有机磷化合物的NMR研究Ⅵ.1,3,2-氧氮磷杂环戊烷的13C谱

测定了19个2-硫代-2-(二乙基氨基)-3-取代苯甲(磺)酰基-1,3,2-氧氮磷杂环戊烷的¹³C NMR参数.在苯甲酰类化合物中,邻位有非氢取代基时,非环的²J(PNC)随温度而变化(0~6.1Hz),这是因羧基与苯环空间位置(构象)随温度变化所致.     

Joint signal alignment precoding and physical network coding for heterogeneous networks

Mobile traffic in cellular based networks is increasing exponentially, mainly due to the use of data intensive services like video. One effective way to cope with these demands is to reduce the cell-size by deploying small-cells along the coverage area of the current macro-cell system. The deployment of small-cells significantly improves the indoor coverage. Nevertheless, as additional spectrum licenses are difficult and expensive to acquire, it is expected that the macro and small-cells will coexist under the same spectrum. The coexistence of the two systems results in cross-tier/inter-system interference. In this context, we consider the application of joint signal alignment (SA) and physical network coding (PNC) for the uplink of heterogeneous networks, in order to cancel the interference generated from small-cells at the macro-cell user terminal. The joint design of SA and PNC allows to serve more users than the case where only PNC or interference alignment (IA) is employed individually. We compare our proposed joint SA-PNC schemes with the recently designed IA based techniques for the uplink heterogeneous systems. Simulation results show that the proposed SA-PNC is quite efficient to remove the inter-tier/system interference while allowing to increase the overall data rate, by serving more users, as compared with the IA based methods     

推转PNC波函数的角动量投影

研究原子核较高自旋态的特征,不仅需要考虑K混合,而且应该引入Coriolis相互作用项,亦即使用推转Hamilton量.推转项的引入破坏了时间反演对称性,单粒子角动量在内禀对称轴上的投影量子数已不再是好量子数.从表面上看,这会使得理论计算变得非常复杂,但考虑到原子核的某些固有对称性,将角动量投影技术应用于含推转成份的粒子数守恒波函数(推转PNC波函数)并不十分困难.在这一理论框架下详细推导计算原子核能谱及电磁性质的基本表达式,从而表明实施该方案的可行性.     

Comparison of the Electrochemical Behavior of the High Molecular Mass Cadmium Proteins in Arabidopsis thaliana and in Vegetable Plants on Using Preparative Native Continuous Polyacrylamide Gel Electrophoresis (PNC‐PAGE)

In Arabidopsis cytosol (supernatant) and in supernatants of vegetable plants high molecular mass cadmium proteins with molecular mass 200 kDa were isolated by using p reparative n ative c ontinuous p olya crylamide g el e lectrophoresis (PNC‐PAGE). Because of a different electrochemical behavior of the Cd proteins in Arabidopsis and endive supernatants on using the same PAGE method, it is concluded that the high molecular mass cadmium proteins of Arabidopsis and endive possess different isoelectric points. Consequently, different chemical structures of the Cd proteins with molecular mass 200 kDa are present in Arabidopsis thaliana and in endive. During the electrophoretic separation of vegetable metalloproteins by using the Model 491 Prep Cell from BioRad, electroanalytical processes like electrode reactions may play an important role.