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1.
Hongchao Li Yufeng Hu Yanguang Zhang Dongge Ma Lixiang Wang Xiabin Jing Fosong Wang 《Journal of polymer science. Part A, Polymer chemistry》2004,42(16):3947-3953
A conjugated poly(p‐CN‐phenylenevinylene) (PCNPV) containing both electron‐donating triphenylamine units and electron‐withdrawing cyano groups was prepared via Knoevenagel condensation in a good yield. Gel permeation chromatography suggested that the soluble polymer had a very high weight‐average molecular weight of 309,000. A bright and saturated red emission was observed under UV excitation in solution and film. Cyclic voltammetry showed that the polymer presented quasi‐reversible oxidation with a relatively low potential because of the triphenylamine unit. A single‐layer indium tin oxide/PCNPV/Mg–Ag device emitted a bright red light (633 nm). © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3947–3953, 2004 相似文献
2.
J. Seixas de Melo J. Pina H.D. Burrows R.E. Di Paolo A.L. Maanita 《Chemical physics》2006,330(3):449-456
A comprehensive photophysical and spectroscopic study of a new class of p-phenylenevinylene oligomers (PPV-trimers) possessing different alkyl and alkyloxy sidechain substituents and different end groups (aldehyde, CC, phenylene and anthracene units) was undertaken in solution at room temperature (293 K), low temperature (77 K) and in thin films. The study comprises absorption, emission and triplet–triplet absorption spectra, together with quantitative measurements of quantum yields (fluorescence, intersystem crossing, internal conversion and singlet oxygen formation) and lifetimes. The data allow the determination of rate constants for all decay processes. From these, several conclusions could be drawn. Changing from alkyl to alkyloxy substituents does not change fluorescence and internal conversion yields but decreases the (already small) intersystem crossing yield. The introduction of anthracene at the terminal ends of the PPV-trimers leads to the lowest fluorescence yield reported in this study. Of particular importance is the fact that the fluorescence quantum yields in films are of the same order of magnitude as those in solution, which suggests the potential for use of these oligomers for light-emitting device applications. With one of the alkyloxy derivatives, a more detailed study of the early part of the fluorescence decay was made, and it was found that upon excitation a fast conformational relaxation process of the initially excited oligomer occurs, leading to a more planar conjugation segment. 相似文献
3.
The preparation and identification of a series of trifluoromethylated and bis(trifluoromethylated) precursors and monomers for bridge substituted trifluoromethylated poly(p-phenylenevinylene) (PPV) is reported. These monomers were prepared in several steps from terephthaldicarboxaldehyde and they contain symmetrical and unsymmetrical combinations of leaving groups and/or polarizers, including chlorides, sulfoxides, sulphones, tosylates and S-methyl (and also O-ethyl) xanthates. The electron withdrawing effect of the trifluoromethyl group dominated the regioselectivity of substitution, thus allowing the convenient and selective formation of unsymmetrically substituted products in high yield. 相似文献
4.
Clarissa A. Olivati Rodrigo F. Bianchi Osvaldo N. Oliveira Jr. 《Polymer Degradation and Stability》2006,91(10):2342-2346
Poly(p-phenylene vinylene) (PPV) derivatives are well known for their applications in polymer light emitting diodes (PLEDs). PPV derivatives are highly susceptible to photo-oxidation though, which is mainly caused by the scission of the vinyl double bond on the polymer backbone. In this work, we show that Langmuir-Blodgett (LB) films are less degraded than cast films of a PPV derivative (OC1OC6-PPV). Both films had similar thickness (∼50 nm) to allow for a more realistic comparison. Degradation was monitored with UV-vis and FTIR spectroscopies. The results indicated that cast films were completely degraded in ca. 400 min, while LB took longer time, i.e. about four times the values for the cast films. The differences can be attributed to the more compact morphology in the LB than in the cast films. With a compact morphology the diffusion of oxygen in the LB film is hampered and this causes a delay in the degradation process. 相似文献
5.
Jin ZHAI Feng Lian BAI Qing Guo HE Ying Shun LI Lei JIANG Tong LIN Organic Solid Laboratory Research Center for Molecular Sciences Institute of Chemistry The Chinese Academy of Science Beijing 《中国化学快报》2000,11(9)
The hotSPOt in the fields of molecular films focuses on highly ordered, ultrathin filmswith molecularly controllable surface properties. It is attractive tO stUdy supramolecularfunctional POlymeric materials with suitable physical properties and abilities to formorganized superstrUctures at the interfacesl'2'3A. Dendritic macromolecules are a kind ofmaterials which is capable of self-organizing into superstrUctUres'. So a new dendrimerlike POly(Phenylene vinylene)- --hyperbranched conj "… 相似文献
6.
