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排序方式: 共有672条查询结果,搜索用时 15 毫秒
1.
Elena Kardash-Strochkova Yakov I. Tur’yan I. Kuselman Naphtali Brodsky 《Accreditation and quality assurance》2002,7(6):250-254
The results of two interlaboratory comparisons of acid number determinations in used motor oils are discussed. It is shown
that the comparability of the measurement results is not as good as that required by known standards for petroleum products.
The problem is motor oil contaminants which accumulated during use, and which are the source of a matrix effect in the acid
number determination. The standard methods’ drawbacks are analyzed and some improvements are proposed. Repeatability and accuracy
of the improved methods are evaluated.
Received: 11 December 2001 Accepted: 15 February 2002 相似文献
2.
描述了简并V型三能级原子与单模相干态光场的Raman相互作用,获得了处于激发态单态的原子与相干态光场相互作用的结果.利用探测原子与光场的相互作用将原子和光场制备成最大缠结态,并注入待测原子,通过原子与腔模构成的Bell基矢演化,对腔场进行选择性探测,获得探测原子相互作用后可能的量子状态,然后对待测原子与腔场进行联合探测,接着对探测原子的量子状态实施幺正变换,就将探测原子制备到待测原子的初始量子态上,从而实现未知原子态的隐形传送. 相似文献
3.
T. Drglin 《Accreditation and quality assurance》2003,8(3-4):130-133
A validation procedure based on the ISO/IEC 17025 standard was used to demonstrate the long-term stability of a calibration
process and to assess the measurement uncertainty of a standard test method for optical emission vacuum spectrometric analysis
of carbon and low-alloy steel (ASTM E 415–99a). The validation was used to provide documented evidence that the selected method
fulfils the requirements and that the method is ”fit for purpose”. A test for drift was applied to determine statistically
whether the analytical results vary systematically with time. The accuracy and traceability of the optimised method were tested
by an analysis of closely matched matrix certified reference materials (CRMs). The measurement uncertainty estimations took
account of the precision study, the bias and its uncertainty, and the qualification of uncertainties not considered in the
overall performance studies.
Received: 2 November 2002 Accepted: 2 January 2003
Acknowledgement The author expresses gratitude to Dr. Aleš Fajgelj for helpful discussions during the 3rd Central European Conference on Reference Materials and Measurements.
Presented at CERMM-3, Central European Reference Materials and Measurements Conference: The function of reference materials
in the measurement process, May 30–June 1, 2002, Rogaška Slatina, Slovenia
Correspondence to T. Drglin 相似文献
4.
An analytical result is not considered to be complete without a statement of the measurement uncertainty associated with
it. Evaluation of measurement uncertainty is therefore an essential part of every determination. In the present study the
measurement uncertainty of the result of determination of selenium in the reference material Seronorm Trace Elements Serum
was studied. The combination of a digestion procedure using sulfuric acid, V2O5 in H2SO4 and hydrogen peroxide and the continuous flow approach of hydride generation atomic fluorescence spectrometry (HG-AFS) detection
was used for selenium determination. The total uncertainty budget was calculated with the help of the GUM Workbench program,
in which computations follow the rules of the ’ISO guide to the expression of uncertainty in measurement’. The major sources
of uncertainty were found to be due to the recovery of the procedure, measurement of peak heights and the purity of Na2SeO3. A selenium mass fraction of 77.1±4.8 ng/g (with a coverage factor of 2.1, 95% probability) was determined, which is comparable
with the recommended value of 80 ng/g.
Received: 13 September 2002 Accepted: 23 December 2002
Acknowledgements We would like to thank Tinkara Buˇcar, B.Sc. for useful discussions and the IAEA Vienna, for financial support of the project
11553/RO.
Presented at CERMM-3, Central European Reference Materials and Measurements Conference: The function of reference materials
in the measurement process, May 30–June 1, 2002, Rogaška Slatina, Slovenia
Correspondence to V. Stibilj 相似文献
5.
