对半导体pn结接触电势的一个讨论

讨论了半导体pn结内建电场和接触电势的形成与可测性，回答了在半导体物理学pn结内容教学中学生经常会提出的一个似是而非的问题．从热力学第一定律、金属-半导体接触等不同角度详细解释了热平衡(零偏下)时pn结不可能对外输出电压和电流的原因．     

High Power THz Undulator Radiation from Linear Accelerator

A 30-MeV femto-second electron linac is built at the Shanghai Institute of Applied Physics, which can produce high power, coherent THz undulator radiation. We report the experimental facility and measurement of the power, frequency spectrum. First experiments show the averaged power at THz to be about 20mW.     

Synthesis and structure of built-up organic macromolecules containing helicene

Built-up macromolecules are acyclic molecules with molecular weights of several thousand daltons, which are synthesized by connecting small molecular units using stepwise methods. The chemical study of built-up macromolecules reveals some noteworthy properties that are different from those of conventional biological and synthetic macromolecules. A characteristic feature of built-up organic macromolecules is that their structures and properties are discontinuous at a certain molecular weight. For such macromolecules, variation in the small molecular units and the formation of cyclic structures substantially affect the structure and properties. The built-up organic macromolecules obtained by connecting helicenes with amide, acetylene, and amine groups are discussed in this paper. Some chiral built-up macromolecules are linked by covalent bonds, and the effects of linking on the structure are compared.     

Tuning of the open‐circuit voltage by wide band‐gap absorber and doped layers in thin film silicon solar cells

We present an experimental study combined with computer simulations on the effects of wide band‐gap absorber and window layers on the open‐circuit voltage (V_oc) in single junction thin film silicon solar cells. The quantity ΔE_p, taking as the difference between the band gap and the activation energy in ?p? layer, is treated as a measure of the p‐layer properties and shows a linear relation with V_oc over a range of 100 mV with a positive slope of around 430 mV/eV. Two limiting mechanisms of V_oc are identified: the built‐in potential at lower ΔE_p and the band gap of the absorber layer at higher ΔE_p. The results of the experimental findings are confirmed by computer simulations. (© 2015 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim)     

基于自主研发的500 MHz NMR谱仪的紫杉醇结构解析

中国科学院武汉物理与数学研究所（WIPM）于2010年成功研制了500 MHz（WIPM-I 500）高分辨超导核磁共振（NMR）谱仪,并将其投入实际应用中.然而,关于其二维核磁共振（2D NMR）谱图的准确性及在此基础上对复杂物质的结构解析尚无系统完整的数据报道.该文利用WIPM-I 500型NMR谱仪,对紫杉醇样品进行了1D NMR及2D NMR（包括¹H-¹H COSY、¹H-¹H TOCSY、J-Res、¹H-¹³C HMQC和¹H-¹³C HMBC）实验,将谱图分析结果与进口仪器进行了对比.结果表明：利用WIPM-I 500型NMR谱仪能够采集准确的2D NMR谱图,为紫杉醇的正确归属提供了实验基础;而且该文也纠正了文献中对紫杉醇的错误归属.     

Mass spectrometric characterization of the zein protein composition in maize flour extracts upon protein separation by SDS‐PAGE and 2D gel electrophoresis

Highly homogenous α zein protein was isolated from maize kernels in an environment‐friendly process using 95% ethanol as solvent. Due to the polyploidy and genetic polymorphism of the plant source, the application of high resolution separation methods in conjunction with precise analytical methods, such as MALDI‐TOF‐MS, is required to accurately estimate homogeneity of products that contain natural zein protein. The α zein protein product revealed two main bands in SDS‐PAGE analysis, one at 25 kDa and other at 20 kDa apparent molecular mass. Yet, high resolution 2DE revealed approximately five protein spot groups in each row, the first at ca. 25 kDa and the second at ca. 20 kDa. Peptide mass fingerprinting data of the proteins in the two dominant SDS‐PAGE bands matched to 30 amino acid sequence entries out of 102 non‐redundant data base entries. MALDI‐TOF‐MS peptide mapping of the proteins from all spots indicated the presence of only α zein proteins. The most prominent ion signals in the MALDI mass spectra of the protein mixture of the 25 kDa SDS gel band after in‐gel digestion were found at m/z 1272.6 and m/z 2009.1, and the most prominent ion signals of the protein mixture of the 20 kDa band after in‐gel digestion were recorded at m/z 1083.5 and m/z 1691.8. These ion signals have been found typical for α zein proteins and may serve as marker ion signals which upon chymotryptic digestion reliably indicate the presence of α zein protein in two hybrid corn products.