were determined by electrophoresis and electro-osmosis, respectively. When the iron (III) oxide particles adhering to the quartz plate were removed by the electro-osmotic flow or the ordinary (Poiseuille) flow, the removal efficiency increased with increasing hydrodynamic force. The removal efficiency by electro-osmotic flow was almost the same as that by ordinary flow under the condition of the same magnitude of applied hydrodynamic force. The values of volume flow rate for the removal efficiency of 0.5 for the electro-osmotic flow was extremely small compared with that for the ordinary flow, showing the effectiveness of particle removal by electrokinetic effect of electro-osmosis. The kinetic analysis of the particle removal process showed that it was characterized by two different rate constants, the rate constant of the rapid process and that of the slow process. The rate constant of slow process increased with increasing electro-osmotic velocity. This shows that the electro-osmotic flow acts as a mechanical force to overcome the energy barrier in the removal process. The rate constant increased with increasing surfactant concentration and this trend became more noticeable as electro-osmotic velocity increased. It is concluded from this result that the effect of surfactant on particle removal is enhanced by the mechanical force in removal processes.     

电场对含水物料中水分子作用的研究进展

电场解冻、电渗透脱水、高压电场干燥三方面的应用研究越来越受到人们的关注 ,是静电研究的一些新领域 ,为脱水与解冻工作开辟了一条新途径 .大量实验表明这三方面应用研究具有物料不升温、很好的保持物料有效成分和不污染环境等许多优点 .文章综述了近年来这三方面研究在国内外的进展与应用成果 ,认为它们的共性都是电场对含水物料中水分子作用的结果 ,并且对此进行了分析 .     

Formulation of electro-chemico-osmotic processes in soils

Electrokinetic techniques have been used for various purposes including consolidation of soils, dewatering of sludges, and hazardous waste remediation among others. Estimating the feasibility of employing electro-osmosis in a particular operation depends on the ability to predict the outcome under a variety of conditions. Predictions of this type are frequently facilitated by the use of a mathematical model designed to represent the physical system under consideration in a rigorous fashion. First, a review of fundamental aspects of electro-chemico-osmotic flow in soils is presented. Following a brief outline of previous studies, identification and quantification of the significant processes, and the construction of mathematical representations are given. This is achieved using an approach based on the macroscopic conservation of mass equations and the principle of a continuum, in contrast to an approach based on the irreversible thermodynamics of coupled flows. Special emphasis is given to coupling effects on transport processes. A complete model and associated boundary conditions are then obtained for electrokinetic processes in a compressible porous medium. The proposed model takes into consideration the migration of a contaminant plume in a flow field generated by an applied electric potential.Symbols a _v soil compressibility - A an entity - C _w mass fraction of water component in the water phase - C _s mass fraction of chemical component in the water phase - C ^* capacitance of the porous medium per unit volume of porous volume - D mechanical dispersion coefficient - D _fw ^ps hydrodynamic diffusion tensor for the chemical component in the water phase - D _fw ^pw hydrodynamic dispersion coefficient for the water component in the water phase - D _f( )/Dt material derivative with respect to an observer moving at the water phase velocity V _f - D _s( )/Dt material derivative with respect to moving solids - e void ratio - f a function - F = 0 equation of a moving boundary - g gravitational acceleration - k permeability tensor of the porous medium - k _e coefficient of electro-osmotic permeability - k _ec coefficient of migration potential - k _hc chemico-osmotic coupling coefficient - m _i number of moles of the ith component - m _i0 number of moles of the ith component at a reference level - n porosity - p pore pressure - p _oi pore pressure at a reverence level - q specific discharge of water phase - q _e current density - q _fe ^p0 constant current density applied at a boundary - q ₀ constant flow rate - q _r specific discharge of the water phase relative to the moving solid matrix - R net mass transfer rate of the chemical component in the water phase - t time - u velocity of a moving surface - _i partial molar density of ith component - V _f velocity of the water phase - V _s velocity of the solid (rate of deformation) - x vertical coordinate - coefficient of matrix compressibility - _p compressibility of water phase in motion - total (overburden) stress tensor - effective stress tensor - _h streaming current conductivity - _e electrical conductivity - electrical potential - _f viscosity of the water phase - _hf density of the water phase     

The detachment of nylon particles from quartz plate by electro-osmotic flow

The direct application of electrokinetic phenomena to detergency was investigated. Experiments were carried out to remove particles from substrate by electro-osmosis. A model system which consisted of spherical nylon particles of 5m in mean diameter, a quartz plate, and wash liquid were used in analyzing the kinetic process of particle removal from substrate. When an electric field was applied to the system, electro-osmotic flow took place, and hence the particles were removed from the quartz surface. The -potentials of nylon particles and quartz plate were measured by electrophoresis. The rate constants of removal,, were obtained from the changes with time in the ratio of particle residue by applying the first-order reaction scheme. The value of increased with increasing electric field and with increasing concentration of surfactant. The total force of interaction between particle and plate was calculated on the basis of heterocoagulation theory of colloid stability.It was found from results thus obtained that the hydrodynamic force due to the electro-osmotic flow worked effectively as a mechanical force on the removal process and the adhesion force of particle to substrate reduced by adding surfactant.     

