全文获取类型
收费全文 | 5652篇 |
免费 | 536篇 |
国内免费 | 638篇 |
专业分类
化学 | 4143篇 |
晶体学 | 19篇 |
力学 | 115篇 |
综合类 | 119篇 |
数学 | 1060篇 |
物理学 | 1370篇 |
出版年
2024年 | 14篇 |
2023年 | 41篇 |
2022年 | 165篇 |
2021年 | 253篇 |
2020年 | 211篇 |
2019年 | 154篇 |
2018年 | 149篇 |
2017年 | 161篇 |
2016年 | 255篇 |
2015年 | 220篇 |
2014年 | 329篇 |
2013年 | 415篇 |
2012年 | 285篇 |
2011年 | 353篇 |
2010年 | 277篇 |
2009年 | 362篇 |
2008年 | 345篇 |
2007年 | 344篇 |
2006年 | 340篇 |
2005年 | 328篇 |
2004年 | 284篇 |
2003年 | 234篇 |
2002年 | 164篇 |
2001年 | 145篇 |
2000年 | 123篇 |
1999年 | 130篇 |
1998年 | 111篇 |
1997年 | 104篇 |
1996年 | 81篇 |
1995年 | 85篇 |
1994年 | 72篇 |
1993年 | 39篇 |
1992年 | 39篇 |
1991年 | 60篇 |
1990年 | 29篇 |
1989年 | 40篇 |
1988年 | 30篇 |
1987年 | 9篇 |
1986年 | 9篇 |
1985年 | 7篇 |
1984年 | 7篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1979年 | 4篇 |
1978年 | 5篇 |
1977年 | 1篇 |
1975年 | 2篇 |
1974年 | 1篇 |
1973年 | 4篇 |
1969年 | 1篇 |
排序方式: 共有6826条查询结果,搜索用时 31 毫秒
1.
Edward G. Sheetz Zhao Zhang Alyssa Marogil Minwei Che Dr. Maren Pink Dr. Veronica Carta Prof. Dr. Krishnan Raghavachari Prof. Dr. Amar H. Flood 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(60):e202201584
The recognition of boron compounds is well developed as boronic acids but untapped as organotrifluoroborate anions (R−BF3−). We are exploring the development of these and other designer anions as anion-recognition motifs by considering them as substituted versions of the parent inorganic ion. To this end, we demonstrate strong and reliable binding of organic trifluoroborates, R−BF3−, by cyanostar macrocycles that are size-complementary to the inorganic BF4− progenitors. We find that recognition is modulated by the substituent's sterics and that the affinities are retained using the common K+ salts of R−BF3− anions. 相似文献
2.
João Marcos G. Barbosa Milenna K. Fernandes Rodrigues Lurian C. David Taynara C. e Silva Danielly A. Fortuna Lima Naiara Z. Pereira Emmanuel B. D'Alessandro Anselmo E. de Oliveira Paulo H. Jorge da Cunha Maria Clorinda S. Fioravanti Nelson R. Antoniosi Filho 《Biomedical chromatography : BMC》2020,34(11):e4935
An innovative volatolomic approach employs the detection of biomarkers present in cerumen (earwax) to identify cattle intoxication by Stryphnodendron rotundifolium Mart., Fabaceae (popularly known as barbatimão). S. rotundifolium is a poisonous plant with the toxic compound undefined and widely distributed throughout the Brazilian territory. Cerumen samples from cattle of two local Brazilian breeds (‘Curraleiro Pé-Duro’ and ‘Pantaneiro’) were collected during an experimental intoxication protocol and analyzed using headspace (HS)/GC–MS followed by multivariate analysis (genetic algorithm for a partial least squares, cluster analysis, and classification and regression trees). A total of 106 volatile organic metabolites were identified in the cerumen samples of bovines. The intoxication by S. rotundifolium influenced the cerumen volatolomic profile of the bovines throughout the intoxication protocol. In this way, it was possible to detect biomarkers for cattle intoxication. Among the biomarkers, 2-octyldecanol and 9-tetradecen-1-ol were able to discriminate all samples between intoxicated and nonintoxicated bovines. The cattle intoxication diagnosis by S. rotundifolium was accomplished by applying the cerumen analysis using HS/GC–MS, in an easy, accurate, and noninvasive way. Thus, the proposed bioanalytical chromatography protocol is a useful tool in veterinary applications to determine this kind of intoxication. 相似文献
3.
