全文获取类型
收费全文 | 570篇 |
免费 | 44篇 |
国内免费 | 24篇 |
专业分类
化学 | 173篇 |
晶体学 | 9篇 |
力学 | 169篇 |
数学 | 38篇 |
物理学 | 249篇 |
出版年
2023年 | 12篇 |
2022年 | 6篇 |
2021年 | 10篇 |
2020年 | 13篇 |
2019年 | 9篇 |
2018年 | 7篇 |
2017年 | 15篇 |
2016年 | 20篇 |
2015年 | 14篇 |
2014年 | 56篇 |
2013年 | 37篇 |
2012年 | 56篇 |
2011年 | 36篇 |
2010年 | 25篇 |
2009年 | 33篇 |
2008年 | 28篇 |
2007年 | 32篇 |
2006年 | 23篇 |
2005年 | 31篇 |
2004年 | 30篇 |
2003年 | 31篇 |
2002年 | 15篇 |
2001年 | 20篇 |
2000年 | 9篇 |
1999年 | 10篇 |
1998年 | 11篇 |
1997年 | 16篇 |
1996年 | 6篇 |
1995年 | 5篇 |
1994年 | 5篇 |
1993年 | 6篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1989年 | 3篇 |
1985年 | 1篇 |
1982年 | 1篇 |
1976年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有638条查询结果,搜索用时 15 毫秒
1.
This paper analyses and models the dynamic interaction among permeable multi-cracks in a piezoelectric strip under anti-plane shear waves by the Schmidt method. The Fourier transform is applied and then two pairs of triple integral equations can be solved using the Schmidt method. The results show that the stress and the electric displacement intensity factors of cracks depend on not only the crack length and the piezoelectric coefficient, but also the thickness of the piezoelectric strip, the distance between multi-cracks and the frequency of incident wave. 相似文献
2.
Frictionless indentation responses of transversely isotropic piezoelectric film/rigid substrate systems under circular cylindrical indenter (i.e., punch), conical indenter (i.e., cone), and spherical indenter (i.e., sphere) are investigated. Both insulating and conducting indenters are considered. The technique of Hankel transformation is employed to derive the corresponding dual integral equations for the mixed boundary value indentation problems. For the two limiting cases of infinitely thick and infinitely thin piezoelectric films, closed-form solutions are obtained. For piezoelectric films of finite thickness, a numerical method is constructed to solve the dual integral equations and semi-empirical models having only two unknown parameters are proposed for the responses of indentation force, electric charge and electric potential, and contact radius. With the two parameters inferred from the numerical results, the semi-empirical formulae are found to provide good estimates of the indentation responses for the two limiting cases of infinitely thick and thin piezoelectric films, as well as those in between. The inferred parameters in the proposed semi-empirical formulae for normalized indentation force and electric charge are checked against four different piezoelectric materials and are found to be insensitive to the selection of piezoelectric materials. It is believed that the proposed semi-empirical indentation formulae are useful in developing experimental indentation techniques to extract the material properties of piezoelectric films. 相似文献
3.
4.
A re-usable and sensitive cryptand-22-coated quartz-crystal membrane piezoelectric sensor with a homemade computer interface for signal acquisition and data processing was prepared and applied as a gas-chromatographic (GC) detector for various organic molecules. The oscillating frequency of the quartz crystal decreased due to the adsorption of organic molecules on cryptand-22. Effects of functional group, molar mass, steric hindrance and polarity of organic molecules on frequency responses of the cryptand-coated piezoelectric crystal detector were investigated. The cryptand-coated piezoelectric crystal GC detector had demonstrated high sensitivity for various polar organic molecules and good reproducibility when re-used. The frequency responses of the cryptand-coated crystal for various molecules were in the following order: carboxylic acids (RCOOH)primary amines (R-NH2)>alcohols (ROH)>secondary amines (R2NH)>tertiary amines (R3N)>ketones. More polar molecules exhibited better frequency responses. The effect of temperature and amount of coating on the frequency responses of cryptand-coated crystal GC detector were also investigated. The cryptand-coated piezoelectric crystal GC detector compared well with the commercial thermal conductivity detector (TCD). 相似文献
5.
提出了控制电位电解和恒电流电解两类电解沉积的压电频移分析法测定的理论公式,用实验结果验证了它的正确性. 相似文献
6.
