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Similar to classical asphericity shifts, aspherical deformations of the electron density in the atomic core region can result in core asphericity shifts in refinements using a Hansen-Coppens multipolar model (HCM), especially when highly precise experimental datasets with resolutions far beyond sin(θ)/λ ≤ 1.0 Å−1 are employed. These shifts are about two orders of magnitude smaller than their counterparts caused by valence shell deformations, and their underlying deformations are mainly of dipolar character for 1st row atoms. Here, we analyze the resolution dependence of core asphericity shifts in α-boron. Based on theoretical structure factors, an appropriate Extended HCM (EHCM) is developed, which is tested against experimental high-resolution (sin(θ)/λ ≤ 1.6 Å−1) single-crystal diffraction data. Bond length deviations due to core asphericity shifts of α-boron in the order of 4–6·10−4 Å are small but significant at this resolution and can be effectively compensated by an EHCM, although the correlation of the additional model parameters with positional parameters prevented a free refinement of all core model parameters. For high quality, high resolution data, a proper treatment with an EHCM or other equivalent methods is therefore highly recommended. 相似文献
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Detailed theoretical investigations into asphericity in the Fermi surface (FS) and Fermi energy (FE) ofNa1_xKx, Na1_xRbx, and Na1_xCsx binary solid solutions are carried out for the first time. The alloying behavior ofthe K, Rb, and Cs with the Na generates the Fermi surface distortion (FSD) of bce simple metals. The FS of Na-K,Na-Rb, and Na-Cs solid solution is a distorted sphere with the largest deviation along [110]. We have found that theimpact of local-field correction function on FSD is maximun at [100] point and minimum at [111] point. The exchangeand correlation effect is found to suppress the value of FE. 相似文献
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计算机控制光学表面成形法初值的确定 总被引:1,自引:0,他引:1
介绍了计算机控制光学表面成形法的原理,分析了几种非球面度的测量方法,研究了非球面度的不同计算方法对采用计算机控制光学表面成形法加工非球面的影响。从光学零件加工的角度对计算机控制光学表面成形法初值的确定进行了探讨。 相似文献
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Stephen J. Pride 《Proceedings of the American Mathematical Society》2008,136(2):377-386
A relative one-relator presentation has the form where is a set, is a group, and is a word on . We show that if the word on obtained from by deleting all the terms from has what we call the unique max-min property, then the group defined by is residually finite if and only if is residually finite (Theorem 1). We apply this to obtain new results concerning the residual finiteness of (ordinary) one-relator groups (Theorem 4). We also obtain results concerning the conjugacy problem for one-relator groups (Theorem 5), and results concerning the relative asphericity of presentations of the form (Theorem 6).
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Joanna Zubik 《Topology and its Applications》2010,157(18):2815-2818
Asymptotic hereditary asphericity (AHA) is a coarse property introduced by Januszkiewicz and ?wia?tkowski in the context of systolic complexes and groups. We show, that spaces of asymptotic dimension 1 are all AHA. 相似文献
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LetX (Δ) be the real toric variety associated to a smooth fan Δ. The main purpose of this article is: (i) to determine the fundamental
group and the universal cover ofX (Δ), (ii) to give necessary and sufficient conditions on Δ under which π1(X(Δ)) is abelian, (iii) to give necessary and sufficient conditions on Δ under whichX(Δ) is aspherical, and when Δ is complete, (iv) to give necessary and sufficient conditions forC
Δ to be aK (π, 1) space whereC
Δ is the complement of a real subspace arrangement associated to Δ. 相似文献
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采用光的干涉方法检测曲面光学表面的加工质量时,都需要事先设计好系统光路的最佳检测技术参数,并能对检测的难度进行有效的评估,从而确保检测的精度。该研究采用了一种计算干涉条纹密度的新方法,对任意光学曲面检测的难度进行评估,并用于确定球面参考光点光源的最佳位置。以非球面为例,计算了非球面的最接近球面的半径和最大非球面度以及非球面检测时球面参考光点光源的最佳位置,说明了计算干涉条纹密度方法在确定干涉检测系统光路调试最佳条件的优越性,可为各种干涉检测系统的设计以及优化调试过程提供理论依据和分析指导。 相似文献