6.
A simple and rapid method is developed to determine the high acidity and the basicity of solutions by chronopotentiometry with a platinum working electrode. The acidity range from 5.0 mol/l H+ to 1.0 mol/l OH− can be measured by the adjustment of deposition potential and time. The response mechanism to acidity and basicity has been explored. The transition potential plateau in chronopotentiograms is caused from the oxidation of hydrogen adsorbed on electrode surface. 相似文献
7.
论测量不确定度 总被引:14,自引:1,他引:14
胡晓燕 《理化检验(化学分册)》2002,38(8):406-409
讨论了测量不确定度的基本概念及应用。分析了误差和不确定度两个概念的区别,探讨了不确定度及分量的评定方法。 相似文献
8.
Reliable, traceable and comparable measurements provide the rational basis for evaluation of the quality of a result and
the starting point for recognized laboratory accreditation in any national area. Modern medical diagnostics and treatment
involve rapidly rising numbers and types of clinical laboratory measurements, that are reliable. Therefore, the basic principles
to be followed to assure the traceability of clinical measurements as required by the Romanian Laws of Metrology are reviewed.
Main sources affecting the quality of the unbroken chain of calibrations that relate the measurements back to appropriate
measurement standards are discussed. Examples of how to achieve traceable measurements in clinical laboratories are presented.
Details of specific uses of reference materials, measuring instruments and standard measurement methods are also discussed.
Received: 8 January 1998 · Accepted: 21 April 1998 相似文献
9.
Vapor pressure data were measured for water, methanol and ethanol as well as their binary mixtures with an ionic liquid (IL) 1-ethyl-3-methylimidazolium dimethylphosphate ([EMIM][DMP]) at varying temperature and IL-content ranging from mass fraction of 0.10–0.70 by a quasi-static method. The vapor pressure data for the IL-containing binary systems were correlated using NRTL equation with average absolute relative deviation (ARD) within 0.0076, and the binary NRTL parameters was used for predicting the vapor pressure of the IL-containing ternary systems with reasonable accuracy. In addition, the infinite activity coefficients of solvents in [EMIM][DMP] and isobaric vapor–liquid equilibrium for IL-containing ternary systems at 101.325 kPa and mass fraction of IL being 0.5 were predicted with the regressed NRTL parameters. The results indicate that ionic liquid [EMIM][DMP] can depress the volatility of the solvents of water, methanol and ethanol but to a varying degree, leading to the variation of relative volatility of a solvent and even removal of azeotrope for water–ethanol mixture. 相似文献
10.
S. Küppers 《Accreditation and quality assurance》1997,2(1):30-35
Any analytical data is used to provide information about a sample. The "possible error" of the measurement can be of extreme
importance in order to have complete information. The measurement uncertainty concept is a way to achieve quantitative information
about this "possible error" using an estimation procedure. On the basis of the analytical result, the chemist makes a decision
on the next step of the development process. If the uncertainty is unknown, the information is not complete; therefore this
decision might be impossible. The major problem for the in-process control (IPC) procedure is that not only the repeatability
but also the intermediate precision (which expresses the variations within laboratories related to different days, different
analysts, different equipment, etc.) has to be good enough to make a decision. Unfortunately, the statistical information
achieved from one single analytical run only gives information about the repeatability. This paper shows that the estimation
of the measurement uncertainty for IPC is a way to solve the problem and gives the necessary information about the quality
of the procedure. An example demonstrates that an estimate of uncertainty based on the standard deviations of an analytical
method gives a value similar to one based on the standard deviations obtained from a control chart. Therefore, the estimation
is both a very useful and also a very cost-effective tool. Though measurement uncertainty cannot replace validation in general,
it is a viable alternative to validation for all methods that will never be used routinely.
Received: 24 May 1996 Accepted: 10 August 1996 相似文献