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The boxes contained kiwifruits were irradiated with cobalt-60 γ-rays at different dosages (0.6 , 1.8 and 3.6 KGy) and stored in a room ventilated at night, the natural ambient air being used as cool source.The results showed that the treatment which fruits irradiated with 0.6 KGy was the best after 85 days. It gave the normal-fruit rate of 95.10%, fruit flesh hardness of 4.10 Kg · cm-2, fresh and plump fruits, good quality and less Vc loss. 相似文献
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Guenter Paczko Norbert Peters Forman Arthur Williams 《Combustion Theory and Modelling》2013,17(4-5):515-531
Experiments on the combustion of large n-heptane droplets, performed by the National Aeronautics and Space Administration in the International Space Station, revealed a second stage of continued quasi-steady burning, supported by low-temperature chemistry, that follows radiative extinction of the first stage of burning, which is supported by normal hot-flame chemistry. The second stage of combustion experienced diffusive extinction, after which a large vapour cloud was observed to form around the droplet. In the present work, a 770-step reduced chemical-kinetic mechanism and a new 62-step skeletal chemical-kinetic mechanism, developed as an extension of an earlier 56-step mechanism, are employed to calculate the droplet burning rates, flame structures, and extinction diameters for this cool-flame regime. The calculations are performed for quasi-steady burning with the mixture fraction as the independent variable, which is then related to the physical variables of droplet combustion. The predictions with the new mechanism, which agree well with measured autoignition times, reveal that, in decreasing order of abundance, H2O, CO, H2O2, CH2O, and C2H4 are the principal reaction products during the low-temperature stage and that, during this stage, there is substantial leakage of n-heptane and O2 through the flame, and very little production of CO2 with no soot in the mechanism. The fuel leakage has been suggested to be the source of the observed vapour cloud that forms after flame extinction. While the new skeletal chemical-kinetic mechanism facilitates understanding of the chemical kinetics and predicts ignition times well, its predicted droplet diameters at extinction are appreciably larger than observed experimentally, but predictions with the 770-step reduced chemical-kinetic mechanism are in reasonably good agreement with experiment. The computations show how the key ketohydroperoxide compounds control the diffusion-flame structure and its extinction. 相似文献
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低温纳米复合相变蓄冷材料热物性研究 总被引:4,自引:0,他引:4
低温相变蓄冷的关键是蓄冷材料的开发.本文针对啤酒工艺对冷源温度的要求,选择BaCl2共晶盐水溶液为相变蓄冷材料基液,在基液中添加粒径为20nm的TiO2纳米粒子,形成具有蓄冷功能的纳米复合材料.对其热物性如导热系数、相变潜热、相变温度、过冷度及粘度进行了实验测量和分析.结果表明,在TiO2纳米粒子的质量分数为1%的情况下,纳米复合蓄冷材料的导热系数比基液提高了11.28%,过冷度从3.97℃降为1.21℃,同时粘度增加了21.7%,相变潜热略有降低. 相似文献
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Nonlinear autonomous dynamical systems with ahomoclinic tangency to a periodic orbit are investigated. We study the bifurcation sequences of the mixed-mode oscillations generated by the homoclinicity, which are shown to belong to two different types, depending on the nature of the Liapunov numbers of the basic periodic orbit. A detailed numerical analysis is carried out to show how the existence of a tangent homoclinic orbit allows us to understand in a quantitative way a particular and regular sequence of cool flame-ignition oscillations observed in a thermokinetic model of hydrocarbon oxidation. Chaotic cool flame oscillations are also observed in the same model. When the control parameter crosses a critical value, this chaotic set of trajectories becomes globally unstable and forms a Cantor-like hyperbolic repellor, and the ignition mechanism generates ahomoclinic tangency to the Cantor set of trajectories. The complex bifurcation diagram may be globally reconstructed from a one-dimensional dynamical system, thanks to the strong contractivity of thermokinetics. It is found that a symbolic dynamics with three symbols is necessary to classify the periodic windows of the complex bifurcation sequence observed numerically in this system. 相似文献
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V. I. Vedeneev L. B. Romanovich V. Ya. Basevich V. S. Arutyunov O. V. Sokolov Yu. V. Parfenov 《Russian Chemical Bulletin》1997,46(12):2006-2010
The phenomenon of the negative temperature coefficient (NTC) of the reaction rate of the oxidation of rich propane—oxygen
mixtures was experimentally studied. The NTC phenomenon is qualitatively described by a simple kinetic model containing a
minimum set of reactions related to the oxidation of the starting hydrocarbon, propane, and the propyl C3H7
. radical formed.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2120–2124, December, 1997. 相似文献