菱镁矿风化石与叶腊石合成堇青石的结构表征

采用菱镁矿风化石、叶腊石、二氧化硅微粉为主要原料,研究分析烧成温度对合成堇青石结晶度、晶粒尺寸、晶相组成和显微结构来确定适宜的合成温度。用X′ Pert plus软件对X射线衍射图进行拟合,分析试样的结晶度,用半定量(semi-quantification)法对试样结晶相中晶相组成进行计算,用Scherrer公式计算试样中堇青石、方石英晶粒的粒径大小。结果表明：采用菱镁矿风化石与叶腊石为原料合成堇青石,当温度由1 350 ℃增加到1 400 ℃,试样的结晶度增加,堇青石晶粒尺寸和堇青石相量增加,在1 400 ℃时,试样结晶度最高,晶粒尺寸最大。晶相组成中堇青石相占67%,方石英相占33%。当温度大于1 400 ℃,试样结晶度降低,堇青石和方石英晶粒尺寸减小,当温度在1 500 ℃时,堇青石相消失,促进了方石英相析出。采用菱镁矿风化石与叶腊石为原料合成堇青石的最佳烧成温度为1 400 ℃。     

Schemata, Distributions and Graphical Models in Evolutionary Optimization

In this paper the optimization of additively decomposed discrete functions is investigated. For these functions genetic algorithms have exhibited a poor performance. First the schema theory of genetic algorithms is reformulated in probability theory terms. A schema defines the structure of a marginal distribution. Then the conceptual algorithm BEDA is introduced. BEDA uses a Boltzmann distribution to generate search points. From BEDA a new algorithm, FDA, is derived. FDA uses a factorization of the distribution. The factorization captures the structure of the given function. The factorization problem is closely connected to the theory of conditional independence graphs. For the test functions considered, the performance of FDA—in number of generations till convergence—is similar to that of a genetic algorithm for the OneMax function. This result is theoretically explained.     

香港全风化花岗岩饱和直剪试验中的剪胀问题

通过对全风化花岗岩的慢剪试验,指出了在直剪试验中出现的两种垂直位移变化形式,其对土体的剪胀剪缩性质的 反映与三轴试验是一致的。剪胀的发生与土体的密实程度密切相关;随垂直压力的增大,剪胀发生所需剪应力也增大;剪应 力达到峰值所需要剪位移总是比剪胀发生时所需的剪位移大。     

食用油脂质过氧化的气相色谱／质谱法定性研究

食用油受热或放置时间过长会产生一系列自由基反应形成脂质过氧化物,并进一步分解成含羰基、环氧基等小分子化合物。用气相色谱／质谱联用方法对存放不同时间的５份食用油中挥发性的脂质过氧化分解物进行了定性分析。在存放２年和３年的食用油中分别鉴别出８和１６个化合物。己醛、２,４－癸二烯醛相对含量较高。     

Inexact Newton method via Lanczos decomposed technique for solving box-constrained nonlinear systems

This paper proposes an inexact Newton method via the Lanczos decomposed technique for solving the box-constrained nonlinear systems. An iterative direction is obtained by solving an affine scaling quadratic model with the Lanczos decomposed technique. By using the interior backtracking line search technique, an acceptable trial step length is found along this direction. The global convergence and the fast local convergence rate of the proposed algorithm are established under some reasonable conditions. Furthermore, the results of the numerical experiments show the effectiveness of the pro- posed algorithm.     

Adsorption behaviour of SO2 and SOF2 gas on Rh-doped BNNT: a DFT study

Abstract

As the insulating medium, SF₆ is widely used in gas insulation equipment. Partial discharge and local overheating can cause the decomposition of SF₆, resulting in a decrease in insulation strength of the equipment. The detection of SF₆ decomposition gas can be used for on-line insulation detection of gas insulation equipment in electric power industry. In order to develop a new sensor gas sensing material for gas detecting. In this work, based on the first-principles density functional calculation (DFT) method of DMol³, the adsorption of SF₆ decomposition gas on (5,0) Z-type Rh-BNNT in different ways was explored. The adsorption energy, adsorption distance, charge transfer as well as density of states were discussed. The results show that the adsorption strength between SO₂ molecule with Rh-BNNT is larger than with SOF₂ molecule, combined with desorption time, theoretically predicts Rh -BNNT have the potential to be a material for SO₂ gas sensors.     

Curing and mechanical behavior of carboxylated NBR containing hygrothermally decomposed polyurethane

Hygrothermally decomposed polyester-urethane (HD-PUR) has been added as modifier (up to 20 phr) to sulfur crosslinked carboxylated nitrile rubber (XNBR). The curing and mechanical characteristics of the XNBR have been investigated as a function of the HD-PUR loading in presence and absence of carbon black (CB). The addition of HD-PUR increased the cure rate of both unfilled and CB filled XNBR but resulted in compounds of lower crosslink density and thus of lower stiffness and strength. Based on infrared spectroscopic results it was speculated that the amine functionality of HD-PUR affected the formation of the ionic clusters formed by the reaction between the -COOH groups of XNBR and ZnO. This occurred likely via a coordination complex. Evidence was also found for the formation of -CONH- linkages. Both coordination complexing and chemical reaction between -COOH and -NH₂ resulted in a lower overall “crosslinking degree” and as a consequence HD-PUR acted as plasticizer in XNBR.     

微波消解技术在难溶贵金属(铂)化合物分析中的应用

本文提出了微波密闭消解处理难溶贵金属化合物Pt（NH3）4Cl2、Pt（NH3）2Cl2、Pt（NH3）2（NO2）2和K2PtCl4的方法；对比了它们的微波密闭消解和传统分解条件；分析了消解后Pt的含量。结果表明：上述各类化合物对应消解时间分别为传统分解法的1／15、1／13和1／11；分析手段随之简化且总分析流程大大缩短；两种方法测得的Pt含量吻合。     

Die chemische Zersetzung von Seltenerd-Nitraten: Eine neue Methode zur Anreicherung schwerer Yttererdnitrate im kg-Maßstab

Summary On addition of oxidizable organic substances to molten rare earth nitrates reaction takes place with evolution of nitric oxides and formation of basic nitrates, the two-step hydrolysis of which results in effective enrichment of heavy yttrium earths (YE) from rare earth mixtures in kg-quantities. Using methanol as reducing agent the reaction takes place at 160°C, much lower than using the method of purely thermal decomposition. In both methods after the first hydrolysis step a productYE(OH)_1.5(NO₃)_1.5·H₂O can be isolated.

     

Equivalence of refined theory and decomposed theorem of an elastic plate

Introduction Ahomogeneous,isotropicplateoccupiestheregion Ω=(x1,x2,x3)｜(x1,x2)∈D,｜x3｜≤h/2,(1) whereDisthecross_sectionoftheplatewhichhasthicknessh.Supposethattwofaces,x3= ±h/2,(x1,x2)∈Darefreeoftractions. Ifstressstateoftheplateisanti_symmetricalaboutmid_planex3=0,thisinducesσ11,σ22, σ33andσ12aretheoddfunctionsaboutx3,σ31andσ23aretheevenfunctionsaboutx3.Usually,theyarecalledtheplate“bending”. Manyauthorsgavevariousplatetheories.TheClassicplatetheoryandReissner’splate theory…