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1.
Wacker oxidation is an industry-adopted process to transform olefins into value-added epoxides and carbonyls. However, traditional Wacker oxidation involves the use of homogeneous palladium and copper catalysts for the olefin addition and reductive elimination. Here, we demonstrated an ultrahigh loading Cu single atom catalyst(14% Cu, mass fraction) for the palladium-free Wacker oxidation of 4-vinylanisole into the corresponding ketone with N-methylhydroxylamine hydrochloride as an additive under mild conditions. Mechanistic studies by 18O and deuterium isotope labelling revealed a hydrogen shift mechanism in this palladium-free process using N-methylhydroxylamine hydrochloride as the oxygen source. The reaction scope can be further extended to Kucherov oxidation. Our study paves the way to replace noble metal catalysts in the traditional homogeneous processes with single atom catalysts. 相似文献
2.
Design of broadband achromatic metasurface device based on phase-change material Ge2Sb2Te5
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Shuyuan Lv 《中国物理 B》2022,31(12):124206-124206
Based on the phase-change material Ge2Sb2Te5 (GST), achromatic metasurface optical device in the longer-infrared wavelength is designed. With the combination of the linear phase gradient GST nanopillar and the adjustment of the crystalline fraction m value of GST, the polarization insensitive achromic metalenses and beam deflector metasurface within the longer-infrared wavelength 9.5 μm to 13 μm are realized. The design results show that the achromatic metalenses can be focused on the same focal plane within the working waveband. The simulation calculation results show that the full-width at half-maximum (FWHM) of the focusing spot reaches the diffraction limit at each wavelength. In addition, the same method is also used to design a broadband achromatic beam deflector metasurface with the same deflection angle of 19°. The method proposed in this article not only provides new ideas for the design of achromatic metasurfaces, but also provides new possibilities for the integration of optical imaging, optical coding and other related optical systems. 相似文献
3.
Kai Xu Zhenchang Tang Yan Zhang Wanshu Li Haiou Li Lihui Wang Liming Liu Honghang Wang Feng Chi Xiaowen Zhang 《Current Applied Physics》2019,19(10):1076-1081
Germanium dioxide (GeO2) aqueous solutions are facilely prepared and the corresponding anode buffer layers (ABLs) with solution process are demonstrated. Atomic force microscopy, X-ray photoelectron spectroscopy and ultraviolet photoelectron spectroscopy measurements show that solution-processed GeO2 behaves superior film morphology and enhanced work function. Using GeO2 as ABL of organic light-emitting diodes (OLEDs), the visible device with tris(8-hydroxy-quinolinato)aluminium as emitter gives maximum luminous efficiency of 6.5 cd/A and power efficiency of 3.5 lm/W, the ultraviolet device with 3-(4-biphenyl)-4-phenyl-5-tert-butylphenyl-1,2,4-triazole as emitter exhibits short-wavelength emission with peak of 376 nm, full-width at half-maximum of 42 nm, maximum radiance of 3.36 mW/cm2 and external quantum efficiency of 1.5%. The performances are almost comparable to the counterparts with poly (3,4-ethylenedioxythiophene):poly (styrenesulfonate) as ABL. The current, impedance, phase and capacitance as a function of voltage characteristics elucidate that the GeO2 ABL formed from appropriate concentration of GeO2 aqueous solution favors hole injection enhancement and accordingly promoting device performance. 相似文献
4.
研究了不同比例的PVK与齐聚PPV衍生物DBVP掺杂体系的能量转移和发光特性.通过对PVK,DBVP及PVK:DBVP掺杂体系的UV-vis,PL和PLE光谱的研究,分析了PVK与DBVP之间的能量转移过程.利用PVK在体系中类似于溶剂的分散作用,制备了结构为ITO/PEDOT/PVK:DBVP/LiF/Al的电致发光器件,研究了掺杂体系的电致发光性能.结果表明,在掺杂体系的光致发光和电致发光中,PVK的发射被有效地抑制,PVK与DBVP之间发生了非常有效的能量转移,通过调节PVK与DBVP的比例,可以获得蓝色和绿色发光,同时可以改善器件的发光性能,当PVK与DBVP的重量比为1∶2时,器件的绿色发光效率达到1·06cd/A,此时发光亮度为52cd/m2. 相似文献
5.
