Determination of partition behavior of organic surrogates between paperboard packaging materials and air

The suitability of recycled paperboard packaging materials for direct food contact applications is a major area of investigation. Chemical contaminants (surrogates) partitioning between recycled paper packaging and foods may affect the safety and health of the consumer. The partition behavior of all possible organic compounds between cardboards and individual foodstuffs is difficult and too time consuming for being fully investigated. Therefore it may be more efficient to determine these partition coefficients indirectly through experimental determination of the partitioning behavior between cardboard samples and air. In this work, the behavior of organic pollutants present in a set of two paper and board samples intended to be in contact with foods was studied. Adsorption isotherms have been plotted and partition coefficients between paper and air have been calculated as a basis for the estimation of their migration potential into food. Values of partition coefficients (Kpaper/air) from 47 to 1207 were obtained at different temperatures. For the less volatile surrogates such as dibutyl phthalate and methyl stearate higher Kpaper/air values were obtained. The adsorption curves showed that the more volatile substances are partitioning mainly in air phase and increasing the temperature from 70 to 100 degrees C their concentrations in air (Cair) have almost doubled. The analysis of surrogates was performed with a method based on solvent extraction and gas chromatographic-flame ionization detection (GC-FID) quantification.     

Adjustable wettability of paperboard by liquid flame spray nanoparticle deposition

Liquid flame spray process (LFS) was used for depositing TiO_x and SiO_x nanoparticles on paperboard to control wetting properties of the surface. By the LFS process it is possible to create either superhydrophobic or superhydrophilic surfaces. Changes in the wettability are related to structural properties of the surface, which were characterized using scanning electron microscope (SEM) and atomic force microscope (AFM). The surface properties can be ascribed as a correlation between wetting properties of the paperboard and the surface texture created by nanoparticles. Surfaces can be produced inline in a one step roll-to-roll process without need for additional modifications. Furthermore, functional surfaces with adjustable hydrophilicity or hydrophobicity can be fabricated simply by choosing appropriate liquid precursors.     

Distortional hardening plasticity model for paperboard

A distortional hardening elasto-plastic model at finite strains suitable for modeling of orthotropic materials is presented. As a prototype material, paperboard is considered. An in-plane model is established. The model developed is motivated from non-proportional loading tests on paperboard where the paperboard is pre-strained in one direction and then loaded in the perpendicular direction. A softening effect is revealed in the pre-strained samples. The observed experimental findings cannot be accurately predicted by current models for paperboard. To be able to model the softening effects, a yield surface based on multiple hardening variables is introduced. It is shown that the model parameters can be obtained from simple uniaxial experiments. The model is implemented in a finite element framework which is used to illustrate the behavior of the model at some specific loading situations and is compared with strain fields obtained from Digital Image Correlation experiments.     

A model for the through-thickness elastic–plastic behaviour of paper

An elastic–plastic material model for the out-of-plane mechanical behaviour of paper is presented. This model enables simulation the elastic–plastic behaviour under high compressive loads in the through-thickness direction (ZD). Paper does not exhibit a sharp transition from elastic to elastic–plastic behaviour. This makes it advantageous to define critical stress states based on failure stresses rather than yield stresses. Moreover, the failure stress in out-of-plane shear is strongly affected by previous plastic through-thickness compression. To cover these two features, a model based on the idea of a bounding surface that grows in size with plastic compression is proposed. Here, both the bounding and the yield surfaces are suggested as parabolas in stress space. While the bounding surface is open for compressive loads, the yield surface is bordered by the maximum applied through-thickness compression.     

吹扫捕集气相色谱法测定卷烟包装卡纸中苯系物残留

采用吹扫捕集气相色谱法测定卷烟包装卡纸中苯系物残留,并对测试条件进行了优化。所测定的苯、甲苯、乙苯、对二甲苯、间二甲苯、邻二甲苯、苯乙烯等在4.3~900μg.L-1浓度范围具有良好的线性,相关系数均达到0.999 9,检出限为1.0~11.6 ng.g-1,回收率为91.5%~109.2%,重复测定5次的相对标准偏差为1.73%~3.24%。