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排序方式: 共有1613条查询结果,搜索用时 31 毫秒
1.
Dr. Sebastian Lars Müller Xinglong Zhou Dr. Peter Leonard Oxana Korzhenko Dr. Constantin Daniliuc Prof. Dr. Frank Seela 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(12):3077-3090
Silver-mediated α-dC–Ag+–β-dC hybrid base pairs decorated with 5-iodo- or 5-octadiynyl residues are well accommodated in duplex DNA. A strong Tm increase and favorable thermodynamic data for duplex DNA were observed after addition of silver ions. The phenomenon is particularly obvious when both nucleobases of the base pairs are functionalized. Neither the position of the base pair, nor the type of 5-substituent had a negative influence. On the contrary, functionalization of conventional silver-mediated β-dC–Ag+–β-dC homo base pairs showed a negative impact induced by the bulky substituents. To this end, cytosine modified 12-mer oligodeoxynucleotides were prepared by solid-phase synthesis employing new α-anomeric 2′-deoxycytidine phosphoramidites. A multigram scale synthesis was developed for 5-iodo-α-d -2′-deoxycytidine ( 1 ) employing the direct glycosylation of cytosine with Hoffer's α-d -halogenose followed by separation of anomeric DMT nucleosides. Regarding base-pair stability and functionalization silver-mediated α/β-dC hybrid base pairs were found to be superior to β/β-dC homo pairs. According to their extraordinary properties, they might find applications in DNA diagnostics, material science, or nanotechnology. 相似文献
2.
3.
Let G be either a split SO(2n+2), or a split adjoint group of type En, (n=6,7,8), over a p-adic field. In this article we study correspondences arising by restricting the minimal representation of G to various dual pairs in G. 相似文献
4.
The surgery obstruction of a normal map to a simple Poincaré pair (X, Y) lies in the relative surgery obstruction group L *(π 1(Y) → π 1(X)). A well-known result of Wall, the so-called π-π-theorem, states that in higher dimensions a normal map of a manifold with boundary to a simple Poincaré pair with π 1(X) ? π 1(Y) is normally bordant to a simple homotopy equivalence of pairs. In order to study normal maps to a manifold with a submanifold, Wall introduced the surgery obstruction groups LP * for manifold pairs and splitting obstruction groups LS *. In the present paper, we formulate and prove for manifold pairs with boundary results similar to the π-π-theorem. We give direct geometric proofs, which are based on the original statements of Wall’s results and apply obtained results to investigate surgery on filtered manifolds. 相似文献
5.
We prove that for any given c, 1 < c < 17/11, almost all natural numbers are representable in the form [x
c] + [p
c], where x is a natural number and p is a prime. 相似文献
6.
7.
A scheme for teleporting a three-particle state is proposed when three pairs of entangled particles are used as quantum channels. Quantum teleportation can be successfully realized with a certain probability if the receiver adopts an appropriate unitary-reduction strategy. The probability of successful teleportation is determined by the smaller coetficients of the three entangled pairs. 相似文献
8.
Athanassios G. Bratsos 《Numerical Algorithms》2007,46(1):45-58
A predictor–corrector (P-C) scheme is applied successfully to a nonlinear method arising from the use of rational approximants
to the matrix-exponential term in a three-time level recurrence relation. The resulting nonlinear finite-difference scheme,
which is analyzed for local truncation error and stability, is solved using a P-C scheme, in which the predictor and the corrector
are explicit schemes of order 2. This scheme is accelerated by using a modification (MPC) in which the already evaluated values
are used for the corrector. The behaviour of the P-C/MPC schemes is tested numerically on the Boussinesq equation already
known from the bibliography free of boundary conditions. The numerical results are derived for both the bad and the good Boussinesq
equation and conclusions from the relevant known results are derived.
相似文献
9.
用庞小峰先生提出的生物能量传递的新理论和 Runge-Kutta数值模拟方法,研究了三通道α-螺旋蛋白质中激发的孤子的动力学特性,求出在0K和300K温度下该孤子稳定地沿蛋白质链传递.由此可见,它能担任在蛋白质分子中传递生物能量的功能.从而再次证实了新理论的可利用性. 相似文献
10.
Nonlocal character of entangled photon pairs generated in spontaneous parametric downconversion is demonstrated. One photon from a pair propagates through a Mach-Zehnder interferometer and is detected in coincidence-count measurement with its twin. Width of the coincidence-count interference pattern (measured for various values of path difference in the Mach-Zehnder interferometer) depends on spectral width of the twin as a result of entanglement of photons in a pair. The experimental setup is analyzed for a Gaussian spectral filter and a Fabry-Perot resonator. It is shown that nonlocal interference is much stronger for cw pumping in comparison with femtosecond pulsed pumping for values of parameters commonly used in spontaneous parametric downconversion experiments. 相似文献