Wenqing Zhang Dr. Jiuxing Li Prof. Dr. Bruno Salena Prof. Dr. Yingfu Li 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(3):592-596
DNA detection is usually conducted under nondenaturing conditions to favor the formation of Watson–Crick base-paring interactions. However, although such a setting is excellent for distinguishing a single-nucleotide polymorphism (SNP) within short DNA sequences (15–25 nucleotides), it does not offer a good solution to SNP detection within much longer sequences. Here we report on a new detection method capable of detecting SNP in a DNA sequence containing 35–90 nucleotides. This is achieved through incorporating into the recognition DNA sequence a previously discovered DNA molecule that forms a stable G-quadruplex in the presence of 7 molar urea, a known condition for denaturing DNA structures. The systems are configured to produce both colorimetric and fluorescent signals upon target binding. 相似文献
4.
Peter Imkeller 《Probability Theory and Related Fields》1996,106(1):105-135
Summary. The analytic treatment of problems related to the asymptotic behaviour of random dynamical systems generated by stochastic
differential equations suffers from the presence of non-adapted random invariant measures. Semimartingale theory becomes accessible
if the underlying Wiener filtration is enlarged by the information carried by the orthogonal projectors on the Oseledets spaces
of the (linearized) system.
We study the corresponding problem of preservation of the semimartingale property and the validity of a priori inequalities
between the norms of stochastic integrals in the enlarged filtration and norms of their quadratic variations in case the random
element F enlarging the filtration is real valued and possesses an absolutely continuous law. Applying the tools of Malliavin’s calculus,
we give smoothness conditions on F under which the semimartingale property is preserved and a priori martingale inequalities are valid.
Received: 12 April 1995 / In revised form: 7 March 1996 相似文献
5.
Laser welding is one of the most precise welding processes in joining sheet metals. In laser welding, performing real time evaluation of the welding quality is very important to enhance the efficiency of the welding process. In this study, the plasma and spatter, which are generated during laser welding, are measured using UV and IR photodiodes. The factors that influence weld quality are classified into five categories; optimal heat input, slightly low heat input, low heat input, partial joining due to gap mismatch, and nozzle deviation. The data number deviated from reference signals and their standard deviations were also considered to evaluate the qualities. A system was also formulated to perform real time evaluations of the weld quality using a fuzzy multi-feature pattern recognition with the measured signals. 相似文献
6.
7.
8.
A new family of proximity graphs: Class cover catch digraphs 总被引:1,自引:0,他引:1
Jason DeVinney 《Discrete Applied Mathematics》2006,154(14):1975-1982
Motivated by issues in machine learning and statistical pattern classification, we investigate a class cover problem (CCP) with an associated family of directed graphs—class cover catch digraphs (CCCDs). CCCDs are a special case of catch digraphs. Solving the underlying CCP is equivalent to finding a smallest cardinality dominating set for the associated CCCD, which in turn provides regularization for statistical pattern classification. Some relevant properties of CCCDs are studied and a characterization of a family of CCCDs is given. 相似文献
9.
10.
Micha? Chmielewski 《Tetrahedron letters》2004,45(31):6007-6010
Comparison of the anion binding properties of a series of uncharged macrocyclic tetraamides reveal significant effects of the receptor's size on the strength of its anion complexes. This study allowed for estimation of the optimal size of a macroring for complexation of common anions. 相似文献