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1.
The structure and rotational barrier for the mesityl-silicon bond of 2,2-dimesityl-1,1,1,3,3,3-hexamethyltrisilane have been investigated by 1H- and 13C-variable temperature nuclear magnetic resonance (NMR) as well as by density functional theory structural calculations. The calculations show that the lowest energy structure has C2 symmetry with nonequivalent ortho methyl groups, consistent with the crystal structure and solution NMR. The nonequivalent ortho methyl groups exchange through a Cs transition state with a calculated relative free energy of 11.0 kcal mol−1. The barrier for this rotation found by dynamic NMR is 13.4 ± 0.2 kcal mol−1 at 298 K. 相似文献
2.
The sunset diagram of λφ4 theory is evaluated numerically in cutoff scheme and a nonzero finite term(in accordance with dimensional regularization (DR) result) is found in contrast to published calculations. This findingdramatically reduces the critical couplings for symmetry breaking in the two-loop effective potential discussed in ourprevious work. 相似文献
3.
A new unified electroweak model is proposed in this paper. In this unified electroweak model, Higgsmechanism is not used, so no Higgs particle exists in the model. In order to keep the masses of intermediate gaugebosons non-zero, two sets of gauge fields will be introduced. In order to introduce symmetry breaking and to help tointroduce the masses of all fields, a vacuum potential is needed. Except for those terms concerning Higgs particle, thefundamental dynamical properties of this model are similar to those of the standard model. And in a proper limit, thismodel will approximately return to the standard model. The purpose of this paper is not to say that the Higgs particledoes not exist in Nature, it is only to prove that, without a Higgs particle, we can also set up a unified electroweak modelwhich is consistent with present experiments. 相似文献
4.
加肋圆柱壳在轴压作用下的屈曲和后屈曲 总被引:2,自引:2,他引:0
本文讨论完善和非完善的,纵向加肋和正交加肋圆柱壳在轴压作用下的屈曲和后屈曲性态.依据文[1]提供的圆柱薄壳屈曲的边界层理论及其分析方法,给出了加肋圆柱壳在轴压作用下的屈曲和后屈曲理论分析.本文同时讨论肋骨与壳板材料不同时对加肋圆柱壳屈曲和后屈曲性态的影响. 相似文献
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As borders between different entities, lines are an important element of natural images. Indeed, the neurons of the mammalian
visual cortex are tuned to respond best to lines of a given orientation. This preferred orientation varies continuously across
most of the cortex, but also has vortex-like singularities known as pinwheels. In attempting to describe such patterns of
orientation preference, we are led to consider underlying rotation symmetries: Oriented segments in natural images tend to
be collinear; neurons are more likely to be connected if their preferred orientations are aligned to their topographic separation.
These are indications of a reduced symmetry requiring joint rotations of both orientation preference and the underlying topography.
This is verified by direct statistical tests in both natural images and in cortical maps. Using the statistics of natural
scenes we construct filters that are best suited to extracting information from such images, and find qualitative similarities
to mammalian vision.
PACS84.35+i 89.70.+c 87.57.Nk 相似文献
8.
设V是一个n维线性空间,V_x~m(G)为V上的张量对称类.A为V的线性算子T的矩阵,K(A)为V_x~m(G)上的诱导线性算子K(T)的矩阵.本文从K(A)的数值半径Υ(K(A))和可分数值半径Υ_x(K(A))定义出发,研究了Υ(K(A))、Υ_x(K(A))与范数||A||_p(1≤p≤2)、广义矩阵函数d_x~G(A)的关系,得到了它们之间的两个不等式. 相似文献
9.
The general stability of single-layer cylindrical grids is studied in linear and nonlinear formulations. Dependence of the general buckling load on the geometry and stiffness parameters of a grid is established in an analytical form. Such grids are numerically analyzed for stability. It is established that the general buckling load is much less than the local buckling load. Typical general buckling modes are found. It is shown that such grids are weakly sensitive to imperfections 相似文献
10.
在二极管泵浦固体激光器耦合光学系统中,柱面透镜起着非常重要的作用。随着系统轻量化、小型化的要求需要用重量轻、尺寸小的光学器件来替代。本文介绍一种用于替代柱面透镜的二元光学元件的设计和制作方法。 相似文献