横向射流式单重态氧发生器的性能实验研究

 对氧碘化学激光器的单重态氧发生器（SOG）进行了改进，采用横向射流方式，并对该横向射流式单重态氧发生器的性能进行了检测。实验中过氧化氢碱溶液温度控制在－16℃左右,氯气流量为530mmol/s，He与氯气的流量比为3;采用PS法测量单重态氧分子的产率,吸收法测量氯气的利用率和相对水含量。得出如下结论:在不使用冷阱和分离器的情况下，最高单重态氧分子产率达到58%, 氯气利用率在80%以上,相对水含量小于等于0.5;气体达到最大流量时,发生器仍然能稳定地工作。     

Resonance method for IR sensing

A highly sensitive method for infrared radiation detection based on thermal resonance in an active bolometer is set forth. An active bolometer is a self-oscillating system consisting of an IR-sensitive cell in a feedback circuit of an adjustable proportional controller. The analysis of an active bolometer autonomous (dark) dynamics reveals that with a generalized gain factor A variation the system evolves from relaxation type towards oscillating and self-oscillating type. When A=A_c, where A_c is a critical value of the generalized gain factor A, the steady state loses stability through self-excited thermal oscillations. The resonance in a system weakly perturbed by IR radiation modulated at self-oscillation frequency q₀[1+exp(iω_ct)] is considered. It is shown that in a small precritical vicinity =(A−A_c)/A_c of the gain factor the amplitude of forced thermal oscillations is proportional to q₀/A_c. The D^* calculation reveals that the detection power of a passive (A=0) bolometer increases with feedback introduction by a factor of 1/||. The detection powers of feasible versions of an active bolometer are compared.     

To the problem of energy recuperation in gyrotrons

A relatively high level of the minimal electron energy at the gyrotron output even at very large spread in pitch factor is explained. An estimation of the recuperation efficiency, which can be obtained due to this effect, is given.     

Physics possibilities at India-based Neutrino Observatory

In this talk I review the physics possible at India-based Neutrino Observatory (INO). I discuss the improvement in the precision of currently known quantities and the possibility measuring the presently unknown quantities.     

Electron g-factor in a gated InAs-inserted-channel In0.53Ga0.47As/In0.52Al0.48As heterostructure

We report on electron g-factor in an InAs-inserted In_0.53Ga_0.47As/In_0.52Al_0.48As heterostructure. The gate voltage dependence of g-factor is obtained from the coincidence method. The obtained g-factor values are surprisingly smaller than the g-factor value of bulk InAs, and it is close to the bare g-factor value of In_0.53Ga_0.47As. The large change in g-factor is observed by applying the gate voltage. The obtained gate voltage dependence is not simply explained by the energy dependence of g-factor.     

用方差定义的激光束横向尺寸的测量

用方差定义的激光束横向尺寸,有着普适、简单和便于利用光学元件并行运算功能的特点.本文提出一种借助改变柱形容器内吸收液浓度来直接测量各种波长激光束横向尺寸的理论和方法.     

Effects of delayed linear electrical perturbation of the Belousov-Zhabotinsky reaction: a case of complex mixed mode oscillations in a batch reactor

Delayed feedbacks are quite common in many physical and biological systems and in particular many physiological systems. Delay can cause a stable system to become unstable and vice versa. One of the well-studied non-biological chemical oscillators is the Belousov-Zhabotinskii (BZ) reaction. This gives relaxation oscillations for a considerable period of time under batch conditions. This paper deals with the effect of perturbing the limit cycle oscillation of BZ reaction by employing a delayed electrical feedback to the system under batch conditions. The parameters chosen to study are external resistance and delay. For various resistances and delays the system was electrically perturbed and found to exhibit various complex mixed mode oscillations. The dynamic features are accounted for by the Oregonator model, with time delay incorporated in one of the variables. This revised version was published online in June 2006 with corrections to the Cover Date.     

Study on the dual-frequency oscillations in galactose-BZ system

Three types of dual-frequency oscillations in KBrO3-galactose-acetone-MnSO4-H2SO4 have been observed in a batch reactor depending on the initial concentration of H2SO4 or Br-. Similar phenomena were also observed when galactose was replaced by other aldosugars such as glucose, arabi-nose, lactose and maltose. However no dual-frequency oscillation has been found when ketosugar like fructose was used instead of galactose as the substrate. The roles of acidity, bromide ion and acetone in dual-frequency oscillations have been analyzed. The mechanism of dual-frequency oscillations has been discussed.     

Theory of measurement of gas-adsorption equilibria by rotational oscillations

The gas adsorbed on the inner surface of a highly porous material like activated carbon or zeolite can be measured by slow damped oscillations of a torsional pendulum. The physical principles and the theory of this method are outlined. Formulas are given relating the increase in mass due to adsorption to changes of the frequency and the logarithmic decrement of slow, damped rotational oscillations of the pendulum. Preliminary measurements of gas adsorption equilibria of nitrogen on activated carbon show that the ratio of the mass adsorbedm, to the mass of the adsorbentm ^s , can be determined by this method with mean absolute error |m/m ^s |0.04%.Dedicated to the memory of Joseph Kestin (1913–1993).     

On the Criteria of Instability for Electrochemical Systems

Both cyclic-voltammetry-based and impedance-based experimental criteria that have been developed recently for the oscillatory electrochemical systems are critically appraised with two typical categories of oscillators.Consistent conclusions can be drawn by the two criteria for the category of oscillators that involve the coupling of charge transfer mainly with surface steps(e.g.ad-and desorption)such as in the electrooxidation of C1 organic molecules.Whereas,impedance-based criterion is not applicable to the category of oscillators that involve the coupling of charge transfer mainly with mass transfer(e.g.diffusion and convection) such as in the Fe(CN)6^3- reduction accompanying periodic hydrogen evolution.The reason is that the negative impedance cannot include the feedback information of convection mass transfer induced by the hydrogen evolution.However,both positive and negative nonlinear feedbacks,i.e., the diffusion-limited depletion and convection-enhanced replenishment of the Fe(CN)6^3- surface concentration,that coexist between the bistability,i.e.,Fe(CN)6^3- reduction with and without hydrogen evolution at lower and higher potential sides respectively,are all reflected in the crossed cyclic voltammogram(CCV).It can be concluded that the voltammetry-based criterion(in time domain)is more intuitive,less time-consuming and has a wider range of applications than the impedancebased one (in frequency domain).