Permeate flux inflection due to concentration polarization in crossflow membrane filtration: A novel analytic approach

A convection-diffusion equation for membrane filtration is analytically solved assuming fast crossflow velocity of a simple shear flow tangential to the membrane surface. In the direction normal to the membrane surface, solute concentration varies in a partially exponential and partially power-wise manner. The permeate flux in an asymptotic limit is proportional to the inverse square root of the distance from the inlet of the membrane channel. Osmotic pressure due to retained solutes on the membrane surface controls the profile of the permeate flux, which undergoes an inflection along the tangential direction if applied pressure is more than four times the feed osmotic pressure.     

Debye-Hückel solution for steady electro-osmotic flow of micropolar fluid in cylindrical microcapillary

Analytic expressions for speed, flux, microrotation, stress, and couple stress in a micropolar fluid exhibiting a steady, symmetric, and one-dimensional electro-osmotic flow in a uniform cylindrical microcapillary were derived under the constraint of the Debye-Hiickel approximation, which is applicable when the cross-sectional radius of the microcapillary exceeds the Debye length, provided that the zeta potential is sufficiently small in magnitude. Since the aciculate particles in a micropolar fluid can rotate without translation, micropolarity affects the fluid speed, fluid flux, and one of the two non-zero components of the stress tensor. The axial speed in a micropolar fluid intensifies when the radius increases. The stress tensor is confined to the region near the wall of the mi- crocapillary, while the couple stress tensor is uniform across the cross-section.     

Debye-H¨uckel solution for steady electro-osmotic flow of micropolar fluid in cylindrical microcapillary

Analytic expressions for speed, flux, microrotation, stress, and couple stress in a micropolar fluid exhibiting a steady, symmetric, and one-dimensional electro-osmotic flow in a uniform cylindrical mi...     

Transport of Multi-Electrolytes in Charged Hydrated Biological Soft Tissues

A mechano-electrochemical theory for charged hydrated soft tissues with multi-electrolytes was developed based on the continuum mixture theory. The momentum equations for water and ions were derived in terms of a mechanochemical force (gradient of water chemical potential), electrochemical forces (gradient of Nernst potentials) and an electrical force (gradient of electrical potential). The theory was shown to be consistent with all existing specialized theories. Using this theory, some mechano-electrokinetic properties of charged isotropic tissues were studied. The well-known Hodgkin–Huxley equation for resting cell membrane potential was derived and the phenomenon of electro-osmotic flow in charged hydrated soft tissues was investigated. Analyses show that the tissue fixed charge density plays an important role in controlling the transport of water and ions in charged hydrated soft tissues.     

Electrical field-induced extraction and separation techniques: Promising trends in analytical chemistry – A review

Sample preparation is an important issue in analytical chemistry, and is often a bottleneck in chemical analysis. So, the major incentive for the recent research has been to attain faster, simpler, less expensive, and more environmentally friendly sample preparation methods. The use of auxiliary energies, such as heat, ultrasound, and microwave, is one of the strategies that have been employed in sample preparation to reach the above purposes. Application of electrical driving force is the current state-of-the-art, which presents new possibilities for simplifying and shortening the sample preparation process as well as enhancing its selectivity. The electrical driving force has scarcely been utilized in comparison with other auxiliary energies. In this review, the different roles of electrical driving force (as a powerful auxiliary energy) in various extraction techniques, including liquid-, solid-, and membrane-based methods, have been taken into consideration. Also, the references have been made available, relevant to the developments in separation techniques and Lab-on-a-Chip (LOC) systems. All aspects of electrical driving force in extraction and separation methods are too specific to be treated in this contribution. However, the main aim of this review is to provide a brief knowledge about the different fields of analytical chemistry, with an emphasis on the latest efforts put into the electrically assisted membrane-based sample preparation systems. The advantages and disadvantages of these approaches as well as the new achievements in these areas have been discussed, which might be helpful for further progress in the future.     

Adhesion of nylon particles to a quartz plate in an aqueous solution and their removal by electro-osmosis

Particle removal by electro-osmotic flow was investigated by comparison with the removal by ordinary flow of water without electrokmetic effect. The relationship between adhesion and removal of particles in terms of force acting on the particle was also discussed. Experiments were carried out in an aqueous solution using nylon particles and a quartz plate. The adhesive force,F _T, for the particles which adhered to the quartz plate in secondary minima in the total potential energy of interaction versus separation distance curves was calculated. Particle removal experiments were carried out applying electro-osmotic and Poiseuille flows. The hydrodynamic force,F _d, which was required to remove particles from the plate was estimated using flow velocities. The effectiveness of electro-osmotic flow on particle removal was larger than that of Poiseuille flow. In the particle removal by electro-osmotic flow, the minimum of the ratioF _d/F _t for particle removal was found to be 50 and the ratio for removal efficiency of 0.5 was about 140.