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1.
《Mendeleev Communications》2022,32(6):777-779
The reactions of aryllithium reagents o-LiC6H4CH2NR2 with (MeO)2CO afford two new tris(aryl)carbinols bearing pendant-NR2 donor groups in the side chain [o-R NCH C H ] COH [R = Me, R + R = (CH) ]. These alcohols feature helical chirality due to differently inclined aromatic fragments and are presented in a crystalline cell as two M and P enantiomers. Carbinol (R = Me) readily reacts with (Me3SiCH2)3Sc(THF)2 to give a scandium bis(alkyl) complex [(o-C6H4CH2NMe2)3CO]Sc(CH2SiMe3)2 featuring rigid binding of the alkoxy anion through a κ1-O, κ2-N chelating coordination mode 相似文献
2.
The theory of free-carrier absorption (FCA) is developed, in the extreme quantum limit when the carriers are assumed to populate
only the lowest quantized energy level, for quasi-two and one-dimensional semiconducting quantum well structures where the
carriers are scattered by ionized impurities. The radiation field is assumed to be polarized in the plane of the layer in
the quasi-two-dimensional case and along the length of the wire in the quasi-one-dimensional case. Expressions for FCA are
obtained for the cases where the impurities are either in the well (background impurities) or outside the well (remote impurities).
Variation of FCA is numerically studied with photon frequency and well width. 相似文献
3.
Absorption and luminiscence measurements were performed on lead-doped KCl:KI mixed single crystals. Strong differences were found between as-grown and quenched samples. New bands were observed in the absorption spectra of unquenched samples in the spectral region between the limit positions of the A bands, corresponding to chloride or iodide lattices. The strong band at 449 nm dominates the luminescence of these samples at low temperatures. Its kinetics have a complicated form and the decay time is in the interval from ns to ms. Quenched samples have a well-known luminescence spectrum caused by octahedral lead impurity centres in KCl single crystals. The kinetics, however, also indicate mixed chlorine and iodine coordination of lead in the investigated crystals. 相似文献
4.
T. K. Solovykh 《Journal of Applied Spectroscopy》1997,64(5):654-657
The role of impurity ions in formation of the optical properties of rare-earth orthoferrites is investigated. Optical spectra
of the substituted against unsubstituted orthoferrites are presented. The influence of different isovalent substitutions on
the optical absorption of orthoferrites that are promising for magnetooptics is studied.
Institute of Solid-State and Semiconductor Physics of the Academy of Sciences of Belarus, 17, P. Brovka St., Minsk, 220072,
Belarus. Translated from zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 5, pp. 642–645, September–October, 1997. 相似文献
5.
6.
Nongelatin dichromated holographic film(NGD) is a new holographic recordingmaterial.Holograms recorded on this material have better environmental stability, higherdiffraction efficiency and stronger real time effect, etc..An experimental study to ascertainthe influence of two electron donors, namely,N,N-dimethylformamide(DMF) and dimethyl-sulfoxide(DMSO),on the real time diffraction efficiency(RTDE) of NGD holograms is car-ried out.The pressence of electron donors not only improves the sensitivity,but also enhancesthe real time effect greatly.RTDE of above 60% at±1 orders of NGD plane transimissiongrating is achieved by introducing electron donors. 相似文献
7.
8.
We have studied the characteristic features of carbazole phosphorescence quenching by benzophenone in toluene at 77 K. We
have shown that the decrease in the relative phosphorescence intensity for carbazole (energy donor) by a greater factor than
we see for the relative change in its decay time is due to the fact that a change in the phosphorescence decay time occurs
only for carbazole molecules participating in triplet-triplet energy transfer, while the substantial decrease in the phosphorescence
intensity for carbazole with no change in the phosphorescence decay time is connected with quenching of its singlet states.
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 4, pp. 554–556, July–August, 2006. 相似文献
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10.
研究了有机杂质以及抗有机杂质添加剂对镀镍过程中阴极极化性能的影响.实验结果表明,有机杂质增大了阴极极化,而抗有机杂质添加剂却能减小阴极极化.实验结果还显示,添加剂消除有机杂质污染的效果同其降低阴极极化的能力密切相关 相似文献