CoFe2O4自形成磁性液体场致结构化对磁化的影响

因为磁性液体的磁性微粒有着很强的相互作用,Langevin顺磁理论不能很好描述磁性液体的磁化强度随外磁场的变化.研究认为影响磁化的主要因素是磁性液体内微粒整体的结构化,其结构的形成储存了部分磁化功,直接或间接地影响了磁化.在此基础上提出“压缩”模型,修正了描述磁性液体常用的Langevin函数,得出了与实验较好符合的曲线.所提出的一个压缩后等效体积分数与外磁场强度的关系式,近似地描述了磁性液体在磁场中磁化的过程.由修正式得出了近似初始磁化率随体积分数变化关系.     

CoFe2O4自形成磁性液体场致结构化对磁化的影响

The Langevin paramagnetic theory can’t describe the relation between magnetization of ferrofluids and applied magnetic field. The structuralization of ferrofluids, which is considered the main influence factor of the magnetization, is regarded. The part of magnetization works is deposited when the structure is forming. This action influences the magnetization of ferrofluids directly or indirectly. On the base of the “compressing” model, the Langevin function that usually describes the magnetization of ferrofluid is modified, and a well-fitted curve is obtained. An equation of the relation between the equivalent volume fraction after being “compressed” and the intensity of magnetic field is discovered, which approximately describes the process of magnetization. The relation between the approximate initial susceptibility and the volume fraction can be obtained from modified formula.     

水基自形成CoFe2O4 磁性液体的零磁场粘滞特性

在零磁场下 ,水基自形成CoFe2 O4磁性液体粘度 η与CoFe2 O4纳米微粒体积分数Φ显示出特异的关系 ,然而 ,球形刚性粒子填料悬浮液粘度理论不能很好解释 .通过对水基自形成CoFe2 O4磁性液体中的微粒相互作用分析发现 ,此磁性液体的沉降和在磁场中的成链需有以预团聚体为核的大粒子存在 .在这一基础上 ,建立了团聚涨落模型 .于是 ,平均粒径、Einsten系数和粒径分布偏差均成为微粒体积分数的函数 ,也即对Popplewell粘度公式的修正 .最后得到与实验很好吻合的 η～Φ曲线及关系式 .     

水基自形成CoFe2O4 磁性液体的零磁场粘滞特性

The plot of viscosity versus particle volume fraction for the water carrier of self-formed CoFe2O4 magnetic fluid is abnormal in zero magnetic field. However,the viscosity theory of the suspension with the global rigid particle filling cannot explain the experiment well. That is because the nanoparticles have aggregated before preparation of magnetic fluid. The fact is found that the sedimentation without magnetic field and the becoming chains in magnetic field of this type of magnetic fluid need the big particles which core are pre-aggregates by researching the interaction of particles of magnetic fluid. Around the big particles,nanoparticles are absorbed with the type of dynamic state. It is on that idea that the model of fluctuant aggregation is made. So,the average diameter,Einstein ratio and particles size distributive deviation of free suspended bodies in zero magnetic fluid are the functions of the particles volume fraction. And then,Popplewell’s formula of the viscosity is modified with this model. As a result,a well-fitted curve is obtained.