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1.
An HPLC post column chemical derivatization procedure based on the interaction between an acridinium triflate and amines to form highly colored derivatives on-line is described for the determination of aromatic amines. Benzocaine and butesin, local anesthetic agents that contain the aromatic amine group, were used as model compounds. Reversed-phase HPLC conditions were developed for both the separation of analytes and the reaction between analytes and the acridinium triflate in the system. Three-dimensional knitted teflon shape coils and the internal diameter and length of the coils were important parameters in reducing band broadening and background noise.N-Methyl-9-chloroacridinium triflate was shown to be applicable to the determination of primary aromatic amines, selected secondary aromatic amines, hydrazides, and hydrazines. Application of the on-line chemical derivatization procedure to the analysis of pharmaceutical dosage forms containing procainamide (primary aromatic amine), isoniazid (hydrazide), and hydralazine (hydrazine) is also described. 相似文献
2.
YBCO线圈的交流损耗直接关系到YBCO设备的运行成本及稳定性。实现对YBCO线圈交流损耗的快速、准确测量,对于开展YBCO涂层导体的应用研究具有重要的意义。文中采用电测量法,在77K、零场和不同频率条件下,对YBCO线圈通以不同运行电流时产生的交流传输损耗进行测量。构建了YBCO线圈交流损耗的数值计算模型,对YBCO线圈交流损耗进行理论研究,最后将实验数据与理论计算结果进行比较,两者结果基本一致。可以发现,YBCO线圈在频率低于75Hz时,交流传输损耗随频率的增大而减小,当频率从75Hz增加到195Hz时,交流传输损耗随频率的增大而增加。 相似文献
3.
亥姆霍兹线圈磁场的均匀性分析 总被引:20,自引:8,他引:20
引入磁场均匀度的概念,对亥姆霍兹线圈磁场的均匀性进行了定量分析,并通过计算机模拟,得出了同一精度下,形成亥姆霍兹线圈均匀磁场的最佳条件. 相似文献
4.
5.
Hana Robson Marsden Alexander Kros Dr. 《Angewandte Chemie (International ed. in English)》2010,49(17):2988-3005
Biological self‐assembly is very complex and results in highly functional materials. In effect, it takes a bottom‐up approach using biomolecular building blocks of precisely defined shape, size, hydrophobicity, and spatial distribution of functionality. Inspired by, and drawing lessons from self‐assembly processes in nature, scientists are learning how to control the balance of many small forces to increase the complexity and functionality of self‐assembled nanomaterials. The coiled‐coil motif, a multipurpose building block commonly found in nature, has great potential in synthetic biology. In this review we examine the roles that the coiled‐coil peptide motif plays in self‐assembly in nature, and then summarize the advances that this has inspired in the creation of functional units, assemblies, and systems. 相似文献
6.
Vossen M Teeuwisse W Reijnierse M Collins CM Smith NB Webb AG 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2011,208(2):291-297
We describe the design and testing of a quadrature transmit, eight-channel receive array RF coil configuration for the acquisition of images of the entire human spinal column at 7 T. Imaging parameters were selected to enable data acquisition in a clinically relevant scan time. Large field-of-view (FOV) scanning enabled sagittal imaging of the spine in two or three-stations, depending upon the height of the volunteer, with a total scan time of between 10 and 15 min. A total of 10 volunteers have been scanned, with results presented for the three subjects spanning the range of heights and weights, namely one female (1.6 m, 50 kg), one average male (1.8 m, 70 kg), and one large male (1.9 m, 100 kg). 相似文献
7.
螺旋管内高压汽水两相流动沸腾干涸点的研究 总被引:1,自引:0,他引:1
在较宽的实验参数范围内(系统压力P=8~15 MPa,质量流速G=800~1800 kg·m~(-2)·s~(-1),壁面热流密度q_w=200~950 kW·m~(-2))对一立式螺旋管内(管内径为10 mm,螺旋直径为300 mm,节距为50 mm)汽水两相流动沸腾干涸特性进行了实验研究。通过研究,获得了干涸发生时螺旋管圈壁温的分布特征以及压力、质量流速和壁面热流密度这三个参数对临界干度的影响规律。同时在实验数据的基础上,提出了一个适用于计算螺旋管内高压高含汽率工况下汽水两相流临界干度的经验关系式。 相似文献
8.
