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1.
Aggregated aromatic molecule--cyclodextrin-precipitant complexes exhibit long-lived phosphorescence at room temperature in water after the chemical binding of oxygen. The temperature dependences of the phosphorescence lifetimes of naphthalene-h8, naphthalene-de, and phenanthrene in the aggregates were measured. For example, the phosphorescence lifetimes of naphthalene-d8 aggregated with -cyclodextrin and cyclohexane are equal to 25.1, 17.6, and 6.8 s at 77, 276, and 347 K, respectively, and that of phenanthrene aggregated with isooctane and -cyclodextrin are 3.24, 3.06, and 1.26 s at 268, 274, and 335 K, respectively. The temperature dependences of the phosphorescence lifetimes at room temperature are determined by the rate constants of the radiative and nonradiative transitions from the triplet state of an aromatic molecule.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2225–2228, September, 1996.  相似文献   
2.
A diaphragm cell has been used to measure mutual diffusion coefficients at 25°C for four binary nonelectrolyte mixtures: ethylbenzene + n-hexane, carbon tetrachloride + ethylbenzene, cyclohexane + p-xylene, and 1,2-dichloroethane + cyclohexane. A free-volume predictive approach for binary mutual diffusion coefficients was developed and tested. Only infinite dilution diffusion coefficients, some readily available pure substance data, and UNIFAC group contribution parameters are used in the model. No binary equilibrium thermodynamic information is required. For 73 binary systems with an overall average absolute deviation of 5.2%, it has been shown that the developed method is better than two commonly available reference methods for the prediction of liquid diffusion coefficients.  相似文献   
3.
Using the Picker flow microcalorimeter, excess heat capacities have been obtained at 25°C throughout the concentration range for 2,2-dimethylbutane,n-hexane, and cyclohexane each mixed with a series of hexadecane isomers of increasing degrees of orientational order, as determined by depolarized Rayleigh scattering. The isomers are 2,2,4,4,6,8,8-heptamethylnonane, 6-, 4-, and 2-methylpentadecane, andn-hexadecane. Thec p E values are negative, increasing rapidly in magnitude with increase of orientational order, and are not predicted by the Prigogine—Flory theory which neglects order. Values ofc p E are obtained at 10, 25, and 55°C for cyclohexane +6-, 4-, and 2-methylpentadecane which with other literature data lead to the temperature dependence of the thermodynamic excess functions for cyclohexane solutions of the five C16 isomers. The excess enthalpy and entropy vary with the C16 isomer and with temperature, but the corresponding variation of the excess free energy is small, indicating a high degree of enthalpy-entropy compensation. This is consistent with a rapid decrease with temperature of orientational order in the C16 isomers.  相似文献   
4.
Densities have been measured as a function of composition for ternary-pseudobinary mixtures of [(benzene + toluene or methylcyclohexane) + (cyclohexane + toluene or methylcyclohexane)] by means of a vibrating-tube densimeter at atmospheric pressure and the temperature 298.15 K. The excess molar volumes, VmE, were calculated from the densities and correlated using the Redlich–Kister equation to estimate the coefficients and standard errors. The experimental and calculated quantities are used to discuss the mixing behavior of the components. The results show the third component, toluene and methylcyclohexane, influences the interaction between benzene and cyclohexane.  相似文献   
5.
The 2 % Re/sibunite catalyst is more active than 2 % Re/-Al2O3 and 2 % Re/-Al2O3 catalysts in the dehydrogenation of cyclohexane into benzene (T = 350 °C,w = 0.5 h–1). The substitution of NH4ReO4 by HReO4 in the preparation of the catalyst enhances its activity by a factor of 1.3. Treatment with HNO3 or oxalic acid increases the selectivity by a factor of 1.2 and 1.35, respectively, the overall conversion of cyclohexane being 32–40 %.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 2119–2121, August, 1996.  相似文献   
6.
Novel [CrIII(amp)(bipy)(Cl)] (1) (H2amp = N-(hydroxyphenyl)salicyldimine; bipy = 2,2-bipyridyl) and [CrIII(app)(bipy)(Cl)]+ (2) (H2app = N-(hydroxyphenyl)pyridine-2-carboxaldimine; bipy = 2,2-bipyridyl) complexes have been synthesized and characterized by physico-chemical methods. Complexes 1 and 2 have been employed as catalysts in the oxidation of both saturated and unsaturated hydrocarbons using tert-butylhydroperoxide (t-BuOOH). The significance of the results with respect to oxo-functionalization of C-H bonds both in unsaturated and saturated hydrocarbons is noted.  相似文献   
7.
Molar excess volumes V E at 25°C have been determined by vibrating-tube densimetry, as a function of mole fraction x for different series of an alkanoate (H 2m+1 C m COOC n H 2n+1 )+cyclohexane. Three types of alkanoates were investigated, i.e., methanoates (m=0, with n=3 and 4), ethanoates (m=1, with n=2, 3, and 4) and propanoates (m=2, with n=1, 2, and 3). In addition, a Picker flow calorimeter was used to obtain molar excess heat capacities C p E at constant pressure at the same temperature. V E is positive for all systems and rather symmetric, with V E (x=0.5) amounting to almost identical values in a series of mixtures containing an alkanoate isomer of same formula (say C4H8O2, C5H10O2, or C6H12O2). The composition dependence of C p E is rather unusual in that two more or less marked minima are observed for most of the mixtures, especially when the alkanoate is a methanoate or an ethanoate. These results are discussed in terms of possible changes in conformation of both the ester and cyclohexane.  相似文献   
8.
金亚明  孟中岳 《催化学报》1993,14(3):213-218
用晶内形成法制备了Ni_xB/沸石催化剂,用饱和氢化学吸附法结合TEM方法考察了负载金属的分散性,并研究了其己环烷脱氢反应性。结果表明,Ni_xB/沸石样品上负载金属的分散性高,金属粒径分布也相对集中;金属负载量、载体结构和性质以及Ni_xB的制备条件对负载金属的分散性有明显影响。Ni_xB/沸石样品呈现较好的环己烷脱氢反应性。  相似文献   
9.
Enthalpies of solution and of transfer of amides for the solvents chloroform (CHCl3), methylenechloride (CH2Cl2), carbontetrachloride (CCl4), cyclohexane (C6H12), N,N-dimethylformamide (DMF), N,N-dimethylacetamide (DMA), and ethylacetate (EtOAc) have been used to isolate and quantify the solvation interactions of amides in chlorinated solvents. Specific interactions at the aminde carbonyl and N–H groups have been identified. An analysis of the transfer enthalpies of pyrrole and methylpyrrole from cyclohexane to the chlorinated solvents shows that specific interactions between the pyrroles and these solvents are similar in nature. A means of calculating differences in the transfers of different solutes between the same solvent pair is given.Work done at Lebanon Valley College.  相似文献   
10.
The Prigogine-Flory-Patterson theory of liquid mixtures has been qpplied to the H m E and V m E for binary mixtures of a bicyclic compound, benzene, cyclohexane and n-hexane with a cycloalkane, cyclohexene, a cycloalkadiene and benzene. Furthermore the Prigogine-Flory theory has been used to predict activity coefficients at infinite dilution from the experimentally determined H m E at 25°C for the mixtures cyclohexane, cyclohexene, 1,3-cyclohexadiene, 1,4-cyclohexadiene and benzene with a bicyclic compound. The predictions are compared to experimental results.  相似文献   
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