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1.
During the course of our investigation of the electron transfer properties of some redox species through highly hydrophobic
long chain alkanethiol molecules on gold in aqueous and non-aqueous solvents, we obtained some intriguing results such as
unusually low interfacial capacitance, very high values of impedance and film resistance, all of which pointed to the possible
existence of a nanometer size interfacial gap between the hydrophobic monolayer and aqueous electrolyte. We explain this phenomenon
by a model for the alkanethiol monolayer—aqueous electrolyte interface, in which the extremely hydrophobic alkanethiol film
repels water molecules adjacent to it and in the process creates a shield between the monolayer film and water. This effectively
increases the overall thickness of the dielectric layer that is manifested as an abnormally low value of interfacial capacitance.
This behaviour is very much akin to the ‘drying transition’ proposed by Lum, Chandler and Weeks in their theory of length
scale dependent hydrophobicity. For small hydrophobic units consisting of apolar solutes, the water molecules can reorganize
around them without sacrificing their hydrogen bonds. Since for an extended hydrophobic unit, the existence of hydrogen bonded
water structure close to it is geometrically unfavourable, there is a net depletion of water molecules in the vicinity leading
to the possible creation of a hydrophobic interfacial gap. 相似文献
2.
3.
关于非平行板电容器电容计算的讨论 总被引:4,自引:3,他引:1
用串联方法计算非平行板电容器的电容,简便地得到与其他方法相同的结果。 相似文献
4.
As predicted by Haldane, spin, S=1 one-dimensional (1D) Heisenberg antiferromagnet (HAF) has an energy gap between the singlet ground state and first excited triplet. On application of magnetic field, the triplet state Zeeman splits and the energy of one of the triplet state becomes zero at a critical field, Hc. Above Hc the system recovers magnetism. Then, we expect that a quasi-1D HAF will show a magnetic long-range ordering (LRO) at low temperatures due to the inter-chain coupling. This field-induced LRO has not been observed before due to complication of the crystal structure in the materials studied so far and/or technical difficulty.From a heat capacity measurement on a single crystal of an S=1 quasi-Q1D HAF, Ni(C5H14N2)2N3(PF6), we found an anomaly at a temperature in finite fields indicating a field-induced phase transition. A magnetic LRO is confirmed by a neutron diffraction measurement on the same sample. The temperature versus magnetic field phase diagram of this compound is constructed and discussed. 相似文献
5.
Cordula Grüttner Knut Müller Joachim Teller Fritz Westphal Allan Foreman Robert Ivkov 《Journal of magnetism and magnetic materials》2007
Bionized nanoferrite (BNF) particles with high specific power absorption rates were synthesized in the size range of 20–100 nm by high-pressure homogenization for targeted cancer therapy with alternating magnetic fields. Several strategies were used to conjugate antibodies to the BNF particles. These strategies were compared using an immunoassay to find optimal conditions to reach a high immunoreactivity of the final antibody–particle conjugate. 相似文献
6.
Werner WinterGünther W.H Höhne 《Thermochimica Acta》2003,403(1):43-53
A method for measuring heat capacities of small samples using a chip-calorimeter and a heat pulse technique is described. The theoretical background to calculate the heat transport properties and the heat capacity of the sample from the pulse response function is given. Problems and potentials of the method are discussed. An example is given. 相似文献
7.
Summary AK-matrix method implemented with anL
2 basis has been utilized to investigate the1
P
0 continuum of the sodium anion below the 4s threshold. The results include the ground-state electron binding energy, the static dipole polarizability, the partial and
total photodetachment cross-sections and the asymmetry parameter β.
The authors of this paper have agreed to not receive the proofs for correction. 相似文献
8.
T'-214相化合物R2-xCexCuO4(R为稀土离子)成为超导体决定于R3+的离子半径大小、Ce4+的取代量和化合物的热处理时的稳定性.从Raman光谱实验结果提出热处理过程中发生电荷转移.Ce4+的取代引起TN(Cu)下降,当TN(Cu)降到0时,超导性出现。不同的稀土离子TN(Cu)不同,稀土离子的反铁磁性(AFM)与超导性(SC)共存。热电势的测量结果可以用双通道模型解释,n型超导体中电子与空穴共存. 相似文献
9.
The chromatographic separation properties of long, thin adsorption tubes enable substance-specific quantitative enrichment and reduction to be achieved when sampling and thermal desorption are carried out in the same flow direction. The specific retention volumes, and also the breakthrough and peak end volumes, of 69 compounds in the boiling range between-164 and 126°C and of a relative molecular mass between 16 and 119 were determined at temperatures between 30 and 130°C: normal alkanes, isoalkanes, cycloalkanes, alkenes, polyenes, alkynes, aromatics, ethers, alcohols, aldehydes, ketones, carboxylic acids and their esters, nitroalkanes, O-heterocycles, S-heterocycles, chloroalkanes, water, nitrogen monoxide, nitrogen dioxide, carbon dioxide, and sulfur dioxide. The correlation between adsorbent temperature and specific retention volume of these components, presented in the form of diagrams, permits the required quantity of adsorbent to be determined for a given sample volume. Contrary to literature sources, even extremely volatile compounds such as propane, propene, methanol, formaldehyde, formic acid, and chloromethane can be quantitatively retained on Tenax provided the operating conditions are appropriately selected. 相似文献
10.
In this paper, the chronoamperometry was used to study the charging processes of polyethylenedioxythiophene (PEDOT) modified electrodes in the potential range where PEDOT was in the oxidized state. The results show that the charging behaviors of the PEDOT films are well agreed with the exhausted finite diffusion model. The dependence of the capacitance values of the films on potential and concentration of solution was also studied in this potential range. 相似文献