Shahriar KhushrushahiMarkus Zahn 《Journal of magnetism and magnetic materials》2011,323(10):1302-1308
Ferrofluid spin-up flow is studied within a sphere subjected to a uniform rotating magnetic field from two surrounding spherical coils carrying sinusoidally varying currents at right angles and 90° phase difference. Ultrasound velocimetry measurements in a full sphere of ferrofluid shows no measureable flow. There is significant bulk flow in a partially filled sphere (1-14 mm/s) of ferrofluid or a finite height cylinder of ferrofluid with no cover (1-4 mm/s) placed in the spherical coil apparatus. The flow is due to free surface effects and the non-uniform magnetic field associated with the shape demagnetizing effects. Flow is also observed in the fully filled ferrofluid sphere (1-20 mm/s) when the field is made non-uniform by adding a permanent magnet or a DC or AC excited small solenoidal coil. This confirms that a non-uniform magnetic field or a non-uniform distribution of magnetization due to a non-uniform magnetic field are causes of spin-up flow in ferrofluids with no free surface, while tangential magnetic surface stress contributes to flow in the presence of a free surface.Recent work has fitted velocity flow measurements of ferrofluid filled finite height cylinders with no free surface, subjected to uniform rotating magnetic fields, neglecting the container shape effects which cause non-uniform demagnetizing fields, and resulting in much larger non-physical effective values of spin viscosity η′∼10−8−10−12 N s than those obtained from theoretical spin diffusion analysis where η′≤10−18 N s. COMSOL Multiphysics finite element computer simulations of spherical geometry in a uniform rotating magnetic field using non-physically large experimental fit values of spin viscosity η′∼10−8−10−12 N s with a zero spin-velocity boundary condition at the outer wall predicts measureable flow, while simulations setting spin viscosity to zero (η′=0) results in negligible flow, in agreement with the ultrasound velocimetry measurements. COMSOL simulations also confirm that a non-uniform rotating magnetic field or a uniform rotating magnetic field with a non-uniform distribution of magnetization due to an external magnet or a current carrying coil can drive a measureable flow in an infinitely long ferrofluid cylinder with zero spin viscosity (η′=0). 相似文献
9.
我们使用分析程序SAITOKSCPF研究了KSTAR PF 超导线圈的运行特性.为了控制KSTAR超导托卡马克的运行等离子的外形以便实现受控热核聚变反应,在超导PF线圈内通过高变化率的运行电流.由于电磁感应,在超导线圈、支持结构和低温容器内产生感应电流和损耗.超临界氦流过CICC导体内部保持超导体运行在4.2K的温度.分析表明最大的温度在PF1线圈内部.在这篇论文中,我们对于单一和连续条件下等离子体放电对超导体运行的影响进行了研究. 相似文献
10.
Martin L. Banson Gary P. Cofer Laurence W. Hedlund G. Allan Johnson 《Magnetic resonance imaging》1992,10(6):929-934
An inductively coupled surface coil for imaging the rat spine at 7 T is described. This planar circular probe was made from microwave substrate to limit the size of the coil and to minimize the magnetic susceptibility. The surface coil was used as a single transmit/receive coil and as a receive-only coil with a birdcage body coil for excitation. The signal-to-noise ratio (SNR) of the probe was compared to a 5-cm birdcage coil and exceeded the birdcage coil's SNR by three to six times at superficial structures. The main advantages of the probe are an improved SNR for superficial structures and a simple design and use. Images with 50 × 50 × 500 μm voxels were obtained of the rat spine with excellent anatomical detail. 相似文献