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1.
A nanomaterials-based novel molecular beacon has attracted growing attentions in fluorescent assays as many nanomaterials possess excellent quenching efficiency. In this work, a gold-based nanobeacon probe was established to detect organophosphorus pesticides for the first time. The constructed gold-based nanobeacon acted as a signal indicator and could display the decreasing of the intensity in the presence of targets, which competitively bound to single strand DNA. To achieve a high sensitive probe, some parameters including solution pH, temperature and reaction time were investigated and optimized. The gold-based nanobeacon probe assay was proved to be rapid and sensitive to achieve a detection limit of 0.035 μM for isocarbophos, 0.134 μM for profenofos, 0.384 μM for phorate and 2.35 μM for omethoate, respectively. The prepared nanobeacon effectively reduced the background and improved the detection sensitivity and selectivity. The probe is stable, easy to operate and does not need sophisticated instruments. These features makes the probe feasible for screening trace organophosphorus pesticides in real samples. 相似文献
2.
We obtain expressions for the energy spectrum widths of Rayleigh waves corresponding to their deformational coupling to Fermi and Boltzmann electrons in a two-dimensional layer near the surface of a semibounded solid. We evaluate the nonequilibrium energy of Rayleigh waves that depends on these widths and is caused by the same coupling to the corresponding hot electrons. We show that this energy is independent of the degeneracy degree of the electrons and is given by the mean energy of free Rayleigh waves heated up to temperature of the electrons. We find conditions under which the thermodynamics is determined by this nonequilibrium energy of Rayleigh waves in films of a certain thickness with Fermi electrons near the surface and by the equilibrium energy of bulk phonons in thicker samples. All the results are obtained using the Keldysh diagram technique applied to the case of semibounded media. 相似文献
3.
4.
M. A. Efendiev J. Fuhrmann S. V. Zelik 《Mathematical Methods in the Applied Sciences》2004,27(8):907-930
For the Boussinesq approximation of the equations of coupled heat and fluid flow in a porous medium we show that the corresponding system of partial differential equations possesses a global attractor. We give lower and upper bounds of the Hausdorff dimension of the attractor depending on a physical parameter of the system, namely the Rayleigh number of the flow. Numerical experiments confirm the theoretical findings and raise new questions on the structure of the solutions of the system. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
5.
Clelia Marchionna Stefano Panizzi 《Mathematical Methods in the Applied Sciences》2007,30(11):1295-1309
We introduce a set of conserved quantities of energy‐type for a strictly hyperbolic system of two coupled wave equations in one space dimension. The system is subject to mechanical boundary conditions. Some of these invariants are asymmetric in the sense that their defining quadratic form contains second order derivatives in only one of the unknowns. We study their independence with respect to the usual energies and characterize their sign. In many cases, our results provide sharp well‐posedness and stability results. Finally, we apply some of our conservation laws to the study of a singular perturbation problem previously considered by J. Lagnese and J. L. Lions. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
6.
We consider goodness of fit tests for the Rayleigh distribution with grouped data. New Kolmogrov–Smirnov type tests are suggested and compared with the traditional chi-square and likelihood ratio tests. The results show that some of the suggested tests have a good power performance as compared with the traditional ones. 相似文献
7.
Starting from the vectorial Rayleigh diffraction integral formula and without using the far-field approximation, a solution of the wave equation beyond the paraxial approximation is found, which represents vectorial non-paraxial elliptical Gaussian beams in free space. The far-field expressions for non-paraxial Gaussian beams and elliptical Gaussian beams can be regarded as special cases treated in this paper. Some basic propagation properties of vectorial non-paraxial elliptical Gaussian beams, including the irradiance distribution, phase term, beam widths and divergence angles are studied. Numerical results are given and illustrated. 相似文献
8.
Starting from the vectorial Rayleigh diffraction integral formula and using a simple expansion of the nucleus in the Rayleigh formula, an analytical propagation equation of vectorial nonparaxial Gaussian beams in free space is derived, which permits us to perform numerical calculations in comparison with the expression derived by Ciattoni et al. and with the direct numerical integration of the Rayleigh formula. It is found that as usual the use of expansion of vectorial Rayleigh diffraction integral is sufficient to provide satisfactory numerical results as compared with the direct integration of the Rayleigh formula. The above two analytical expressions are valid under certain conditions, however both are applicable in the far field. 相似文献
9.
提出级联佛克脱型原子滤光器(Linked VADOF)的新构想。从理论上分析并计算了级联佛克脱型原子滤光器的透射谱。结果表明,级联佛克脱型原子滤光器将佛克脱型原子滤光器的多峰改造为单峰结构,具有比佛克脱型原子滤光器更窄的线宽和更高的噪声抑制比。将这种新型结构应用于激光信标锁频。该锁频方案提高了信标光频率的稳定性。在此基础上,给出了发射端采用级联佛克脱型原子滤光器锁频,接收端采用法拉第型原子滤光器(FADOF)滤光的新型卫星激光链路系统。外场初步联调实验表明了该系统的可行性。 相似文献
10.
R. A. Taylor S. Haacke B. Deveaud I. Bar Joseph R. Zimmermann 《Physica E: Low-dimensional Systems and Nanostructures》1998,2(1-4)
The time-resolved secondary emission of resonantly created excitons in GaAs quantum wells is studied using femtosecond up-conversion spectroscopy. The behaviour of the rise and decay of the secondary emission and reflectivity in quantum wells is strongly dependent upon the disorder at the interfaces, the exciton density and the temperature. In the case of low densities and temperatures the emission is independent of the exciton density and rises quadratically in time, in excellent agreement with recent theory for Rayleigh scattering from two-dimensional excitons subjected to disorder. These rise times are compared directly with
times measured by time-integrated four-wave mixing (FWM). The comparison of the dynamics displayed in time-resolved secondary radiation and time-integrated FWM provide a clear understanding of the coherence properties of QW excitons in the first few picoseconds after excitation. High-contrast oscillations that are due to quantum beats between the heavy- and light-hole 1s-states are seen. The visibility decay at very low densities is long
ps and is related to the action of potential fluctuations on the scattering of heavy-hole and light-hole excitons. 相似文献