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神经网络法计算镉(Ⅱ),羟基及碳酸根三元体系的形态分布 总被引:2,自引:0,他引:2
采用前馈线笥网络BP算法,计算了Cd62+-OH^-CO^2-3三元体系的累积稳定常数。用Hopfield反馈网络研究了体系中络合物的形态分布。溶液中溶解的CO2对lgβ1的计算结果有重要影响,对lgβ2,lgβ3,lgβ4的结果影响不大。 相似文献
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本文给出了一个激光对光学材料表面热破坏效应的简化物理模型及数值研究结果。所得到的铜反射镜热破坏阈值与激光脉宽的关系与实验和理论符合很好。提出了反射镜后表面外冷却临界厚度的概念,并得到一个关于多脉冲积累效应的幂定标关系。 相似文献
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积累检测在光电设备中的应用分析 总被引:2,自引:0,他引:2
有些光电检测设备要求高的探测概率和低的虚警概率,使用单次检测不能达到要求。若采用积累榆测法则能满足系统要求。通过对积累检测在不同类型光电设备中的应用分析,建立了不同的数学模型,推导出各模型的探测概率和虚警概率的计算公式,并给出了相应的计算结果。计算结果表明:积累检测在主动探测设备中使用不连续的“K out of N”模型,能够有效提高探测概率,降低虚警概率。但在被动探测设备中,探测概率有所卜降,虚警概率会大大降低。 相似文献
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The effect of annealing condition on the microstructure evolution, together with mechanical properties of Fe-28.5Ni steel processed by one and six cycles of accumulative roll bonding (ARB), was explored. The evolution of microstructure was studied by means of Electron Backscattered Diffraction method. The ARB-processed specimens were annealed for 30 minutes between 500°C and 600°C, and the effect of these annealing processes was elaborated. Results showed a significantly reduced martensite phase during ARB process cycles. Moreover, a refined and stabilised ultrafine structure was obtained in 6-cycle ARB-processed specimen. Results also show that by annealing the 1-cycle specimen at 550°C, no significant microstructural change and mechanical properties variation are identified. As such, no significant microstructural change and mechanical properties variation were notified for annealing of 6-cycle ARB-processed specimen at 500°C. However, annealing at 600°C in both conditions led to a complete recrystallisation of the deformed structure. Annealing at 550°C in 6-cycle ARB-processed specimen showed partial recrystallisation as well as an abnormal grain growth characteristic. The abnormal grain growth was seen by annealing of 1-cycle ARB-processed specimen at 600°C. The changing features of dislocations were discussed in these specimens in terms of changing the dynamics of low- and high-angle grain boundaries. Tensile test results also showed a significant increase in the yield/ultimate tensile strengths with the application of ARB cycles. Although ARB process led to a rapid reduction of total elongation, full restoration during high-temperature annealing returned this value back to the initial, non-deformed, condition. 相似文献
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Accumulative back extrusion (ABE) processing, as a novel severe plastic deformation (SPD) method, has been recently justified to be capable of modifying the microstructural characteristics of alloys. In line to its ongoing researches, the present work has been planned to study the evolution of γ-Mg17Al12 intermetallic phase during ABE and subsequent ageing treatment in a high Al-bearing Mg–Al–Zn alloy. The behaviour of γ intermetallic has been systematically examined as following points of view: (i) strain–temperature-dependent morphology changes, (ii) strain-induced dissolution, and (iii) re-ageing behaviour as a function of time and temperature. Aiming to analyse the morphology of eutectic γ compound with respect to the strain and temperature, 2D projections of effective diameter, shape factor and globularity have been made in strain/temperature graphs. The processing conditions (strain and temperature) corresponding to the desired and undesired morphologies are introduced and microstructurally explained through underlying plasticity mechanisms, i.e., ‘necking-thinning-particle separation’ and ‘brittle fragmentation.’ The former mechanism is suggested to be in relation with partial strain-induced dissolution of eutectic γ phase, leading to generation of a supersaturated solid solution. This has resulted to the observation of ‘off-stoichiometry’ phenomena in Mg17Al12 phase and has been justified through dislocation-assisted deformation mechanism at elevated temperature. Surprisingly, a unique re-ageing behaviour has been found for the obtained solid solutions, where a modified kinetics and morphology of γ phase precipitation were characterized. The altered precipitation behaviour is attributed to the specific defect structure achieved by SPD acting as fast diffusion channel for Al solutes. 相似文献
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经济发展系统中的积累率的辨识问题 总被引:1,自引:1,他引:0
讨论了一类非定常经济系统的积累率的辨识问题,利用Banach空间中的Banach-Saks-Mazur定理,对极小化序列中的弱收敛序列,构造强收敛极小化序列,从而得到了辨识问题解的存在唯一性. 相似文献
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Dr. Thierry Lonhienne Dr. Amanda Nouwens Prof. Craig M. Williams Prof. James A. Fraser Yu‐Ting Lee Dr. Nicholas P. West Prof. Luke W. Guddat 《Angewandte Chemie (International ed. in English)》2016,55(13):4247-4251
Acetohydroxyacid synthase (AHAS) inhibitors are highly successful commercial herbicides. New kinetic data show that the binding of these compounds leads to reversible accumulative inhibition of AHAS. Crystallographic data (to a resolution of 2.17 Å) for an AHAS–herbicide complex shows that closure of the active site occurs when the herbicidal inhibitor binds, thus preventing exchange with solvent. This feature combined with new kinetic data shows that molecular oxygen promotes an accumulative inhibition leading to the conclusion that the exceptional potency of these herbicides is augmented by subversion of an inherent oxygenase side reaction. The reactive oxygen species produced by this reaction are trapped in the active site, triggering oxidation reactions that ultimately lead to the alteration of the redox state of the cofactor flavin adenine dinucleotide (FAD), a feature that accounts for the observed reversible accumulative inhibition. 相似文献
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