Xufeng Wu Gaoquan Shi Feng'En Chen Shaohu Han Junbiao Peng 《Journal of polymer science. Part A, Polymer chemistry》2004,42(12):3049-3054
Poly[2‐methoxy‐5‐(2′‐ethylhexyloxy)‐p‐phenylenevinylene] (MEH‐PPV) with a molar mass of 26–47 × 104 g mol?1 and a polydispersity of 2.5–3.2 was synthesized by a liquid–solid two‐phase reaction. The liquid phase was tetrahydrofuran (THF) containing 1,4‐bis(chloromethyl)‐2‐methoxy‐5‐(2′‐ethylhexyloxy)benzene as the monomer and a certain amount of tetrabutylammonium bromide as a phase‐transfer catalyst. The solid phase consisted of potassium hydroxide particles with diameters smaller than 0.5 mm. The reaction was carried out at a low temperature of 0 °C and under nitrogen protection. No gelation was observed during the polymerization process, and the polymer was soluble in the usual organic solvents, such as chloroform, toluene, THF, and xylene. A polymer light‐emitting diode was fabricated with MEH‐PPV as an active luminescent layer. The device had an indium tin oxide/poly(3,4‐ethylenedioxylthiophene) (PEDOT)/MEH‐PPV/Ba/Al configuration. It showed a turn‐on voltage of 3.3 V, a luminescence intensity at 6.1 V of 550 cd/m2, a luminescence efficiency of 0.43 cd/A, and a quantum efficiency of 0.57%. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3049–3054, 2004 相似文献
7.
Francesco Babudri Antonio Cardone Gianluca M. Farinola Raffaele Tommasi 《Journal of organometallic chemistry》2008,693(15):2631-2636
Poly(2′,5′-dioctyloxy-4,4′,4″-terphenylenevinylene) with (E) configuration of the vinylene double bonds was prepared by Suzuki-Miyaura polymerization of (E)-4,4′-dibromostilbene and 2,5-dioctyloxy-1,4-benzenediboronic acid. Attempts to extend this simple procedure to the synthesis of the polymer with (Z) configuration, starting from (Z)-4,4′-dibromostilbene, were unsuccessful. However, the use of (Z)-4,4′-diiodostilbene and a careful choice of Pd catalyst and experimental conditions, lead to a material with a >95/<5 (Z)/(E) ratio of vinylene units. The investigation of optical properties of both the (E) and (Z) polymers evidenced that (Z) linkages act as defects which reduce the effective conjugation length in the polymer backbone. 相似文献
8.
Woo‐Hyung Lee Hoyoul Kong Se‐Young Oh Hong‐Ku Shim In‐Nam Kang 《Journal of polymer science. Part A, Polymer chemistry》2009,47(1):111-120
A series of modified thiophene groups containing PPV‐based semiconducting materials, poly[(2,5‐bis(octyloxy)‐1,4‐phenylenevinylene)‐alt‐(2,2′bithienylenevinylene)] ( PPBT ), poly[(2,5‐bis(octyloxy)‐1,4‐phenylenevinylene)‐alt‐(5,5‐thiostilylenevinylene)] ( PPTVT ), have been synthesized through a Horner coupling reaction. From the FTIR and 1H NMR spectroscopy, the configuration of the vinylene groups in the polymers was all trans (E) geometry. The weight‐average molecular weights (Mw) of PPBT and PPTVT were found to be 11,700 and 11,800, with polydispersity indices of 2.51 and 2.53, respectively. PPBT and PPTVT thin films exhibit UV–visible absorption maxima at 538 and 558 nm, respectively, and the strong absorption shoulder peaks at 578 and 602 nm, respectively. Solution processed field‐effect transistors (FET) fabricated using all the polymers showed p‐type OTFT characteristics. The field‐effect mobility of the PPTVT was obtained up to 2.3 × 10?3 cm2 V?1 s?1, an on/off ratio of 1.0 × 105 with ambient air stability. Studies of the atomic force microscopy (AFM) and X‐ray diffraction (XRD) analysis of the polymer thin films revealed that all the polymers were amorphous structure. The greater planarity and rigidity of PPTVT compared to PPBT results in elongation of conjugation length and better π–π stacking of polymer chains in amorphous region, which leads to improved FET performance. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 111–120, 2009 相似文献
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10.
Manuela Martín‐Zarco Santiago Toribio Joaquín C. García‐Martínez Julián Rodríguez‐López 《Journal of polymer science. Part A, Polymer chemistry》2009,47(23):6409-6419
A series of polyamido amine (PAMAM) dendrimers (Generations 2, 3, 4, and 6) fully functionalized at their periphery with first‐ and second‐generation poly (phenylenevinylene) (PPV) dendrons have been efficiently prepared. MALDI‐TOF mass spectrometry proved to be particularly useful for the characterization of the new hybrid dendrimers as well as for the estimation of the average number of PPV dendrons attached to the surface. The optical absorption and emission properties of these systems were studied. The materials display extremely high molar extinction coefficients and emit blue light with only slightly lower fluorescence quantum yields than the corresponding free dendrons. Self‐quenching interactions between PPV units were not observed in THF. However, the luminescence properties underwent a dramatic change when toluene was used as the solvent. The lower polarity of toluene caused shrinkage of the PAMAM structure and brought the PPV chromophores closer together, leading to self‐quenching interactions and excimer formation. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 6409–6419, 2009 相似文献