Guangyu Shen Hua Wang Shuzhen Tan Jishan Li Guoli Shen Ruqin Yu 《Analytica chimica acta》2005,540(2):279-284
A novel piezoelectric immunosensor based on mixed self-assembled monolayers (mixed SAMs) formed by short-chain amine- and carboxyl-terminated thiols has been developed to immobilize antigens onto gold electrodes for detecting antisperm antibody (AsAb) in human serum samples. The properties and the enhanced performance of the affinity biosensor interface based on mixed SAMs are investigated. Most importantly, analytical results of several human serum samples using the developed technique are in satisfactory agreement with those given by the enzyme-linked immunosorbent assay (ELISA) method in the concentration ranging from 32.3 to 300.0 mU/ml. It means the procedure proposed in this paper is likely to have a great potential in research and may play an important clinical role in a few years later. 相似文献
7.
Kazuyoshi Yano Hiroshi Yoshitake Uwe T. Bornscheuer Rolf D. Schmid Kazunori Ikebukuro Kenji Yokoyama Yuzo Masuda Isao Karube 《Analytica chimica acta》1997,340(1-3):41-48
Piezoelectric quartz crystal sensors were developed using lipids with various properties for highly sensitive detection of chemical vapors. Lipids with varying lengths of alkyl chains were coated onto 10 MHz AT-cut quartz crystal resonators and the response of these modified crystals to chemical vapors were measured. It was shown that hydrophilic compounds, such as ethanol and methanol, could be recognized efficiently by lipids having shorter alkyl chains, whereas lipids with longer alkyl chains showed affinity to more hydrophobic vapors, such as toluene, hexane and cyclohexane. Frequency changes caused by adsorption of alcohols could be enhanced when cholesterol was co-immobilized in the lipid layer. To confirm the assumption that the sensor-response might be affected by the properties of lipids derived from acyl chains, we have examined the effects of two types of newly synthesized unusual lipids on sensor response. When lipids having one triple bond each at different positions on their alkyl chains were coated onto quartz crystals separately, lower responses were observed compared to responses obtained for a sensor with immobilized, saturated phosphatidylcholine. Lipids containing -branched acyl chains, however, showed good affinity for organic vapors, and sensor responses improved 4–5-fold. Moreover, these sensors were shown to have sensitivity of the same order as the humans' sense of smell (10−5–10−6 w/w in liquid paraffin) when measured using standard odorants (isovaleric acid, skatole, etc.) for an olfactometry established in Japan. 相似文献
8.
Piezoelectric materials have received much attention due to their great potential in environmental remediation by utilizing vibrational energy. In this paper, a novel piezoelectric catalyst, CoOx nanoparticles anchored BiFeO3 nanodisk composite, was intentionally synthesized via a photodeposition method and applied in piezocatalytic degradation of rhodamine B (RhB) under ultrasonic vibration. The as-synthesized CoOx/BiFeO3 composite presents high piezocatalytic efficiency and stability. The RhB degradation rate is determined to be 1.29 h−1, which is 2.38 folds higher than that of pure BiFeO3. Via optimizing the reaction conditions, the piezocatalytic degradation rate of the CoOx/BiFeO3 can be further increased to 3.20 h−1. A thorough characterization was implemented to investigate the structure, piezoelectric property, and charge separation efficiency of the CoOx/BiFeO3 to reveal the nature behind the high piezocatalytic activity. It is found that the CoOx nanoparticles are tightly adhered and uniformly dispersed on the surface of the BiFeO3 nanodisks. Strong interaction between CoOx and BiFeO3 triggers the formation of a heterojunction structure, which further induces the migration of the piezoinduced holes on the BiFeO3 to CoOx nanoparticles. The recombination of electron-hole pairs is retarded, thereby increasing the piezocatalytic performance greatly. This work may offer a new paradigm for the design of high-efficiency piezoelectric catalysts. 相似文献
9.
10.
本文结合自组装单分子层膜(SAMs)和聚电解质静电吸附组装技术,提出了一种新的用于气相压电免疫检测的生物分子固定化方法,研制了一种用于检测小鼠IgG抗体的压电免疫传感器。首先在石英晶片的金电极表面自组装了一层L-胱氨酸SAMs,再在膜上组装带相反电荷的海藻酸钠,最后通过调节pH值定向固定羊抗鼠纯化抗体,优化了固定条件。通过超声雾化法产生的小鼠IgG气溶胶,研制成了直接气相检测小鼠IgG的压电免疫系统。结果表明,该方法对所固定的生物分子活性影响较小,传感器对小鼠IgG的响应快,灵敏度高,在0.14~6μg.μL-1范围内具有良好的线性关系,精密度好,再生方便。 相似文献