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The far-infrared spectrum of acrolein, CH2CHCHO, is studied in the 100–360 cm−1 region using continuum radiation from a synchrotron source. The combination of a very high resolution spectrometer, a long absorption path, and a low sample pressure, yields observed line widths of less than 0.0008 cm−1. Observation of the ν18 (157.9 cm−1), and ν13 (323.8 cm−1) fundamental bands, together with six hot bands in the same regions, gives information on eight low-lying vibrational states of the molecule, including the Fermi and Coriolis interactions among them. Combining the present assignments with previous data on the ν12 (564.34 cm−1) and ν17 (593.08 cm−1) fundamental bands, all ten excited vibrational levels below 700 cm−1 are analyzed in terms of one 1-state fit, two 2-state fits, and one 5-state fit. 相似文献
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The far-infrared spectrum of acrolein, CH2CHCHO: The ν18 fundamental and (ν17 + ν18) − ν18 hot bands
The ν18 fundamental band (∼158 cm−1) of acrolein is studied at high resolution (0.0015 cm−1) using synchrotron radiation from the Canadian Light Source facility and a Bruker IFS 125HR Fourier transform spectrometer. By fitting this band, together with some pure rotational transitions, molecular parameters are obtained to accurately determine the energies of the ν18 = 1 state levels for values of (J, Ka) up to at least (45, 24). These parameters should be useful for future high resolution studies of acrolein hot bands. This is demonstrated here by a detailed analysis of the (ν17 + ν18) − ν18 hot band at ∼589 cm−1. The upper state (ν17 + ν18) of this band is found to be perturbed by Coriolis interactions analogous to those affecting the ν17 state. 相似文献
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Synthesis of ferrocenyl-substituted pyrazoles via the reaction between (2-formyl-1-chlorovinyl)ferrocene and hydrazine derivatives is described. Depending upon the substitution pattern of hydrazine, the reaction affords 1-alkyl/aryl-5-ferrocenylpyrazoles and/or 1-alkyl/aryl-3-ferrocenylpyrazoles. The reaction appears to be general for a variety of hydrazine derivatives. 相似文献
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