全文获取类型
收费全文 | 1095篇 |
免费 | 22篇 |
国内免费 | 82篇 |
专业分类
化学 | 485篇 |
晶体学 | 20篇 |
力学 | 502篇 |
综合类 | 8篇 |
数学 | 28篇 |
物理学 | 156篇 |
出版年
2024年 | 2篇 |
2023年 | 15篇 |
2022年 | 21篇 |
2021年 | 26篇 |
2020年 | 29篇 |
2019年 | 23篇 |
2018年 | 21篇 |
2017年 | 31篇 |
2016年 | 37篇 |
2015年 | 34篇 |
2014年 | 24篇 |
2013年 | 63篇 |
2012年 | 63篇 |
2011年 | 76篇 |
2010年 | 51篇 |
2009年 | 60篇 |
2008年 | 68篇 |
2007年 | 67篇 |
2006年 | 69篇 |
2005年 | 64篇 |
2004年 | 66篇 |
2003年 | 34篇 |
2002年 | 24篇 |
2001年 | 28篇 |
2000年 | 29篇 |
1999年 | 21篇 |
1998年 | 21篇 |
1997年 | 20篇 |
1996年 | 16篇 |
1995年 | 14篇 |
1994年 | 15篇 |
1993年 | 12篇 |
1992年 | 10篇 |
1991年 | 10篇 |
1990年 | 13篇 |
1989年 | 4篇 |
1988年 | 7篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1982年 | 1篇 |
1980年 | 3篇 |
1979年 | 2篇 |
1978年 | 1篇 |
1977年 | 1篇 |
排序方式: 共有1199条查询结果,搜索用时 46 毫秒
1.
Tsuguo SUNAMURA 《Proceedings of the Japan Academy. Series B, Physical and biological sciences》2015,91(9):481-500
Substantial progress in research on the recession of coastal cliffs composed of soft materials has been made in recent years and data with higher accuracy have been accumulated. This paper provides the state of the art review in the recession studies and highlights two new findings obtained from the reanalysis of existing data. The review topics are: episodic and localized nature of cliff recession; the development of cliffline; the relationship between cliff height and recession rate; mechanisms of cliff toe erosion by waves; a fundamental equation for wave-induced toe erosion; factors controlling toe erosion; and slope instabilities and mass movements. The findings are presented on (1) the temporal change in cliffline recession mode and (2) the effect of beach sediment at the cliff base on the cliff erosion. 相似文献
2.
Sh. M. Aitaliev 《International Applied Mechanics》2004,40(10):1065-1091
Some results on underground structures obtained by Kazakh mechanicians are reviewed. The review covers a period of the last forty years. Also results on the mechanics of special objects are discussed.Translated from Prikladnaya Mekhanika, Vol. 40, No. 10, pp. 3–36, October 2004. 相似文献
3.
High-resolution Fourier transform spectra of CH3OH have been investigated in the infrared region from 930 to 1450 cm−1 in order to map the torsion-rotation energy manifolds associated with the ν7 in-plane CH3 rock, the ν11 out-of-plane CH3 rock, and the ν6 OH bend. Upper-state term values have been determined from the assigned spectral subbands, and have been fitted to power-series expansions to obtain substate origins and effective B-values for the three modes. The substate origins have been grouped into related families according to systematic trends observed in the torsion-vibration energy map, but there are substantial differences from the traditional torsional patterns. There appears to be significant torsion-mediated spectral mixing, and a variety of “forbidden” torsional combination subbands with |Δυt|>1 have been observed, where υt denotes the torsional quantum number (equivalent to υ12). For example, coupling of the (υ6,υt)=(1,0) OH bend to nearby torsionally excited (υ7,υt)=(1,1) CH3-rock and (υ8,υt)=(1,1) CO-stretch states introduces (υ6,υt)=(1,0)←(0,1) subbands into the spectrum and makes the ν7+ν12−ν12 torsional hot band stronger than the ν7 fundamental. The results suggest a picture of strong coupling among the OH-bending, CH3-rocking, and CO-stretching modes that significantly modifies the traditional energy structure and raises interesting and provocative questions about the torsion-vibration identity of a number of the observed states. 相似文献
4.
Vanessa de Freitas Cunha Lins Geraldo Francisco de Andrade Reis Carlos Roberto de Araujo 《Applied Surface Science》2006,253(5):2875-2884
In this work, electrochemical impedance spectroscopy and linear polarization are used in determining porosity of zinc phosphates, and of nickel and manganese modified zinc phosphates on electrogalvanized steel. The porosity of the phosphate layers ranges from 0.1% for the manganese-modified hopeite to 8% for hopeite, using the linear polarization and the electrochemical impedance spectroscopy techniques. The porosity values measured using the two techniques were in agreement. All impedance spectra of coated samples showed two steps, with two capacitive arcs and an inductive looping. 相似文献
5.
