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间规聚苯乙烯的化学改性 总被引:4,自引:0,他引:4
介绍了间规聚苯乙烯(sPS)的结构,特性和各种化学改性方法,包括在sPS侧链苯环上引入磺酸基,卤素等功能基因,在sPS分子链末端引入马来酸酐,丙烯酸酯等极性基因,与氢化丁二烯-苯乙烯热塑性弹性体(SEBS)形成接枝共聚物,及其与各类烯烃单体的共聚,对进一步拓宽sPs的应用领域具有重要意义。 相似文献
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The copolymerization of styrene (St) with maleic anhydride (MAh) performed at 22 °C in the presence of dibenzyl trithiocarbonate exhibits controlled nature evidenced by: narrow molecular weight distribution, controlled molecular weight and first-order polymerization kinetics. The composition analysis of the copolymers obtained by 13C NMR spectra shows the molar fraction of St in obtained copolymers is almost equal to 0.5 throughout the copolymerization. The sequence structure of the copolymer was obtained from DEPT experiments by recording the spectra at π/4 and 3π/4, and then combining them together, the results showed that the copolymers obtained possessed well-defined alternating structure. The experiment shows that charge-transfer-complex formed from St and MAh participates in both initiation and chain growth throughout the copolymerization. 相似文献
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Maria ?wita?a-?eliazkow 《Polymer Degradation and Stability》2006,91(6):1233-1239
Thermal degradation processes in copolymers of styrene with two stereoisomers of 1,2-ethylenedicarboxylic acids (i.e. maleic acid (the cis-isomer) and fumaric acid (the trans-isomer)) have been studied by mass spectrometry, FTIR and TG measurements. The influence of the chemical composition on thermal degradation of copolymers with acid by non-isothermal thermogravimetric analysis (TG) was also studied. The stereo-configuration of carboxyl groups in copolymers was analysed by potentiometric titration. It was found that copolymers degrade in two main complex stages. The initial step in the decomposition involves the formation of cyclic five-membered anhydrides. The presence of trans configuration of carboxyl groups hinders the formation of cyclic anhydrides and shifts the decomposition to higher temperatures, making decarboxylation competitive. At higher temperatures anhydride decomposition takes place and finally the degradation of main chains occurs. 相似文献
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本实验测定了二苄基马来酸酯甲醇溶液的荧光光谱,并发现马来酸酐对该荧光体系有猝灭作用,通过对不同马来酸酐浓度与各种浓度的二苄基马来酸酯甲醇溶液在400nm处荧光强度数据的分析,发现马来酸酐的浓度与荧光猝灭程度在一定范围内呈良好的线型关系。据此,提出了用荧光猝灭法对马来酸酐及二苄基马来酸酯的定量分析 相似文献
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The use of poly(maleic acid–styrene)-encapsulated silica for the determination of monovalent and divalent cations is well accepted in ion chromatography. The separation of Mn2+, alkali and alkaline earth metal cations is obtained under the same chromatographic conditions. The influences of pH and the concentration of eluent on the retention of cations have been studied. The preparation conditions of packings were studied. The metal ions in the boiler water samples from a thermal power plant were quantitatively determined using this column. The results are in agreement with those determined by ICP and Volumetric analysis methods. 相似文献
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Li Yan Liang Shao Ping Ren Yi Quan Zheng Man Geng Lu Guangzhou Institute of Chemistry Chinese Academy of Sciences Guangzhou China Key Laboratory of Polymer Materials for Electronics Guangdong China Graduate School of the Chinese Academy of Sciences Beijing China 《中国化学快报》2007,18(2):225-228
A series of novel liquid crystalline epoxides with lateral substituents were cured with anhydrides and the cure kinetics was investigated by non-isothermal DSC technique. The results showed that the lengths of lateral substituents have great effect on the value of Ea. The curing reaction became less active, when the liquid crystalline epoxides have long lateral substituents and were controlled by diffusion at the late stage of cure. A nematic structure was observed by POM and XRD. 相似文献
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