迈克耳逊干涉仪的彩色光环的调节与拍摄

本文介绍了迈克耳逊干涉仪的彩色光环的产生机理、快速调节与拍摄方法。     

非标准色传感器引起的颜色误差分析

本文推导了两种非标准色传感器在测色时引入的误差公式,并对其进行分析。最后通过计算8个样品的颜色对分析结果给于验证。     

The effect of (natural) polyols on the initial colour of heavy metal- and zinc-free poly(vinyl chloride)

The propensity of (natural) polyols dispersed in heavy metal- and zinc-free PVC sheets to improve the initial colour, e.g. the colour during the first minutes of exposure to high processing temperatures (short-term stability), has been investigated. It is shown using W(Lab) values that the initial colour improves upon addition of polyols containing primary hydroxyl groups. The polyols act as HCl scavengers, presumably via an acid-catalysed S_N2 substitution of the primary hydroxyl groups by chloride ions. In contrast, polyols with only secondary or tertiary hydroxyl groups accelerate the thermal degradation of PVC. Notwithstanding, the efficacy of the (natural) polyols containing primary hydroxyl groups will be reduced if the polyol is susceptible to competitive acid-catalysed intramolecular cyclodehydration reactions under the processing conditions. This is substantiated by a comparison of the behaviour of mannitol and 3,4-di-O-methyl-d-mannitol. The methylated derivative, which is less prone to undergo intramolecular cyclodehydration, improves the initial colour of heavy metal- and zinc-free PVC sheets more significantly than mannitol itself.     

双显色剂高灵敏协同显色反应的研究——钴(Ⅲ)-亚硝基R盐-结晶紫体系

在水溶液中钴(Ⅱ)与亚硝基R盐所形成的配合阴离子可以与有机碱阳离子(结晶紫)缔合形成中性缔合分子。在聚乙烯醇存在下,配合物可稳定存在于水溶液中。钴(Ⅲ)-亚硝基R盐-结晶紫配合物在510nm处有一最大吸收,摩尔吸光系数ε_(510)=1.47×l0~5L·mol~(-1)·cm(-1)。配合物中各组分的摩尔比为:Co:R:CV=1:3:6。反应具有较高的选择性,采用双峰双波长法测定钴可使灵敏度得到进一步提高,相应的摩尔吸光系数ε_(510-640)=4.09×10~5L·mol~(-1)·cm~(-1)。方法用于合成试样中钴的测定,结果满意。     

氮杂冠醚研究：Ⅸ.双偶氮基开链冠醚的合成及紫外可见光谱研究

用邻硝基苯酚经过先桥接，还原，然后使生成的重氮盐分别与苯酚，取代苯酚和取代苯胺偶联的方法，合成了两类新型的双偶氮基于链有色冠醚，方法简便，产率高，在一定的酸性介质中，这类冠醚存在着铵醌互交异构。测定了它们在不同介质中的紫外可见光谱，并对最大吸收峰进行归属。     

微量元素对宝玉石物理性质的影响

微量元素的介入对宝石的形成是极其重要的。它们在宝石内部或发生类质同象替代，改变了宝石的一些物理性质，如宝石的颜色、荧光、折射率、密度，也会增加宝石一些特殊的光学效应，如变色效应，使宝石的外观变得更加绚丽多彩。     

The Influence of Polyols on the Process Kinetics and Bioactive Substance Content in Osmotic Dehydrated Organic Strawberries

In recent years, an increasing interest in reducing sugar consumption has been observed and many studies are conducted on the use of polyols in the osmotic dehydration process to obtain candied or dried fruits. The studies in the literature have focused on the kinetics of the process as well as the basic physical properties. In the scientific literature, there is a lack of investigation of the influence of such polyol solutions such as sorbitol and mannitol used as osmotic substances during the osmotic dehydration process on the contents of bioactive components, including natural colourants. Thus, the aim of the study was to evaluate the impact of polyols (mannitol and sorbitol) in different concentrations on the process kinetics and on chosen physical (colour and structural changes) as well as chemical (sugars and polyol content, total anthocyanin content, total polyphenol content, vitamin C, antioxidant activity) properties of osmotic-dehydrated organic strawberries. Generally, the results showed that the best solution for osmotic dehydration is 30% or 40% sorbitol solutions, while mannitol solution is not recommended due to difficulties with preparing a high-concentration solution and its crystallization in the tissue. In the case of sorbitol, the changes of bioactive compounds, as well as colour change, were similar to the sucrose solution. However, the profile of the sugar changed significantly, in which sucrose, glucose, and fructose were reduced in organic strawberries and were partially replaced by polyols.     

UV light impact on ellagitannins and wood surface colour of European oak (Quercus petraea and Quercus robur)

Two European oak species (Q. petraea and Q. robur) have a high content of phenols which may participate in the alteration of colour upon UV irradiation. To study the photodegradation process of oak surfaces, the two oak species extractives, vescalagin, castalagin, ellagic acid and gallic acid were analysed quantitatively by HPLC before and after UV irradiation. Irradiation time was altered between 3, 24, 72, 96, 120, 144, 192 and 216 h. In parallel, any colour changes of Oak wood surface was followed after 120 h of UV-irradiation by measuring CIELAB parameters (DL*, Da*, Db* and DE*). We observed that 60% of total phenol content of extractives decreased after the maximal exposure time. Our findings also showed that castalagin and gallic acid were destroyed after 216 h and vescalagin and ellagic acid after 72 h. This study proves the photosenibility of oakwood extractives which, supplementary to lignin degradation, would strongly result in the discolouration of oak heartwood.     

Colour symmetry double point groups

Thirty four distinct composition series arising out of the 32 crystallographic double point groups are employed to re-derive in a simple and elegant fashion all the 169 distinct colour symmetry groups generated by the 32 double point groups, exploiting the idea of colour generators. The advantage of the method employed and some possible applications of these colour groups are discussed. The resulting colour groups are tabulated.     

A ‘tree’ for generation and identification of the colour symmetry point groups

A flow chart (inverted ‘tree’) for generating and identifying the 58 magnetic and 18 polychromatic point groups using a classification for the 32 generating crystallographic point groups is suggested. The idea of colour generator is explored for generating the colour symmetry point groups. The advantages in presenting the identification of colour groups through a tree are discussed.