A. S. Romakhin I. M. Zaripov Yu. G. Budnikova Yu. M. Kargin E. V. Nikitin A. P. Tomilov Yu. A. Ignat'ev 《Russian Chemical Bulletin》1992,41(6):1036-1040
The mechanism of the electrosynthesis of phosphate esters from white phosphorus was investigated. It was shown that the reaction takes place by two paths, i.e., monomeric (with the participation of dissolved phosphorus) and polymeric (with the participation of phosphorus on the surface of an emulsion drop). It was established that in an alcohol solution of tetraethylammonium iodide the main part of the final product is formed through an intermediate polymeric compound. It was noticed that by studying the dynamics of the accumulation of the dissolved product during electrolysis it is possible to trace the mechanism of reaction of the phosphorus at the individual stages of the process.A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Scientific Center, Russian Academy of Sciences, 420028 Kazan'. V. I. Ul'yanov-Lenin Kazan' State University, 420028 Kazan'. Translated fromIzvestiya Akademii Nauk, Seriya Khimicheskaya, No. 6, pp. 1328–1333, June, 1992. 相似文献
6.
In order to better understand the early continental evolution of the Anshan area, one ofthe typical Precambrian distribution areas of the North China Craton, the geochronology and REEcomposition of the zircons from the meta-argillo-arenaceous rock occurred as enclave in 3.1 GaLishan trondhjemite are studied by using SHRIMP ll ion microprobe. It is indicated that the Pa-leoarchaean is a very important continental formation period in the Anshan area and 3.2 Ga can beregarded as the boundary between the Paleoarchaean and Mesoarchaean. 相似文献
7.
The direct flow injection potentiometric (FIP) analysis of phosphate in hydroponic nutrient solution has been carried out using a cobalt-wire ion-selective electrode (ISE). Synthetic hydroponic nutrient solution, commercial hydroponic nutrient solution and working hydroponic farm nutrient solution were analysed for phosphate using the FIP technique. It is shown that FIP results compare favourably to standard methods of analysis such as spectrophotometry and indirect photometric ion-pair chromatography. Reproducible FIP response curves with a slope of −(47.57±0.03) mV per decade and intercept of −(169.7±0.1) mV were obtained for four separate calibrations in the concentration range 5.0×10−4–1.0×10−2 M H2PO4−. Anion corrections for interferences by Cl−, NO3− and SO42− were applied to all samples using the selectivity coefficients determined independently using a fixed interference method. Nevertheless, it was found that anion corrections were not necessary, as the deviations fell within the bounds of experimental error for the cobalt-wire ISE technique (i.e.±2–5% R.S.D.). The proposed FIP method enables the direct determination of phosphate in hydroponic nutrient solutions. 相似文献
8.
Reduced inorganic phosphorus in the natural environment: significance, speciation and determination 总被引:1,自引:0,他引:1
It is commonly assumed that phosphorus occurs almost exclusively in the environment as fully oxidized phosphate (primarily H2PO4− and HPO42−, where the oxidation state of phosphorus is +V). Recent developments in the field of microbiology and research on the origin of life have suggested a possibly significant role for reduced, inorganic forms of phosphorus in bacterial metabolism and as evolutionary precursors of biological phosphate compounds. Reduced inorganic forms of phosphorus include phosphorus acid (H3PO3, P(+III)), hypophosphorus acid (H3PO2, P(+I)) and various forms of phosphides (P(−III)). Reduced phosphorus has been detected in anaerobic sediments, sewage treatment facilities and in industrial and agricultural processes.Microbiological evidence suggests a significant role for reduced phosphorus species in metabolic processes and raises interesting questions regarding the biogeochemistry of this nutrient in the environment. However, the paucity of data on the presence and cycling of reduced phosphorus compounds in the environment requires attention in order to elucidate the role of these compounds in natural systems. This paper discusses the significance of reduced phosphorus in the natural environment, its speciation and methods of detection. 相似文献
9.
一种新的磷酸根离子敏感电极研究 总被引:5,自引:0,他引:5
一种新的磷酸根离子敏感电极研究肖丹,俞汝勤,李军,袁孔铨(湖南大学化学化工系,长沙,410082)关键词磷酸根,离子选择电极,磷酸二氢根磷酸根离子浓度的测定在化学化工、环境保护、生命科学和临床医学等领域有着重要的意义。对磷酸根离子敏感电极的研究和探索... 相似文献
10.
Christian Lherbet 《Tetrahedron letters》2005,46(20):3565-3567
The treatment of trialkyl phosphate with different alkyl bromides provides facile access to mixed phosphate esters. The presence of substoichiometric amounts of lithium bromide was found to be critical to this transesterification process, supporting a mechanism involving initial generation of phosphate anion, followed by its nucleophilic attack on alkyl bromide. 相似文献