报道了硅基有机微腔的电致发光(EL).该微腔由上半透明金属膜、中心有源多层膜和多孔硅分布Bragg反射镜(PS DBR)组成.半透明金属膜由Ag(20nm)构成,充当发光器件的负电极和微腔的上反射镜.有源多层膜由Al (1 nm) / LiF(05 nm) /Alq3/Alq3:DCJTB/NPB/CuPc/ITO/SiO2组成,其中的Al/LiF为电子注入层,ITO为正电极,SiO2为使正、负电极电隔离的介质层.该PS DBR是采用设备简单、成本低廉且非常省时的电化学腐蚀法用单晶Si来制备的;该PS
关键词:
电化学腐蚀
电致发光
窄峰发射
硅基有机微腔 相似文献
6.
7.
Changes in thin zinc-sulfide films under the action of the γ-radiation of Co60 are studied by investigating electroluminescence spectra of terbium embedded in these films as a luminescent probe. It is
shown that changes in the relation of the intensities of bands, a decrease in their halfwidth and the background component,
and simplification of the spectrum are observed in a short-wave region of the Tb radiation spectrum that corresponds to5D3→7Fj transitions. The same modification of the radiation spectrum is characteristic of ZnS films whose crystalline structure is
ordered in the course of thermal annealing at a temperature of 350°C. Based on the analysis of the data obtained it is inferred
that irradiating the ZnS films with small radiation doses of 104–105 rad leads to the ordering of their crystalline structure due to the elimination of one of the types of structural defects.
Institute of Physics of Semiconductors, National Academy of Sciences of Ukraine, 45, Nauka Ave., Kiev-28, 252650. Translated
from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 3, pp. 338–341, May–June, 1997. 相似文献
8.
本文介绍了EltctronicWorkbench软件和计算机虚拟仪器系统,采用计算机模拟仿真技术对电子线路实验加以辅助设计和探索。 相似文献
9.
An optical fiber multi-function device consisting of a single gradient-index-rod lens and a multi-facet blazed reflection
grating is proposed to simultaneously realize functions of wavelength demultiplexing and optical signal distribution in a
multimode optical fiber transmission system. We analyzed the demultiplexing characteristics and the tolerance of optical components
using the ray trace method. This device can realize not only low loss optical signal distribution but also offers improved
demultiplexing characteristics in comparison with the previously proposed demultiplexer-multiposition switch. The following
characteristics are expected from the design using commercially available optical components: a working band of 0.64–0.88
μm, channel separation of 34–36 nm, 3 dB bandwidth of 27–28 nm, channel cross-talk of less than - 40 dB and minimum excess
insertion loss of 0.9–2.1 dB. 相似文献
10.
高斯光束计算平板波导自由传输区远场分布及其修正 总被引:2,自引:2,他引:0
对近轴近似条件下求解亥姆霍兹方程得到的高斯光束显式传播公式做了分析,同时,基于基尔霍夫衍射理论,在菲涅耳近似的条件下给出了相应的高斯光束在远场的传播公式,在此基础上,对近轴近似条件做出了定量分析,给出了这个近似条件引入的误差,提出了一种计算高斯光束远场分布的修正方法,并采用有限差分-光束传播方法(FD-BPM)来检验各种方法的准确性。把这种修正方法应用到平面光集成波导器件,如阵列波导光栅(AWG)、蚀刻衍射光栅(EDG)等器件的设计和模拟中,可以大大降低工作的复杂性,同时可以得到精确的结果。 相似文献