复注及多孔注浆理论研究

针对柱面注浆方式，研究了有关渗透注浆的单孔复注及不同方式布孔时多孔注浆的相互影响等问题，推导出一些有价值的岩体注浆理论公式，可用于指导现场注浆工程的设计与施工．     

Identifying Linking-Pin Organizations in Inter-Organizational Networks

Within the large literature on inter-organizational networks, there has been some discussion of linking-pin organizations and the role they play in integrating these networks. Based on this verbal specification of linking-pin organizations, we construct operational criteria and empirical methods for identifying these structurally important organizations in potentially large and complex inter-organizational networks. These methods are based on ideas drawn from blockmodeling, structural holes, centrality and centralization of networks, and identifying cut-points in networks. These methods are applied to a constructed example and then to real empirical inter-organizational networks. Implications and contrasts with other methods are discussed, together with some open problems.     

Peculiar relics from Primordial Black Holes in the inflationary paradigm

Depending on various assumptions on the energy scale of inflation and assuming a primordial power spectrum of a step‐like structure, we explore new possibilities for Primordial Black Holes (PBH) and Planck relics to contribute substantially to Cold Dark Matter in the Universe. A recently proposed possibility to produce Planck relics in four‐dimensional string gravity is considered in this framework. Possible experimental detection of PBHs through gravitational waves is also explored. We stress that inflation with a low energy scale, and also possibly when Planck relics are produced, leads unavoidably to relics originating from PBHs that are not effectively classical during their formation, rendering the usual formalism inadequate for them.     

Dependence of Performance of Organic Light-emitting Devices on Sheet Resistance of Indium-tin-oxide Anodes

IntroductionIndium-tin-oxide(ITO) has been widely used asthe anode material in organic light-emitting devices(OLEDs) because of its high transmittance in the visi-ble region and low electrical resistivity. In the pastyears, many investigations focused on …     

NMR investigation on the conformational properties of N-[2-pyridyl-N-oxide]-amino derivatives

The proton NMR spectra of N-[2-pyridyl-N-oxide]-derivatives of primary and secondary ethylamines, containing a substituent R on the C atom bearing the amino function, have been completely analysed in terms of the fundamental NMR parameters. The preferred conformations of the compounds investigated were established by the indications from NOE experiments as well as: (1) the long range coupling across the five bond between the aminic hydrogen and the proton in 4-position of the pyridine-N-oxide ring (⁵J_m^H,NH ～ 0·5 c/s), (2) the value of the vicinal coupling constant in the fragment CHNH (³J_NHCH ～ 7–9 c/s), (3) the large deshielding (Δτ ～ 1–1·5 ppm) observed for the resonance position of the proton on the asymmetric C atom in secondary amine derivatives with respect to the corresponding primary ones, and (4) the diamagnetic shielding produced on protons in position 3 and 4 of the pyridine-N-oxide ring by different aromatic groups introduced in the R substituent.The NMR data confirmed the preferred rotamers previously suggested on the basis of ORD and CD measurements.     

飞秒激光高精细加工柴油机喷油嘴倒锥孔法

利用飞秒激光加工热效应小、高精细、对材料无选择性等特点,针对柴油发动机高压共轨系统中关键零件——喷油嘴偶件喷油孔的加工需求,设计了一种利用三光楔扫描的飞秒激光加工装置,并进行了喷油嘴倒锥孔加工工艺研究.采用微孔三座标测量机(测量准确度1.2μm)对倒锥孔尺寸准确度进行检测,通过喷油嘴高压液体流量试验台(测量准确度±0.1%)对批量制孔后的油嘴进行了流量测试,结果表明:所设计装置加工的油嘴性能可以满足欧V排放法规的应用要求,对提升汽车制造业水平及柴油车排放标准具有重要意义.     

作为宇宙信使的X射线

60年前,里卡多·贾科尼团队用探空火箭首次探测到了来自太阳系以外的X射线辐射,从此打开了人类探索宇宙的一个全新的窗口。与我们所熟悉的可见光天空不同,在“看不见”的X射线宇宙,明亮的发光天体涵盖了黑洞、中子星、白矮星等致密天体,星系团和星系中弥漫的大量不可见的高温气体,以及各种剧烈的灾变事件。它们代表着宇宙中最为奇特的天体和极端的物理条件,如极强引力场、极强磁场和极高温。文章重点介绍最有代表性的X射线源,包括中子星和黑洞X射线双星、超大质量黑洞和活动星系核、星系团,以及伽马暴、超新星和潮汐瓦解恒星事件等爆发天体。     

Quasi-normal modes of extremal black holes from hidden conformal symmetry

In this Letter, we construct the quasi-normal modes of three-dimensional extremal black holes in an algebraic way. We show that the infinite towers of the quasi-normal modes of scalar, vector and tensor could be constructed as the descendents of the highest weight modes. Our investigation shows that the hidden conformal symmetry suggested in Chen et al. (2010) [5] is an intrinsic property of the extremal black hole. Moreover, we notice that we need to fix the freedom in defining the local vector fields and find the right hidden conformal symmetry to obtain the physical quasi-normal modes.     

Quantum-corrected finite entropy of noncommutative acoustic black holes

In this paper we consider the generalized uncertainty principle in the tunneling formalism via Hamilton–Jacobi method to determine the quantum-corrected Hawking temperature and entropy for 2+1$2+1$-dimensional noncommutative acoustic black holes. In our results we obtain an area entropy, a correction logarithmic in leading order, a correction term in subleading order proportional to the radiation temperature associated with the noncommutative acoustic black holes and an extra term that depends on a conserved charge. Thus, as in the gravitational case, there is no need to introduce the ultraviolet cut-off and divergences are eliminated.     

Halogen Bonding: An Interim Discussion

Halogen bonding is a noncovalent interaction that is receiving rapidly increasing attention because of its significance in biological systems and its importance in the design of new materials in a variety of areas, for example, electronics, nonlinear optical activity, and pharmaceuticals. The interactions can be understood in terms of electrostatics/polarization and dispersion; they involve a region of positive electrostatic potential on a covalently bonded halogen and a negative site, such as the lone pair of a Lewis base. The positive potential, labeled a σ hole, is on the extension of the covalent bond to the halogen, which accounts for the characteristic near‐linearity of halogen bonding. In many instances, the lateral sides of the halogen have negative electrostatic potentials, allowing it to also interact favorably with positive sites. In this discussion, after looking at some of the experimental observations of halogen bonding, we address the origins of σ holes, the factors that govern the magnitudes of their electrostatic potentials, and the properties of the resulting complexes with negative sites. The relationship of halogen and hydrogen bonding is examined. We also point out that σ‐hole interactions are not limited to halogens, but can also involve covalently bonded atoms of Groups IV–VI. Examples of applications in biological/medicinal chemistry and in crystal engineering are mentioned, taking note that halogen bonding can be “tuned” to fit various requirements, that is, strength of interaction, steric factors, and so forth.