全文获取类型
收费全文 | 5034篇 |
免费 | 1124篇 |
国内免费 | 247篇 |
专业分类
化学 | 1860篇 |
晶体学 | 190篇 |
力学 | 467篇 |
综合类 | 72篇 |
数学 | 453篇 |
物理学 | 3363篇 |
出版年
2024年 | 8篇 |
2023年 | 32篇 |
2022年 | 109篇 |
2021年 | 96篇 |
2020年 | 98篇 |
2019年 | 99篇 |
2018年 | 109篇 |
2017年 | 216篇 |
2016年 | 281篇 |
2015年 | 177篇 |
2014年 | 323篇 |
2013年 | 614篇 |
2012年 | 335篇 |
2011年 | 328篇 |
2010年 | 296篇 |
2009年 | 287篇 |
2008年 | 319篇 |
2007年 | 288篇 |
2006年 | 319篇 |
2005年 | 278篇 |
2004年 | 211篇 |
2003年 | 205篇 |
2002年 | 220篇 |
2001年 | 145篇 |
2000年 | 155篇 |
1999年 | 136篇 |
1998年 | 103篇 |
1997年 | 88篇 |
1996年 | 75篇 |
1995年 | 84篇 |
1994年 | 60篇 |
1993年 | 46篇 |
1992年 | 38篇 |
1991年 | 30篇 |
1990年 | 29篇 |
1989年 | 20篇 |
1988年 | 18篇 |
1987年 | 14篇 |
1986年 | 12篇 |
1985年 | 17篇 |
1984年 | 18篇 |
1983年 | 3篇 |
1982年 | 14篇 |
1981年 | 12篇 |
1980年 | 5篇 |
1978年 | 6篇 |
1977年 | 4篇 |
1976年 | 7篇 |
1975年 | 3篇 |
1973年 | 4篇 |
排序方式: 共有6405条查询结果,搜索用时 31 毫秒
1.
Saqib Kamal Arif I. Inamdar Kuan-Ru Chiou Batjargal Sainbileg Muhammad Usman Jenq-Wei Chen Tzuoo-Tsair Luo Michitoshi Hayashi Chen-Hsiung Hung Wen-Feng Liaw Kuang-Lieh Lu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(30):e202103905
The dielectric properties of coordination polymers has been a topic of recent interest, but the role of different functional groups on the dielectric properties of these polymers has not yet been fully addressed. Herein, the effects of electron-donating (R=NH2) and electron-withdrawing (R=NO2) groups on the dielectric behavior of such materials were investigated for two thermally stable and guest-free Zn-based coordination polymers, [Zn(L1)(L2)]n ( 1 ) and [Zn(L1)(L3)]n ( 2 ) [L1=2-(2-pyridyl) benzimidazole (Pbim), L2=5-aminoisophthalate (Aip), and L3=5-nitroisophthalate (Nip)]. The results of dielectric studies of 1 revealed that it possesses a high dielectric constant (κ=65.5 at 1 kHz), while compound 2 displayed an even higher dielectric constant (κ=110.3 at 1 kHz). The electron donating and withdrawing effects of the NH2 and NO2 substituents induce changes in the polarity of the polymers, which is due to the inductive effect from the aryl ring for both NO2 and NH2. Theoretical results from density functional theory (DFT) calculations, which also support the experimental findings, show that both compounds have a distinct electronic behavior with diverse wide bandgaps. The significance of the current work is to provide information about the structure-dielectric property relationships. So, this study promises to pave the way for further research on the effects of different functional groups on coordination polymers on their dielectric properties. 相似文献
2.
Chao Liu Liying Wang Lin Yang Famei Wang Chunhong Xu Jingwei Lv Guanglai Fu Xianli Li Qiang Liu Haiwei Mu Tao Sun Paul K. Chu 《Physics letters. A》2019,383(25):3200-3206
A single-polarization filter comprising a gold-coated photonic crystal fiber based on surface plasmon resonance is designed and investigated. The pattern matching and coupled polarization characteristics analyzed by the full-vector finite element method (FEM) and losses at 1,540 nm are achieved to 1,016.01739 dB/cm (x-pol core mode) and 33.81917 dB/cm (y-pol core mode). The crosstalk (CT) value of the 1,540 nm band is ?853.12653 dB for fiber length and the bandwidth is 850 nm. The working wavelength of the filter ranges from 1,280 nm to 1,540 nm by varying the diameter of outer air holes (), the diameter of inner air holes (), the metal film thickness (t), as well as the liquid refractive index (n). 相似文献
3.
