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排序方式: 共有7917条查询结果,搜索用时 31 毫秒
1.
Dr. Sebastian Lars Müller Xinglong Zhou Dr. Peter Leonard Oxana Korzhenko Dr. Constantin Daniliuc Prof. Dr. Frank Seela 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(12):3077-3090
Silver-mediated α-dC–Ag+–β-dC hybrid base pairs decorated with 5-iodo- or 5-octadiynyl residues are well accommodated in duplex DNA. A strong Tm increase and favorable thermodynamic data for duplex DNA were observed after addition of silver ions. The phenomenon is particularly obvious when both nucleobases of the base pairs are functionalized. Neither the position of the base pair, nor the type of 5-substituent had a negative influence. On the contrary, functionalization of conventional silver-mediated β-dC–Ag+–β-dC homo base pairs showed a negative impact induced by the bulky substituents. To this end, cytosine modified 12-mer oligodeoxynucleotides were prepared by solid-phase synthesis employing new α-anomeric 2′-deoxycytidine phosphoramidites. A multigram scale synthesis was developed for 5-iodo-α-d -2′-deoxycytidine ( 1 ) employing the direct glycosylation of cytosine with Hoffer's α-d -halogenose followed by separation of anomeric DMT nucleosides. Regarding base-pair stability and functionalization silver-mediated α/β-dC hybrid base pairs were found to be superior to β/β-dC homo pairs. According to their extraordinary properties, they might find applications in DNA diagnostics, material science, or nanotechnology. 相似文献
2.
3.
Thomas Wittmann Dr. Renée Siegel Nele Reimer Dr. Wolfgang Milius Prof. Dr. Norbert Stock Prof. Dr. Jürgen Senker 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(1):314-323
The resistance of metal–organic frameworks towards water is a very critical issue concerning their practical use. Recently, it was shown for microporous MOFs that the water stability could be increased by introducing hydrophobic pendant groups. Here, we demonstrate a remarkable stabilisation of the mesoporous MOF Al‐MIL‐101‐NH2 by postsynthetic modification with phenyl isocyanate. In this process 86 % of the amino groups were converted into phenylurea units. As a consequence, the long‐term stability of Al‐MIL‐101‐URPh in liquid water could be extended beyond a week. In water saturated atmospheres Al‐MIL‐101‐URPh decomposed at least 12‐times slower than the unfunctionalised analogue. To study the underlying processes both materials were characterised by Ar, N2 and H2O sorption measurements, powder X‐ray diffraction, thermogravimetric and chemical analysis as well as solid‐state NMR and IR spectroscopy. Postsynthetic modification decreased the BET equivalent surface area from 3363 to 1555 m2 g?1 for Al‐MIL‐101‐URPh and reduced the mean diameters of the mesopores by 0.6 nm without degrading the structure significantly and reducing thermal stability. In spite of similar water uptake capacities, the relative humidity‐dependent uptake of Al‐MIL‐101‐URPh is slowed and occurs at higher relative humidity values. In combination with 1H‐27Al D ‐HMQC NMR spectroscopy experiments this favours a shielding mechanism of the Al clusters by the pendant phenyl groups and rules out pore blocking. 相似文献
4.
Matt Visser Carlos Barceló Stefano Liberati 《General Relativity and Gravitation》2002,34(10):1719-1734
Condensed matter systems, such as acoustics in flowing fluids, light in moving dielectrics, or quasiparticles in a moving superfluid, can be used to mimic aspects of general relativity. More precisely these systems (and others) provide experimentally accessible models of curved-space quantum field theory. As such they mimic kinematic aspects of general relativity, though typically they do not mimic the dynamics. Although these analogue models are thereby limited in their ability to duplicate all the effects of Einstein gravity they nevertheless are extremely important—they provide black hole analogues (some of which have already been seen experimentally) and lead to tests of basic principles of curved-space quantum field theory. Currently these tests are still in the realm of gedanken-experiments, but there are plausible candidate models that should lead to laboratory experiments in the not too distant future. 相似文献
5.
属间远缘杂交水稻耐旱性生理特性的比较研究 总被引:4,自引:0,他引:4
采用在YOSHIDA水稻专用培养营养液中添加一定量的PEG 6000的方法,比较研究了模拟干旱胁迫条件下属间远缘杂交新型水稻品种“远诱1号”(Y)及其水稻亲本“圭630”(G)、高梁亲本“桃长红”(T)以及生产推广杂交组合“汕优63”(S)等试验材料某些生态生理特性的差异。研究结果表明,在-1.0MPa的高渗胁迫下,Y、G、T的萌发系数均有不同程度的下降,正常培养条件下的萌发系数GC分别为36.9 相似文献
6.
The dependence of the beam propagation factor (M
2 parameter) with the absorbed pump power in the case of monolithic microchip laser under face-cooled configuration is extensively
studied. Our investigations show that the M
2 parameter is related to the absorbed pump power through two parameters (α and β) whose values depend on the laser material properties and laser configuration. We have shown that one parameter arises due
to the oscillation of higher order modes in the microchip cavity and the other parameter accounts for the spherical aberration
associated with the thermal lens induced by the pump beam. Such dependency of M
2 parameter with the absorbed pump power is experimentally verified for a face-cooled monolithic microchip laser based on Nd3+ -doped GdVO4 crystal and the values of α and β parameters were estimated from the experimentally measured data points. 相似文献
7.
固体间界面的物理模型和界面对声波的反射 总被引:4,自引:0,他引:4
简要描述了模拟两固体间界面特性的弹簧模型,该模型最早是根据静力学方法提出的,后来用固体间界面薄层的声波反射方法加以改进,从界面弹簧模型可以方便地得到界面外近似边界条件,其中包含界面“弹簧”振子的劲度常数和质量,文章还给出了两相间固体中界面声反射系数的表达式,介绍了测量界面劲度常数的超声反射谱方法。最后讨论了仍关声波与界面相互作用研究领域中最近的一些研究进展。 相似文献
8.
9.
Zhao Hanzhong 《Acta Mechanica Solida Sinica》2002,15(2):156-162
A finite difference/boundary integral procedure to determine the acoustic reflected pressure from a fluid-loaded bi-laminated
plate is described. The bi-laminate is composed of a piezoelectric layer and an elastic layer in contact with the fluid, and
is held by an acoustically hard baffle. In the numerical model, the fluid pressure at fluid/solid interface is replaced by
a continuum of point sources weighted by the normal acceleration of the elastic plate, and the governing equation system is
solved in the solid domain. With the normal acceleration found, the reflected pressure in the fluid is determined by an integral
expression involving the Green's function. It is demonstrated that an appropriate applied voltage potential across the piezoelectric
layer has the effect of cancelling either the reflected or scattered pressure of the plate at any chosen field points in the
fluid.
Project supported by the National Natural Science Foundation of China (No. 10172039). 相似文献
10.
混合判断矩阵排序方法研究 总被引:2,自引:0,他引:2
本文介绍了混合判断矩阵及完全一致性混合判断矩阵的概念,提出了混合判断矩阵排序的一种最小偏差法,并给出了其收敛性迭代算法,最后通过算例说明了方法的可行性。 相似文献