19F-NMR进展

19F-NMR技术由于其化学位移范围大、不易出现峰重叠及灵敏度高等优点,自上个世纪50年代出现以来,在分析光学异构体,生命科学等研究中有其特殊意义.在体内核磁共振技术中,19F-NMR与其他方法相比,在不损伤样品的条件下,就可进行实时定量监测.近30年,引人氟代指示剂进行体内19F-NMR的研究,含氟生物活性物质以及含氟材料的研究受到很大的重视,19F-NMR技术及其应用发展起来.从近10年的情况来看,含氟生物活性物质的研究以及在医药、农药和具有优异性能的含氟材料的研究应用受到很大的重视,这是近期19F-NMR研究发展的一个主要特点.     

Numerical Analysis of Thermally Coupled Flow Problems with Interfaces and Phase-change Effects

In this work a fixed mesh finite element approach is presented to solve thermally coupled flow problems including moving interfaces between immiscible fluids and phase-change effects. The weak form of the full incompressible Navier-Stokes equations is obtained using a generalized streamline operator (GSO) technique that enables the use of equal order interpolation of the primitive variables of the problem: velocity, pressure and temperature. The interfaces are defined with a mesh of marker points whose motion is obtained applying a Lagrangian scheme. Moreover, a temperature-based formulation is considered to describe the phase-change phenomena. The proposed methodology is used in the analysis of a filling of a step mould and a gravity-driven flow of an aluminium alloy in an obstructed vertical channel.     

Decomposition through formalization in a product space

When an optimization problem is posed in a product space it is classical to decompose this problem. The goal of this paper is to show how such an approach can be used when the problem to be solved is not naturally posed in a product space. By associating systematically to this problem an equivalent one posed in ann-fold cartesian product space, we obtain by decomposition of the latter both a splitting of operators and a desintegration of constraints for the former. Applications to three rather classical mathematical programming problems are given.     

Ffast Transient Fluorescence Technique to Study Critical Exponents at the Glass Transition

The fast transient fluorescence (FTRF) technique was used to study critical exponents at the glass transition in free-radical crosslinking copolymerization (FCC) for two different monomeric systems, methyl methacrylate (MMA) and styrene (S). Pyrene (P_y ) was used as a fluorescence probe. The fluorescence lifetimes of P_y from its decay traces were measured and used to monitor the gelation process. Changes in the viscosity of the pregel solutions due to glass formation dramatically enhance the fluorescent yield of aromatic molecules. This effect is used to study the glass transition upon gelation of MMA and S monomeric systems as a function of time, at various temperatures and crosslinker concentrations. The results are interpreted in the view of percolation theory. The gel fraction and weight average degree of polymerization exponents β and γ are found to be 0.37 ± 0.02 and 1.66 ± 0.07 in agreement with percolation results.     

Combined neural network and reduced FRF techniques for slight damage detection using measured response data

Summary  This paper deals with structural damage detection using measured frequency response functions (FRF) as input data to artificial neural networks (ANN). A major obstacle, the impracticality of using full-size FRF data with ANNs, was circumvented by applying a data-reduction technique based on principal component analysis (PCA). The compressed FRFs, represented by their projection onto the most significant principal components, were used as the ANN input variables instead of the raw FRF data. The output is a prediction of the actual state of the specimen, i.e. healthy or damaged. A further advantage of this particular approach is its ability to deal with relatively high measurement noise, which is a common occurrence when dealing with industrial structures. The methodology was applied to detect three different states of a space antenna: reference, slight mass damage and slight stiffness damage. About 600 FRF measurements, each with 1024 spectral points, were included in the analysis. Six 2-hidden layer networks, each with an individually-optimised architecture for a specific FRF reduction level, were used for damage detection. The results showed that it was possible to distinguish between the three states of the antenna with good accuracy, subject to using an adequate number of principal components together with a suitable neural network configuration. It was also found that the quality of the raw FRF data remained a major consideration, though the method was able to filter out some of the measurement noise. The convergence and detection properties of the networks were improved significantly by removing those FRFs associated with measurement errors. Received 9 March 2000; accepted for publication 12 December 2000     

正交试验法优选山绿茶中乌苏酸提取工艺

筛选山绿茶中乌苏酸的最佳提取工艺。采用正交设计L9(34)考察液固比、提取时间、乙醇浓度和提取次数4个因素,用高效液相色谱法测定山绿茶中乌苏酸的含量。山绿茶中乌苏酸的最佳提取工艺为A2B3C3D1,即选择液固比(mL/g)10∶1、提取时间4h、乙醇浓度90%、提取次数1次。本法工艺合理,质量稳定,适宜于工业化生产。     

Spot Size Technique: A Theoretical Approach To Optimize Dispersion Compensated

Using a spot size based optimization technique, a bend loss versus dispersion diagram has been obtained theoretically for the most widely used step-index disper sion compensated optical fibers (DCF). The Rayleigh scattering loss can be incorpo rated with bend loss to calculate figure of merit (FOM), thus giving an FOM versus dispersion curve on a single diagram. The plot of the FOM-dispersion curve on a single diagram is useful from the designer's point of view, as it provides a quick reference for choosing the best suitable DCF, which should have large negative dispersion as well as maximum possible value of FOM. The effect of fiber manufac turing losses such as absorption loss on the maximum value of FOM has also been estimated.     

傅里叶变换红外光谱固体制样技术

通过对溴化钾与纳米固体超强酸样品的比例进行了探讨 ,得出制样时溴化钾与样品比例范围为1∶ 0 .0 0 1— 1∶ 0 .0 2 9,其最佳比例范围为 1∶ 0 .0 0 98— 1∶ 0 .0 1 5 ,并且应用于其他固体样品的测定 ,结果基本一致。同时得出 ,固体样品的最少检测量为 2 .0× 1 0 -5g     

Uniformity in radon exhalation from construction materials using can technique

The uniformity in radon exhalation rates for 46 tiles of granite, marble and ceramic used as construction materials were determined using “Can Technique” employing CR-39 nuclear track detectors (NTDs). On each tile, two sealed cans, each enclosing one NTD fixed at the center of the tile surface area covered by the can, were mounted at two different locations of each individual tiles. The track production rates on the NTDs representing radon exhalation rates were measured. The radon exhalation rates from the surface of individual tiles showed uniform exhalations within the calculated uncertainties of the measured values. This makes Can Technique an alternative simple method to measure radon exhalation rates. Calibration required to convert track production rates into radon exhalation rates for the used can and NTD was done using an active technique. The correlation between the measurements by the two techniques shows a good linear correlation coefficient (0.83).