Sha Xia Dan Wang Nian-Ke Chen Dong Han Xian-Bin Li Hong-Bo Sun 《Annalen der Physik》2020,532(3):1900318
Defects play a central role in controlling the electronic properties of two-dimensional (2D) materials and realizing the industrialization of 2D electronics. However, the evaluation of charged defects in 2D materials within first-principles calculation is very challenging and has triggered a recent development of the WLZ (Wang, Li, Zhang) extrapolation method. This method lays the foundation of the theoretical evaluation of energies of charged defects in 2D materials within the first-principles framework. Herein, the vital role of defects for advancing 2D electronics is discussed, followed by an introduction of the fundamentals of the WLZ extrapolation method. The ionization energies (IEs) obtained by this method for defects in various 2D semiconductors are then reviewed and summarized. Finally, the unique defect physics in 2D dimensions including the dielectric environment effects, defect ionization process, and carrier transport mechanism captured with the WLZ extrapolation method are presented. As an efficient and reasonable evaluation of charged defects in 2D materials for nanoelectronics and other emerging applications, this work can be of benefit to the community. 相似文献
4.
Tatiana Monaretto Andre Souza Tiago Bueno Moraes Victor Bertucci-Neto Corinne Rondeau-Mouro Luiz Alberto Colnago 《Magnetic resonance in chemistry : MRC》2019,57(9):616-625
The traditional way to enhance signal-to-noise ratio (SNR) of nuclear magnetic resonance (NMR) signals is to increase the number of scans. However, this procedure increases the measuring time that can be prohibitive for some applications. Therefore, we have tested the use of several post-acquisition digital filters to enhance SNR up to one order of magnitude in time domain NMR (TD-NMR) relaxation measurements. The procedures were studied using continuous wave free precession (CWFP-T1) signals, acquired with very low flip angles that contain six times more noise than the Carr–Purcell–Meiboom–Gill (CPMG) signal of the same sample and experimental time. Linear (LI) and logarithmic (LO) data compression, low-pass infinity impulse response (LP), Savitzky–Golay (SG), and wavelet transform (WA) post-acquisition filters enhanced the SNR of the CWFP-T1 signals by at least six times. The best filters were LO, SG, and WA that have high enhancement in SNR without significant distortions in the ILT relaxation distribution data. Therefore, it was demonstrated that these post-acquisition digital filters could be a useful way to denoise CWFP-T1, as well as CPMG noisy signals, and consequently reducing the experimental time. It was also demonstrated that filtered CWFP-T1 method has the potential to be a rapid and nondestructive method to measure fat content in beef and certainly in other meat samples. 相似文献
5.
Zhong Yin Xiao 《International Journal of Infrared and Millimeter Waves》2006,27(6):847-855
A new compact bandpass filter composed of two coupled linear tapered line resonators (LTLRs) is designed. The two resonators
are arranged in different layers. The filter has two transmission zeros on both sides of the passband. It has small size and
steep response below its passband. It is also shown that this filter has 0.6 dB low insertion loss at the centre frequency
and 10.5% 3dB bandwidth.
This work was supported by the Development Foundation of Shanghai Educational Committee (217608) and Shanghai Leading Academic
Discipline Project (T0102). 相似文献
6.
直流稳压电源可以将交流电压变换为直流电压,并使之稳定,在我们现实生活中应用很广泛,在实验中我们利用的电学知识,设计制造了一种直流稳压电源。本文简要介绍了这种直流稳压电源波形演示器的设计目的和电路原理,重点阐述了它的制作流程、滤波和稳压原理以及性能测试输出波形。 相似文献
7.
8.
9.
Weidong Gao Meiqiong Zhan Shuhai Fan Janda Shao Zheng-Xiu Fan 《Applied Surface Science》2005,250(1-4):195-202
The laser-induced damage (LID) behavior of narrow-band interference filters was investigated with a Nd:YAG laser at 1064 nm under single-pulse mode and free-running mode. The absorption measurement of such coatings was performed with surface thermal lensing (STL) technique. The damage morphologies under the two different laser modes were also studied in detail. It was found that all the filters exhibited a pass-band-center-dependent absorption and laser-induced damage threshold (LIDT) behavior, but the damage morphologies were diverse. The explanation was given with the analysis of the electric field distribution and the operational behavior of the irradiation laser. 相似文献
10.
In this paper the performances of inhomogeneous dielectric slabs as solar light collectors for both illumination and solar energy applications are analysed. 相似文献